Extraction of Active Compounds from Mixtures of Hemp (Cannabis sativa) with Plants of the Zingiberaceae Family.

Hemp is probably one of the most studied plants for its health-promoting properties, with countless documented and patented extraction methods, but literature is scarce on the simultaneous extraction of mixture of raw materials. Hemp, along with other plant materials, could represent a potentially highly valuable source material with resulting reciprocal effects. In this study, hemp (Cannabis sativa) and three members of the Zingiberaceae family, ginger (Zingiber officinale), turmeric (Curcuma longa), and cardamom (Elettaria cardamomum), were extracted simultaneously, and their bioactive component values were investigated. Two extraction methods were used, namely ultrasound-assisted extraction with ethanol and supercritical fluid extraction with carbon dioxide. First, extracts were obtained from separate plant materials. Then, hemp was extracted in combination with ginger, turmeric, and cardamom in a 1:1 ratio. The extracts obtained were evaluated for their antioxidant activity and total phenolic content using UV/VIS spectrophotometry; cannabinoid content, 6-gingerol, and 6-shogaol were measured using liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS); volatile components such as 1,8-cineole, alpha-terpinyl acetate, linalool, and aR-turmerone were measured using gas chromatography with mass spectrometry (GC/MS).

Zero-Waste Approach for Heavy Metals' Removal from Water with an Enhanced Multi-Stage Hybrid Treatment System.

The aim of the work was to develop a zero-waste technological solution for hybrid removal of heavy metals from river sediments. The proposed technological process consists of sample preparation, sediment washing (a physicochemical process for sediment purification), and purification of the wastewater produced as a by-product. A suitable solvent for heavy metal washing and the effectiveness of heavy metal removal were determined by testing EDTA and citric acid. The process for removing heavy metals from the samples worked best with citric acid when the 2% sample suspension was washed over a 5-h period. The method was chosen of the adsorption of heavy metals from the exhausting washing solution on natural clay. Analyses were performed of the three main heavy metals, Cu(II), Cr(VI), and Ni(II), in the washing solution. Based on the laboratory experiments, a technological plan was prepared for the purification of 100,000 tons of material per year.

Determination of the Kinetics and Thermodynamic Parameters of Lignocellulosic Biomass Subjected to the Torrefaction Process.

The torrefaction process upgrades biomass characteristics and produces solid biofuels that are coal-like in their properties. Kinetics analysis is important for the determination of the appropriate torrefaction condition to obtain the best utilization possible. In this study, the kinetics (Friedman (FR) and Kissinger-Akahira-Sunose (KAS) isoconversional methods) of two final products of lignocellulosic feedstocks, miscanthus (Miscanthus x giganteus) and hops waste (Humulus Lupulus), were studied under different heating rates (10, 15, and 20 °C/min) using thermogravimetry (TGA) under air atmosphere as the main method to investigate. The results of proximate and ultimate analysis showed an increase in HHV values, carbon content, and fixed carbon content, followed by a decrease in the VM and O/C ratios for both torrefied biomasses, respectively. FTIR spectra confirmed the chemical changes during the torrefaction process, and they corresponded to the TGA results. The average Eα for torrefied miscanthus increased with the conversion degree for both models (25-254 kJ/mol for FR and 47-239 kJ/mol for the KAS model). The same trend was noticed for the torrefied hops waste samples; the values were within the range of 14-224 kJ/mol and 60-221 kJ/mol for the FR and KAS models, respectively. Overall, the Ea values for the torrefied biomass were much higher than for raw biomass, which was due to the different compositions of the torrefied material. Therefore, it can be concluded that both torrefied products can be used as a potential biofuel source.