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Observations of superconductivity and charge density waves (CDW) in graphene have been elusive thus far due to weak electron-phonon coupling (EPC) interactions. Here, we report a unique observation of anomalous transport and multiple charge ordering phases at high temperatures (T1â¼213K,T2â¼325K) in a 0D-2D van der Waals (vdW) heterostructure comprising of single layer graphene (SLG) and functionalized (amine) graphene quantum dots (GQD). The presence of functionalized GQD contributed to charge transfer with shifting of the Dirac point â¼ 0.05 eV above the Fermi level (ab initio simulations) and carrier densitynâ¼-0.3×1012 cm-2confirming p-doping in SLG and two-fold increase in EPC interaction was achieved. Moreover, we elucidate the interplay between electron-electron and electron-phonon interactions to substantiate high temperature EPC driven charge ordering in the heterostructure through analyses of magnetotransport and weak anti-localization (WAL) framework. Our results provide impetus to investigate strongly correlated phenomena such as CDW and superconducting phase transitions in novel graphene based heterostructures.
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To understand the possible lubricant mechanism in ceramic-on-ceramic hip joint prostheses, biochemical reactions of the synovial fluid and the corresponding frictional coefficients were studied. The experiments were performed in a hip joint simulator using the ball-on-cup configuration with balls and cups made from two types of ceramics, BIOLOX®forte and BIOLOX®delta. Different lubricants, namely albumin, γ-globulin, hyaluronic acid and three model synovial fluids, were studied in the experiments and Raman spectroscopy was used to analyze the biochemical responses of these lubricants at the interface. BIOLOX®delta surface was found less reactive to proteins and model fluid lubricants. In contrast, BIOLOX®forte ball surface has shown chemisorption with both proteins, hyaluronic acid and model fluids imitating total joint replacement and osteoarthritic joint. There was no direct correlation between the measured frictional coefficient and the observed chemical reactions. In summary, the study reveals chemistry of lubricant film formation on ceramic hip implant surfaces with various model synovial fluids and their components.
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To deal with the general problem of biomolecule specific binding analysis, we have applied the technique of difference spectra to the surface plasmon resonance (SPR)-enhanced total internal reflection ellipsometry measurement. We suggest a three-step treatment of the SPR background that can easily be integrated with the usual measurement routine. First, making use of the difference spectrum in ellipsometric angle Δ, single peak footprints of the topmost layer are obtained that facilitate its sensitive detection during film growth. Subsequently, circumventing the need for explicit knowledge of the substrate properties, the difference spectra peaks can be used for the end-point analysis of a binding. Finally, tracking the binding effectivity of the analyte we determine the injection speed and analyte concentration windows needed for successful monitoring of the film growth. We demonstrate our approach on a comprehensive two-stage binding experiment involving two biologically relevant molecules: the C-terminal domain (CTD) of RNA polymerase II and CTD-interacting domain of one of its transcription factors, the Rtt103 protein.
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ARN Polimerasa II/química , Resonancia por Plasmón de Superficie/métodos , Sitios de Unión , Unión Proteica , Dominios Proteicos , Proteínas de Saccharomyces cerevisiae/química , Factores de Transcripción/químicaRESUMEN
Miniature Surface Enhanced Raman Scattering (SERS) sensors were fabricated by coating the carbon fiber microelectrodes with copper nanowires. The coating procedure, based on anodizing the copper wire in ultrapure water followed by cathodic deposition of the anode-derived material onto carbon fiber electrodes, provides a "clean" copper nanowire network. The developed miniature (10µm in diameter and 2mm in length) and nanoscopically rough SERS substrates are applicable in drug sensing, as shown by the detection and resolving of a range of seized designer drugs in trace amounts (microliter volumes of 10-10-10-12M solutions). The copper nanowire modified carbon microfiber substrates could also find further applications in biomedical and environmental sensing.
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Técnicas Biosensibles/métodos , Carbono/química , Cobre/química , Drogas de Diseño/análisis , Electrodos , Nanocables/química , Espectrometría Raman/métodos , Fibra de Carbono , Propiedades de SuperficieRESUMEN
Synthesis of graphene by chemical vapor deposition is a promising route for manufacturing large-scale high-quality graphene for electronic applications. The quality of the employed substrates plays a crucial role, since the surface roughness and defects alter the graphene growth and cause difficulties in the subsequent graphene transfer. Here, we report on ultrasmooth high-purity copper foils prepared by sputter deposition of Cu thin film on a SiO2/Si template, and the subsequent peeling off of the metallic layer from the template. The surface displays a low level of oxidation and contamination, and the roughness of the foil surface is generally defined by the template, and was below 0.6 nm even on a large scale. The roughness and grain size increase occurred during both the annealing of the foils, and catalytic growth of graphene from methane (≈1000 °C), but on the large scale still remained far below the roughness typical for commercial foils. The micro-Raman spectroscopy and transport measurements proved the high quality of graphene grown on such foils, and the room temperature mobility of the graphene grown on the template stripped foil was three times higher compared to that of one grown on the commercial copper foil. The presented high-quality copper foils are expected to provide large-area substrates for the production of graphene suitable for electronic applications.
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This paper discusses the fundamentals, applications, potential, limitations, and future perspectives of polarized light reflection techniques for the characterization of materials and related systems and devices at the nanoscale. These techniques include spectroscopic ellipsometry, polarimetry, and reflectance anisotropy. We give an overview of the various ellipsometry strategies for the measurement and analysis of nanometric films, metal nanoparticles and nanowires, semiconductor nanocrystals, and submicron periodic structures. We show that ellipsometry is capable of more than the determination of thickness and optical properties, and it can be exploited to gain information about process control, geometry factors, anisotropy, defects, and quantum confinement effects of nanostructures.
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In the previous paper [11], a method for geometrical and transducer-time-delay auto-calibration of an ultrasonic computed tomography (USCT) system has been described, aiming at calibration of individual ultrasonic (US) transducer positions. The present contribution describes a novel modification of the method utilizing the particular USCT system concept: the exactly known spatial relations among transducers grouped in each of the transducer array systems (TASes). The algorithms used for the calibration remain based on the principles similar to the global positioning system (GPS) navigation, however, the positions and orientations of complete TASes are calibrated, rather than individual positions of transducers. This way, the number of unknowns is substantially reduced while the number of available equations remains unchanged. Consequently, a solution substantially more robust with respect to measurement noise can be obtained based on this highly overdetermined equation system. The method is capable of calibrating the individual positions of all ultrasonic transducers via their positions in TASes as well as their individual time delays at once during sc. empty measurement, without a need for any particular arrangements, e.g. calibration phantoms.
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Algoritmos , Transductores , Ultrasonografía/normas , Calibración , Simulación por Computador , Diseño de Equipo , Modelos Teóricos , Fantasmas de Imagen , Reproducibilidad de los Resultados , Procesamiento de Señales Asistido por Computador , Ultrasonografía/instrumentaciónRESUMEN
This paper presents a method for geometrical and time-delay auto-calibration of an ultrasonic computed tomography (USCT) system. The algorithms used for the calibration are based on the principles similar to the global positioning system (GPS) navigation. Ultrasonic transmitters and receivers in USCT can be viewed like satellite transmitters and mobile receiver units in GPS. However, unlike in GPS, none of the positions of the transmitters or receivers in USCT are assumed to be known and all are the to-be-calibrated unknowns. The presented method is capable of calibrating the positions of all ultrasonic transducers and their individual time delays at once. No calibration phantoms are necessary.
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Tomografía Computarizada por Rayos X/instrumentación , Ultrasonido , Ultrasonografía/instrumentación , Algoritmos , Calibración , Simulación por Computador , Diseño de Equipo , Imagenología Tridimensional/métodos , Modelos Estadísticos , Modelos Teóricos , Reconocimiento de Normas Patrones Automatizadas , Reproducibilidad de los Resultados , Procesamiento de Señales Asistido por Computador , Factores de Tiempo , Tomografía Computarizada por Rayos X/métodos , Ultrasonografía/métodosRESUMEN
The contribution deals with the first step in using proper wave-equation based ultrasound propagation model in image reconstruction from the ultrasonic computed tomography data. Particularly, it compares the transducer calibration results obtained via direct measurement of the empty image field and consequential data processing based on a simple direct-propagation model with the simulation results obtained via solving the single-frequency wave equation under proper border conditions reflecting the realistic measurement geometry. The results show a reasonable qualitative agreement when a certain degree of phase-shifted coupling from the transmitting transducer elements to the neighbouring elements of the transducer field is admitted.