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Org Lett
; 25(31): 5880-5884, 2023 Aug 11.
Artículo
en Inglés
| MEDLINE
| ID: mdl-37498083
RESUMEN
Bromo-functionalized B1-polycyclic aromatic hydrocarbons (PAHs) with LUMOs of less than -3.0 eV were synthesized and used in cross-couplings to form donor-acceptor materials. These materials spanned a range of S1 energies, with a number showing thermally activated delayed fluorescence and significant emission in the near-infrared region of the spectrum. These B1-PAHs represent a useful family of acceptors that can be readily synthesized and functionalized.