RESUMEN
Highly efficient coelectrolysis of CO2/H2O into syngas (a mixture of CO/H2), and subsequent syngas conversion to fuels and value-added chemicals, is one of the most promising alternatives to reach the corner of zero carbon strategy and renewable electricity storage. This research reviews the current state-of-the-art advancements in the coelectrolysis of CO2/H2O in solid oxide electrolyzer cells (SOECs) to produce the important syngas intermediate. The overviews of the latest research on the operating principles and thermodynamic and kinetic models are included for both oxygen-ion- and proton-conducting SOECs. The advanced materials that have recently been developed for both types of SOECs are summarized. It later elucidates the necessity and possibility of regulating the syngas ratios (H2:CO) via changing the operating conditions, including temperature, inlet gas composition, flow rate, applied voltage or current, and pressure. In addition, the sustainability and widespread application of SOEC technology for the conversion of syngas is highlighted. Finally, the challenges and the future research directions in this field are addressed. This review will appeal to scientists working on renewable-energy-conversion technologies, CO2 utilization, and SOEC applications. The implementation of the technologies introduced in this review offers solutions to climate change and renewable-power-storage problems.
RESUMEN
Agricultural non-point source pollution (AGNPSP) is an important risk factor affecting the water environment. Among the areas where cropland NPSP occurs, the coastal zone should be of greater concern. Typhoons, heavy precipitation, and abundant rivers and ponds accelerate the transport process of AGNPSP to the offshore waters. It is urgent to construct a simple and accurate model to assess the risk of AGNPSP in the coastal zones. Thus, this study takes the nitrogen pollution from agricultural cultivation in the coastal zone of the Yellow River Delta as an example. A new minimum cumulative resistance (MCR) to agricultural non-point source pollution (AGNPSP-MCR) model is first proposed to simulate the transport process of cropland NPSP into the sea based on the "source-sink" theory in landscape ecology. Finally, the risk is assessed for AGNPSP transport into the sea. The results show the following. (1) The environmental factors of vegetation cover, rainfall erosivity, and soil erodibility are the three most important factors in pollution transportation, weighted 0.3433, 0.2608, and 0.2219, respectively, while the least influential factor is slope, with a weight of only 0.0053. (2) The minimum cumulative resistance of AGNPSP transportation shows a significant positive correlation with the distance to the river and sea, and is higher on the west sides away from the ocean, and smaller in the eastern coastal area near the sea. (3) Similarly, the regions facing serious AGNPSP risk are concentrated in the eastern coastal area, and the cropland area above medium risk was 252.72 km2, accounting for 47.57% of the total cultivated land area. (4) Compared with the traditional MCR model, the AGNPSP-MCR model takes into account the quantitative differences of the transport process characteristics of AGNPSP, and it is constrained by the topographical parameter, so the results of AGNPSP risk are more reliable. This study provides a new reference for risk assessments of AGNPSP in the coastal zones.
