RESUMEN
Recently, responsive structure color fibers and fabrics have been designed and prepared for colorimetric detecting of volatile organic compounds (VOCs). Fabric substrates can offer greater flexibility and portability than flat and hard substrates such as glass, silicon wafers, etc. At present, one-dimensional photonic crystal (multilayer films) and three-dimensional dense photonic crystal layers are mainly constructed on fabrics to achieve the response to VOCs. However, the binding force between these structural color coatings and the fabrics was poor, and the dense structures inevitably hindered the diffusion of VOCs. Here, thermoplastic polyurethane (TPU) inverse opal (IOs) fabrics were prepared by sacrificing the SiO2 photonic crystal templates to achieve colorimetric detecting of VOCs. The IOs layer of TPU was cured directly on the fabric surface, TPU infiltrated into the fabric yarns, and bonded the fabrics and IOs layer into a whole, which greatly improved the binding force, and the porous structure and large specific surface area of IOs were conducive to the diffusion of VOCs. The results showed that the TPU IOs fabrics have large reflection peak shifts to DMF, THF, toluene and chloroform vapors, and its concentration has a good linear relationship with the maximum reflection peak value of TPU IOs fabrics. The theoretical detection limits are 1.72, 0.89, 0.78 and 1.64 g m-3, respectively. The response times are 105, 62, 75 and 66 seconds, with good stability. Finally, it was calculated that the discoloration of the TPU IOs fabrics in VOCs was due to the joint-effects of lattice spacing and effective refractive index increase.
RESUMEN
In vitro drug release systems have recently received tremendous attention because they allow noninvasive, convenient, and prolonged administration of pharmacological agents. On-demand epidermal drug release systems can improve treatment efficiency, prevent multidrug resistance, and minimize drug toxicity to healthy cells. In addition, real-time monitoring of drug content is also essential for guiding the determination of drug dosage and replacing drug carriers in time. Therefore, it is important to integrate the above properties in one ideal epidermal patch. Herein, photonic crystals (PCs) based on Fe3O4@C nanoparticles were introduced into drug-loaded poly(N-isopropylacrylamide-co-acrylic acid) (P(NIPAM-AAc)) hydrogel-functionalized textiles. Drug loading and release depended on the expansion and contraction of the hydrogels. The lower critical solution temperature (LCST) of the hydrogels was adjusted to 40 °C, which is higher than the skin temperature, by varying the content of hydrophilic comonomer acrylic acid (AAc) to store the drug at room temperature, and on-demand release was achieved by mild thermal stimulation. Moreover, the lattice spacing (d) of PCs varied with the expansion and contraction of the hydrogels, which can cause the color of P(NIPAM-AAc) hydrogel-functionalized textiles to change. These synchronous thermoresponsive chromic drug uptake and release behaviors provided an effective method for visual and real-time monitoring of drug content. Furthermore, in view of the poor mechanical properties of hydrogel wound dressings, textile matrices were composited to prevent holistic breaking during the stretching process. Biological experiments proved that the drug-loaded P(NIPAM-AAc) hydrogel-functionalized textiles had good antibacterial properties and wound-healing effects.
