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1.
J Environ Manage ; 352: 120093, 2024 Feb 14.
Artículo en Inglés | MEDLINE | ID: mdl-38232597

RESUMEN

Droughts have devastating effects on various sectors and are difficult to quantify and track because of the invisible and slow but prevalent propagation. This dilemma is more significant in the case of the complex interactions between land and atmosphere mechanisms, which are inadequately considered in previous drought metrics. Here, we investigate the spatiotemporal variability of the recently devised metric called 'Drought Potential Index (DPI)', which incorporates the antecedent land water storage and current precipitation. Using the spatial weighted centroid method, we elucidate the emerging spatial movement of the DPI within 168 major global river basins and analyze its influential factors. Improved drought detection and performance disparity of DPI as compared with multi-scale (i.e., 1, 3, 6, 9, 12-month) Standardized Precipitation Index, ensemble soil moisture anomaly, and Total Storage Deficit Index corroborate the robustness and improved insights of DPI. Higher increasing trends in DPI are detected over dryland basins (0.39 ± 0.43 %/a) than in the humid zones (0.15 ± 0.34 %/a). Six hotspot basins, namely, Don, Yellow, Haihe, Rio Grande, Sao Francisco, and Ganges river basins, are identified with increasing (2.1-3.5%/a) DPI during 2003-2021. The interannual occurrence of the highest DPI, spatial shifts, and relative contribution of DPI's constituent variables correspond well to the climatic and anthropogenic changes in humid and dry land basins. The absolute latitudinal/longitudinal shifts of ∼2° (as high as ∼3.2/4.9°) in DPI in 30% (47 out of 168 basins) of the global basins highlight the need for analyzing the water scarcity problems from both the perspectives of long-term trends and spatial shifts. Our findings provide a global assessment of the spatiotemporal shifts of drought potential and will be beneficial to understanding the anthropogenic and climatic influences on water resource management under a changing environment.


Asunto(s)
Sequías , Ríos , Agua , Atmósfera , Suelo , Cambio Climático
2.
J Environ Manage ; 345: 118673, 2023 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-37506447

RESUMEN

Due to excessive nutrient enrichment and rapidly increasing water demand, the occurrence of riverine environment deterioration events such as algal blooms in rivers of China has become more frequent and severe since the 1990s, which has imposed harmful consequences on riverine ecosystems. However, tackling river algal blooms as an important issue of restoring riverine environment is very challenging because the complex interaction mechanisms between the causes are impacted by multiple factors. The contributions of our study consist of: (1) optimizing joint operation of water projects for boosting synergies of water quality and quantity, and hydroelectricity; and (2) preventing algal bloom from perspectives of hydrological and water-quality conditions by regulating water releases of water projects. This study proposed a multi-objective optimization methodology grounded on the Non-dominated Sorting Genetic Algorithm to simultaneously minimize the excess values of algal bloom indicators (water quality, O1), minimize the used reservoir capacity for water supply (water quantity, O2), and maximize the hydropower generation (hydroelectricity, O3). The proposed methodology was applied to several catastrophic algal bloom events that took place between 2017 and 2021 and thirteen water projects in the Hanjiang River of China. The results indicated that the proposed methodology largely stimulated the synergistic benefits of the three objectives by reaching a 36.7% reduction in total nitrogen and phosphorus concentrations, a 33.1% improvement in the remaining reservoir capacity, and a 41.0% improvement in hydropower output, as compared with those of the standard operation policy (SOP). In addition, the optimal water release schemes of water projects would increase the minimum streamflow velocity of downstream algal bloom control stations by 8.6%-9.4%. This study provides a new perspective on water project operation in the environmental improvement in big river systems while boosting multi-objectives synergies to support environmentalists and decision-makers with scientific guidance on sustainable water resources management.


Asunto(s)
Monitoreo del Ambiente , Calidad del Agua , Ecosistema , Mejoramiento de la Calidad , Ríos , Eutrofización , China , Fósforo/análisis , Nitrógeno/análisis
3.
Nat Commun ; 14(1): 3197, 2023 Jun 02.
Artículo en Inglés | MEDLINE | ID: mdl-37268612

RESUMEN

Increasing atmospheric moisture content is expected to intensify precipitation extremes under climate warming. However, extreme precipitation sensitivity (EPS) to temperature is complicated by the presence of reduced or hook-shaped scaling, and the underlying physical mechanisms remain unclear. Here, by using atmospheric reanalysis and climate model projections, we propose a physical decomposition of EPS into thermodynamic and dynamic components (i.e., the effects of atmospheric moisture and vertical ascent velocity) at a global scale in both historical and future climates. Unlike previous expectations, we find that thermodynamics do not always contribute to precipitation intensification, with the lapse rate effect and the pressure component partly offsetting positive EPS. Large anomalies in future EPS projections (with lower and upper quartiles of -1.9%/°C and 8.0%/°C) are caused by changes in updraft strength (i.e., the dynamic component), with a contrast of positive anomalies over oceans and negative anomalies over land areas. These findings reveal counteracting effects of atmospheric thermodynamics and dynamics on EPS, and underscore the importance of understanding precipitation extremes by decomposing thermodynamic effects into more detailed terms.

4.
J Environ Manage ; 342: 118232, 2023 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-37270980

RESUMEN

Artificial neural networks exhibit significant advantages in terms of learning capability and generalizability, and have been increasingly applied in water quality prediction. Through learning a compressed representation of the input data, the Encoder-Decoder (ED) structure not only could remove noise and redundancies, but also could efficiently capture the complex nonlinear relationships of meteorological and water quality factors. The novelty of this study lies in proposing a multi-output Temporal Convolutional Network based ED model (TCN-ED) to make ammonia nitrogen forecasts for the first time. The contribution of our study is indebted to systematically assessing the significance of combining the ED structure with advanced neural networks for making accurate and reliable water quality forecasts. The water quality gauge station located at Haihong village of an island in Shanghai City of China constituted the case study. The model input contained one hourly water quality factor and hourly meteorological factors of 32 observed stations, where each factor was traced back to the previous 24 h and each meteorological factor of 32 gauge stations was aggregated into one areal average factor. A total of 13,128 hourly water quality and meteorological data were divided into two datasets corresponding to model training and testing stages. The Long Short-Term Memory based ED (LSTM-ED), LSTM and TCN models were constructed for comparison purposes. The results demonstrated that the developed TCN-ED model can succeed in mimicking the complex dependence between ammonia nitrogen and water quality and meteorological factors, and provide more accurate ammonia nitrogen forecasts (1- up to 6-h-ahead) than the LSTM-ED, LSTM and TCN models. The TCN-ED model, in general, achieved higher accuracy, stability and reliability compared with the other models. Consequently, the improvement can facilitate river water quality forecasting and early warning, as well as benefit water pollution prevention in the interest of river environmental restoration and sustainability.


Asunto(s)
Amoníaco , Monitoreo del Ambiente , Monitoreo del Ambiente/métodos , China , Reproducibilidad de los Resultados , Modelos Teóricos , Nitrógeno/análisis , Predicción
5.
Sci Total Environ ; 891: 164494, 2023 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-37245810

RESUMEN

Due to a small proportion of observations, reliable and accurate flood forecasts for large floods present a fundamental challenge to artificial neural network models, especially when the forecast horizons exceed the flood concentration time of a river basin. This study proposed for the first time a Similarity search-based data-driven framework, and takes the advanced Temporal Convolutional Network based Encoder-Decoder model (S-TCNED) as an example for multi-step-ahead flood forecasting. A total of 5232 hourly hydrological data were divided into two datasets for model training and testing. The input sequence of the model included hourly flood flows of a hydrological station and rainfall data (traced back to the previous 32 h) of 15 gauge stations, and the output sequence stepped into 1- up to 16-hour-ahead flood forecasts. A conventional TCNED model was also built for comparison purposes. The results demonstrated that both TCNED and S-TCNED could make suitable multi-step-ahead flood forecasts, while the proposed S-TCNED model not only could effectively mimic the long-term rainfall-runoff relationship but also could provide more reliable and accurate forecasts of large floods than the TCNED model even in extreme weather conditions. There is a significant positive correlation between the mean sample label density improvement and the mean Nash-Sutcliffe Efficiency (NSE) improvement of the S-TCNED over the TCNED at the long forecast horizons (13 h up to 16 h). Based on the analysis of the sample label density, it is found that the similarity search largely improves the model performance by enabling the S-TCNED model to learn the development process of similar historical floods in a targeted manner. We conclude that the proposed S-TCNED model that converts and associates the previous rainfall-runoff sequence with the forecasting runoff sequence under a similar scenario can enhance the reliability and accuracy of flood forecasts while extending the length of forecast horizons.

6.
Ground Water ; 61(3): 402-420, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-36098234

RESUMEN

The gravity recovery and climate experiment (GRACE) and its Follow-On mission provide a versatile tool for monitoring groundwater depletion in North China Plain (NCP). However, intermittent data gaps and inherent coarse spatial resolution have restricted the continuous detection of regional groundwater storage anomaly (GWSA) after 2014, the period of interest during the implementation of the south-to-north water diversion middle route project (SNWDP). Here, we investigated the spatiotemporal changes of GWSA in the NCP during 2004 to 2020 based on continuous downscaled GRACE data. First, we derived the continuous terrestrial water storage anomaly from six GRACE and Follow-On solutions (i.e., spherical harmonics (SH) and mass concentration [mascon] solutions). Second, we employed a long short-term memory (LSTM) model and water balance equation to downscale GWSA (i.e., 0.25° × 0.25°). Lastly, we investigated its spatiotemporal characteristics before (2004 to 2014) and after (2015 to 2020) the SNWDP operation. We show the applicability of the continuous downscaled GWSA to capture the characteristics of in situ measurements. The GWSA detects groundwater depletion at a significant (p < 0.05) rate of -17.09 ± 1.80 (SH) and -17.87 ± 1.65 (mascon) mm/a during 2004 to 2014, but a recovering trend of 7.18 ± 3.98 (SH) and 8.23 ± 4.99 (mascon) during 2015 to 2018. The subsequent groundwater extraction and precipitation reduction from 2019 to 2020, resulted in the decreasing trend of GWSA from 2015 to 2020, which is -19.11 ± 8.75 (SH) and -19.72 ± 9.08 mm/a (mascon), respectively. Spatially, the overall depletion trends become nonsignificant along the canals of SNWDP compared to the period 2004 to 2014, and groundwater recovering with trends <6 mm/a near Beijing and Tianjin are detected by the mascon solution during 2015 to 2020.


Asunto(s)
Agua Subterránea , Agua , Clima , Abastecimiento de Agua , China
7.
Environ Sci Pollut Res Int ; 30(7): 17741-17764, 2023 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-36201077

RESUMEN

Energy efficiency is crucial to greenhouse gas (GHG) emission pathways reported by the Intergovernmental Panel on Climate Change. Electrical overload frequently occurs and causes unwanted outages in distribution networks, which reduces energy utilization efficiency and raises environmental risks endangering public safety. Electrical load, however, has a dynamically fluctuating behavior with notoriously nonlinear hourly, daily, and seasonal patterns. Accurate and reliable load forecasting plays an important role in scheduling power generation processes and preventing electrical systems from overloading; nevertheless, such forecasting is fundamentally challenging, especially under highly variable power load and climate conditions. This study proposed a deep learning-based monotone composite quantile regression neural network (D-MCQRNN) model to extract the multiple non-crossing and nonlinear quantile functions while conquering the drawbacks of error propagation and accumulation encountered in multi-step-ahead probability density forecasting. The constructed models were assessed by an hourly power load series collected at the electric grid center of Henan Province in China in two recent years, along with the corresponding meteorological data collected at 16 monitoring stations. The results demonstrated that the proposed D-MCQRNN model could significantly alleviate the time-lag and biased-prediction phenomena and noticeably improve the accuracy and reliability of multi-step-ahead probability density forecasts on power load. Consequently, the proposed model can significantly reduce the risk and impact of overload faults and effectively promote energy utilization efficiency, thereby mitigating GHG emissions and moving toward cleaner energy production.


Asunto(s)
Aprendizaje Profundo , Gases de Efecto Invernadero , Reproducibilidad de los Resultados , Redes Neurales de la Computación , Predicción , Probabilidad
8.
Sci Total Environ ; 835: 155474, 2022 Aug 20.
Artículo en Inglés | MEDLINE | ID: mdl-35489503

RESUMEN

Global compilations and regional studies, indicative of the unsustainable extraction and subsequent unremittingly depleting groundwater (GW) in India, either provide bulk estimates or are confined to the river basins and therefore conceal inferences from a nationwide policymaking perspective. Here, we provide the state-wise past (2000-2020) and future (2030-2050) assessment of dwindling groundwater in India utilizing in-situ groundwater levels (GWL) from 54,112 wells, remote sensing products, and hydrological simulations. By employing three machine learning methods, we show a decline in GWL of over 80% in North India with a notable shift towards the eastern state of Uttar Pradesh and a cumulative groundwater loss (169.96 ± 19.67 km3) equivalent to the water storage capacity of the world's biggest dam (Kariba Dam, Zimbabwe). Its likely contribution to sea-level rise (0.47 ± 0.06 mm) is about 64% of that from annual global glacier melt. Our results typically contrast the GW recovery paradox in South India (e.g., a declining trend of -84.48 ± 38.81 mm/a (p < 0.05) in Andhra Pradesh during 2000-2020), reveal high seasonal variability (e.g., up to ~6 m in Maharashtra), and illustrate the skewed effect of survivor bias in the traditional assessments. We infer the significant impact of underlying hydrogeology and the implementation of water-related policies and projects on the GWL dynamic and variability in the region. Projected GWL reveals a likely water scarcity situation for about 2.8 million km2 area and one billion residents of the country up to 2050. Our observation-based analysis offers insights into the state-level monthly GW dynamics, which is critical for efficient interstate resource allocation, development plans, and policy interventions with broad methodological implications for the water-scarce countries.


Asunto(s)
Agua Subterránea , Hidrología , India , Aprendizaje Automático , Agua
9.
Sci Rep ; 12(1): 798, 2022 01 17.
Artículo en Inglés | MEDLINE | ID: mdl-35039583

RESUMEN

The hydrological cycle, affected by climate change and rapid urbanization in recent decades, has been altered to some extent and further poses great challenges to three key factors of water resources allocation (i.e., efficiency, equity and sustainability). However, previous studies usually focused on one or two aspects without considering their underlying interconnections, which are insufficient for interaction cognition between hydrology and social systems. This study aims at reinforcing water management by considering all factors simultaneously. The efficiency represents the total economic interests of domesticity, industry and agriculture sectors, and the Gini coefficient is introduced to measure the allocation equity. A multi-objective water resources allocation model was developed for efficiency and equity optimization, with sustainability (the river ecological flow) as a constraint. The Non-dominated sorting genetic algorithm II (NSGA-II) was employed to derive the Pareto front of such a water resources allocation system, which enabled decision-makers to make a scientific and practical policy in water resources planning and management. The proposed model was demonstrated in the middle and lower Han River basin, China. The results indicate that the Pareto front can reflect the conflicting relationship of efficiency and equity in water resources allocation, and the best alternative chosen by cost performance method may provide rich information as references in integrated water resources planning and management.

10.
Sci Total Environ ; 817: 152998, 2022 Apr 15.
Artículo en Inglés | MEDLINE | ID: mdl-35031376

RESUMEN

Terrestrial water storage is a crucial component in water cycle and plays an important role in flood formations process, particularly in a changing environment. In this study, we aim to examine the future variation of terrestrial water storage anomaly (TWSA) and associated flood potential in one of the most flood-prone regions, the Yangtze River basin in China. Using the Gravity Recovery and Climate Experiment (GRACE) data, we perform bias correction for seven general circulation models (GCMs) from the Coupled Model Intercomparison Project Phase 6 under three Shared Socio-economic Pathway (SSP) scenarios: SSP126, SSP245, and SSP585. The spatiotemporal characteristics of changes in future Flood Potential Index are projected and compared between the near (2031-2060) and far (2071-2100) future with reference to the historical period (1985-2014). The results show that GCMs-simulated TWSA generally agrees well with the GRACE results after downscaling and bias correction with the average correlation coefficient of 0.86, Nash-Sutcliffe efficiency of 0.73 and the root mean square error of 21.68 mm. We found that the total variance of projected TWSA is mainly sourced from the internal variability and model uncertainties, while the uncertainties in scenarios contribute relatively less. Moreover, the flood potential is projected to decline during the near future under various scenarios and even lower during the far future under SSP585 scenario. Our findings provide implications for flood control and management under climate change over high flood risk regions worldwide.


Asunto(s)
Inundaciones , Ríos , Cambio Climático , Agua , Ciclo Hidrológico
11.
Sci Rep ; 11(1): 7879, 2021 04 12.
Artículo en Inglés | MEDLINE | ID: mdl-33846438

RESUMEN

Global warming and anthropogenic changes can result in the heterogeneity of water availability in the spatiotemporal scale, which will further affect the allocation of water resources. A lot of researches have been devoted to examining the responses of water availability to global warming while neglected future anthropogenic changes. What's more, only a few studies have investigated the response of optimal allocation of water resources to the projected climate and anthropogenic changes. In this study, a cascade model chain is developed to evaluate the impacts of projected climate change and human activities on optimal allocation of water resources. Firstly, a large set of global climate models (GCMs) associated with the Daily Bias Correction (DBC) method are employed to project future climate scenarios, while the Cellular Automaton-Markov (CA-Markov) model is used to project future Land Use/Cover Change (LUCC) scenarios. Then the runoff simulation is based on the Soil and Water Assessment Tool (SWAT) hydrological model with necessary inputs under the future conditions. Finally, the optimal water resources allocation model is established based on the evaluation of water supply and water demand. The Han River basin in China was selected as a case study. The results show that: (1) the annual runoff indicates an increasing trend in the future in contrast with the base period, while the ascending rate of the basin under RCP 4.5 is 4.47%; (2) a nonlinear relationship has been identified between the optimal allocation of water resources and water availability, while a linear association exists between the former and water demand; (3) increased water supply are needed in the water donor area, the middle and lower reaches should be supplemented with 4.495 billion m3 water in 2030. This study provides an example of a management template for guiding the allocation of water resources, and improves understandings of the assessments of water availability and demand at a regional or national scale.

12.
Sci Total Environ ; 707: 136074, 2020 Mar 10.
Artículo en Inglés | MEDLINE | ID: mdl-31863997

RESUMEN

Heat wave flash drought or precipitation deficit flash drought has devastating impacts on society and the environment. This study explored the historical changes (1960-2015) of the two categories of flash drought over the Pearl River Basin (PRB) in China, and revealed how they would change in the future (2016-2100), by coupling the variable infiltration capacity mode with the global climate model under representative concentration pathway (RCP) 2.6, 4.5, and 8.5 scenarios. Our results indicate that during 1960-2015, the mid-northern PRB has experienced heat wave flash drought frequently while the western PRB suffered from precipitation deficit flash drought. In future, heat wave flash drought under RCP2.6 and 4.5 would occur mostly in the western and eastern PRB. Specifically, heat wave flash drought would become severe under RCP8.5, especially for the eastern PRB. However, precipitation deficit flash drought would be concentrated in the western PRB. Except for the central regions, PRB generally exhibits a significant upward trend in heat wave flash drought under RCP4.5. Under RCP8.5, distinct increases in both categories of flash drought across almost the whole PRB are expected. For precipitation deficit flash drought, only a few regions show significant upward trends under RCP2.6 and 4.5.

14.
Data Brief ; 26: 104440, 2019 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-31516958

RESUMEN

The dataset contains reservoir characteristic parameters, streamflow series of reservoirs in the upper Yangtze River, the standard operating rules (SORs) and the seasonal top of buffer pools (seasonal TBPs) for these reservoirs, which were provided by the Yangtze River Commission. Moreover, annual hydropower of these reservoirs is tested to evaluate operation performance. These research materials are related to the research article in Advances in Water Resources, entitled 'Optimal impoundment operation for cascade reservoirs coupling parallel dynamic programming with importance sampling and successive approximation' (He et al., 2019). The dataset could be used to derive optimal operating rules to explore the potential benefits of water resources via our proposed algorithm (importance sampling - parallel dynamic programming, IS-PDP) in different runoff scenarios. It can also be further applied for water resources management and other potential users.

15.
Nat Commun ; 9(1): 4389, 2018 10 22.
Artículo en Inglés | MEDLINE | ID: mdl-30348951

RESUMEN

Weather extremes have widespread harmful impacts on ecosystems and human communities with more deaths and economic losses from flash floods than any other severe weather-related hazards. Flash floods attributed to storm runoff extremes are projected to become more frequent and damaging globally due to a warming climate and anthropogenic changes, but previous studies have not examined the response of these storm runoff extremes to naturally and anthropogenically driven changes in surface temperature and atmospheric moisture content. Here we show that storm runoff extremes increase in most regions at rates higher than suggested by Clausius-Clapeyron scaling, which are systematically close to or exceed those of precipitation extremes over most regions of the globe, accompanied by large spatial and decadal variability. These results suggest that current projected response of storm runoff extremes to climate and anthropogenic changes may be underestimated, posing large threats for ecosystem and community resilience under future warming conditions.

16.
J Biosci Bioeng ; 122(3): 345-50, 2016 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-27036597

RESUMEN

Soil microbial biomass (SMB) and bacterial community structure, which are critical to global ecosystem and fundamental ecological processes, are sensitive to anthropogenic activities and environmental conditions. In this study, we examined the possible effects of closed-off management (an ecological natural restoration measures, ban on anthropogenic activity, widely employed for many important wetlands) on SMB, soil bacterial community structure and functional marker genes of nitrogen cycling in Dongting Lake wetland. Soil samples were collected from management area (MA) and contrast area (CA: human activities, such as hunting, fishing and draining, are permitted) in November 2013 and April 2014. Soil properties, microbial biomass carbon (MBC), and bacterial community structure were investigated. Comparison of the values of MA and CA showed that SMB and bacterial community diversity of the MA had a significant increase after 7 years closed-off management. The mean value of Shannon-Weiner diversity index of MA and CA respectively were 2.85 and 2.07. The gene copy numbers of 16S rRNA and nosZ of MA were significant higher than those of CA. the gene copy numbers of ammonia-oxidizing archaea (AOA) and nirK of MA were significant lower than those of CA. However, there was no significant change in the gene copy numbers of ammonia-oxidizing bacteria (AOB) and nirS.


Asunto(s)
Biomasa , Lagos , Microbiología del Suelo , Humedales , Amoníaco/metabolismo , Archaea/genética , Archaea/aislamiento & purificación , Archaea/metabolismo , Bacterias/genética , Bacterias/aislamiento & purificación , China , Genes Bacterianos/genética , Actividades Humanas , Ciclo del Nitrógeno/genética , ARN Ribosómico 16S/genética , Suelo/química
17.
Chemosphere ; 77(3): 368-75, 2009 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-19679329

RESUMEN

This paper spatially analyzed human health risk associated with ingesting manganese (Mn) contents in groundwater and vegetables irrigated with contaminated pond water in Huangxing Town, Middle China. The combination of monitoring data and sequential indicator simulation (SIS) was used to determine Mn exposure distributions in pond water and groundwater. Hazard quotient (HQ) associated with ingesting Mn was calculated to evaluate the risk to human health. Many HQs determined from risks exceed 1 in the region, indicating that the use of groundwater and pond water poses potential risk to human health. Lower risk areas are located in the northwest and partly southeast of the region. The probabilistic risk assessment formulated suitable references for pollution remedy and control in Huangxing Town. Safe areas in 75th percentile of HQ map are suggested to be safe for use and, the manganese residues in the unsafe areas of the 25th percentile of HQ map is to be treated firstly.


Asunto(s)
Manganeso/análisis , Contaminantes del Suelo/análisis , Contaminantes Químicos del Agua/análisis , China , Ingestión de Alimentos , Agua Dulce/química , Indicadores de Salud , Humanos , Medición de Riesgo , Suelo/análisis , Verduras/química
18.
Water Res ; 39(16): 3755-62, 2005 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-16112169

RESUMEN

Environment-friendly cellulose/chitin beads being prepared by coagulating a blend of cellulose and chitin in 6 wt% NaOH/5 wt% thiourea aqueous solution with 5% H2SO4 possessed higher heavy metals uptake capacity than pure chitin flakes. The mechanisms of Pb2+ adsorption on cellulose/chitin beads at pH0=5 were investigated at the molecular levels by scanning electron micrographs (SEM), transmission electron micrographs (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffraction (XRD). The result revealed that mechanisms for the adsorption of Pb2+ on the cellulose/chitin beads could be described as complexation between Pb2+ and N atom in the chitin, and further adsorption of Pb2+ nearby the complexed Pb2+ and precipitation of the hydrolysis product of the Pb2+ complex on the beads as the crystalline state. Furthermore, structural factors such as larger surface area of the beads resulted from microporous-network structure, low crystallinity of cellulose/chitin beads and high hydrophilicity induced by hydrophilic skeleton of cellulose played an important role in increasing adsorption ability.


Asunto(s)
Plomo/química , Purificación del Agua/métodos , Adsorción , Celulosa/química , Precipitación Química , Quitina/química , Hidrólisis , Plomo/aislamiento & purificación , Contaminantes del Agua/aislamiento & purificación
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