RESUMEN
Herein, a novel nanocomposite based on lanthanum zinc ferrite and nickel tungstate was created by incorporation between (MMT-jeffamine-400) nanoparticles (NPs), chloromethyl styrene as a binder and polymethyl methacrylate monomer using solution polymerization. The as-designed nanocomposites were employed to confiscate xylenol orange "X.O" as an acidic dye and rhodamine B "RhB" as "an amphoteric dye" from colored wastewater. The impact of several parameters such as solution pH, initial dye concentration, the effect of time, and the effect of temperature was explored. The consequences indicated that the pure organoclay had negligible adsorption while that composed of organoclay with PMMA@CMS-polymer incorporated with LaZnFe2O4@NiWO4 particles detached more than 90% for xylenol orange (XO) and 93% for "rhodamine B" molecules. Electrostatic interactions are the predominant factor in the adsorption of cationic and amphoteric adsorbates, as proven by zeta-potential measurement. Additionally, the adsorbent may be regenerate and utilized up to five times with good adsorption capabilities by adding sodium hydroxide. As a result, the removal can be effectively accomplished using the nanocomposite as an adsorbent. The actual and theoretical adsorption capacity values for both dyes at all doses were closely matched, which supported the adsorption kinetics data that fit the pseudo-first order rate model well. The adsorption data's correlation values (0.995 for XO and 0.98 for RhB) indicated that both dyes' Langmuir adsorption would perform well. Furthermore, the adsorption of XO and RhB dyes on the adsorbent is confirmed to be a viable reaction by the negative values of ΔGo. The enhanced adsorbent material for the removal of amphoteric and anionic dyes from waste water is the synthesized LaZnFe2O4 supported NiWO4@D400-MMT@CMS/MMA nanocomposites, which exhibits a reusability affinity of up to five cycles.
RESUMEN
In this work, direct gas-phase epoxidation of propylene (DPO) to propylene oxide by molecular oxygen has been studied by using Ag-MoO3 supported on titanium-containing hexagonal mesoporous silica (Ti-HMS n ) of different Si/Ti molar ratios. The promotion effect of NaCl on the synthesized catalysts has also been investigated. Among the studied supports, the hexagonal mesoporous silica (HMS) with a Si/Ti ratio of 10 was the most suitable one for production of propylene oxide (PO). The optimal performance of the AgMo/Ti-HMS10 catalyst in DPO exhibited a selectivity to PO of 43.2% with a propylene conversion of 14.1%, at 400 °C, 0.1 MPa, and a space velocity of 12,000 h-1. The catalyst verified good stability over at least 20 h on stream. Only 2.7% PO selectivity with a propylene conversion of 10.1% was achieved over the AgMo/HMS sample. The incorporation of Ti into the HMS frame could optimize the particle size distribution of Ag, producing Ag nanoparticles with an average size of 6.8 nm compared with that of Ag/HMS (24.3 nm). The in situ Raman spectrum of AgMo/Ti-HMS10 heated in a stream of C3H6/He at 400 °C showed new bands at 616, 390, and 210 cm-1, characteristic of the Ag x Mo y O z intermediate phase. The obtained results suggested that this formed AgMo/Ti-HMS10 phase could most likely be relevant for selective epoxidation of propylene. However, during the reaction of C3H6 with AgMo/HMS, the formation of this intermediate was hardly detected. On the other hand, the hydrogen temperature-programmed reduction measurements indicated improved reducibility of MoO3 in the AgMo/Ti-HMS10 catalyst, which acknowledged the role of Mo6+ in gaining electrons from silver to form positively charged Ag. This could reduce the effective charge of the adsorbed oxygen on silver sites and in turn favor the epoxidation path of propylene rather than the combustion route. Also, during the reaction of C3H6 with NaAgMo/Ti-HMS10 at 400 °C, two new Raman bands were detected at 277 and 350 cm-1, characteristic of Ag2MoO4.
