Adsorptive membrane separation for eco-friendly decontamination of chlorpyrifos via biochar-impregnated cellulose acetate mixed matrix membrane.

In this work, the phase inversion approach is used to synthesize a blended mixed matrix membrane from cellulose acetate polymer and sugarcane bagasse biochar. The experiments were carried out to estimate the extent of chlorpyrifos (CPS) pesticide removal. The results showed that the removal rate was more than 99% in making the filtered water suitable enough for domestic use. The physical and functional characteristics of the membranes, such as permeability, and contact angle were identified. The changes in the membrane characteristics were observed using scanning electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction both before and after the experimental trials. Experiments were conducted to assess not only the rejection characteristics of CPS, as a function feed concentration, but also the effect co-ions on the rejection used to analyze the composition both before and after filtration. The effects of initial CPS concentration, biochar loading, and co-ions on the membrane were investigated. The membranes showed contact angles between 70° and 97° and a permeability between 0.25 × 1010 m Pa-1 s-1 and 0.31 × 1010 m Pa-1 s-1. The effective removal of CPS from the contaminated aqueous stream was attributed to a combination of adsorptive uptake and membrane-based separation. CPS was found to get adsorbed onto the membrane matrix through an intraparticle diffusion mechanism along with an irreversible monolayer adsorption. The membrane-solute adsorptive interaction was represented by Langmuir isotherm and intraparticle diffusion models with a maximum adsorption capacity of 192.3 mg g-1. The findings indicated the efficacy of biochar-cellulose acetate mixed matrix membrane for sustainable and eco-friendly treatment of chlorpyrifos contaminated water.

Adsorptive removal of oxytetracycline hydrochloride using bagasse-based biochar powder and beads.

Oxytetracycline Hydrochloride (OTC), a common antibiotic used to treat specific illnesses in humans and animals, is characterized by poor absorption into cells, low volatility, and high hydrophilicity. It is a potent contaminant that poses a serious threat to the ecosystem, particularly the aquatic sources. Adsorption onto natural adsorbents is one of the most successful, economical, and ecologically friendly ways to remove antibiotics from waste water. The present work focuses on the adsorption of OTC utilizing alginate biochar beads (AlBCB) and biochar powder (BC) derived from bagasse. The influence of several factors were studies and optimized through batch studies employing BC and AlBCB. After 50 min BC displayed a removal of 97%, at an initial concentration of 10 ppm. The experimental data was discovered to follow PFO kinetics and fit with the Freundlich isotherm adsorption model. AlBCB, after a contact time of 40 min, indicated a maximum percentage removal of 86% for initial concentration of 10 ppm OTC. Al-biochar beads showed the maximum percentage removal at pH 10. 0.5 g of adsorbent was used to carry out all batch experiments at room temperature. The adsorption fitted Freundlich adsorption isotherm and intraparticle diffusion kinetics.

Global impact of COVID-19 on agriculture: role of sustainable agriculture and digital farming.

The rise and spread of the coronavirus pandemic (COVID-19) has created an imbalance in all sectors worldwide, massively disrupting the global economy. Social distancing, quarantine regulations, and strict travel restrictions have led to a major reduction in the workforce and loss of jobs across all industrial sectors. One of the sectors completely exposed was the agriculture and food sector. The initiation of a nationwide lockdown by the government resulted in the shutdown of industries globally impacting the overall supply chain from farmer to consumer. The need of the hour is to propose effective solutions which can serve the dual purpose of market growth as well as customer satisfaction. This paper reviews the impact of COVID-19 on the agro-food system and its economy stressing critical factors like food production, demand, price hikes, security, and supply chain resilience. To conserve natural resources and meet the sustainable development goals (SDG), importance has been given to adopting sustainable agricultural practices with a prime focus on techniques like urban agriculture, crop rotation, hydroponics, and family farming. Possible advancements like the use of digital tools, mainly artificial intelligence, machine learning, deep learning, and block-chain technology, in the agro-food sector have been discussed as they could be a promising tool to develop a self-reliant society. This work would be a perfect platform to understand the growing impact of the pandemic as well as supporting cost-effective solutions for a green ecosystem.

Metformin as an emerging concern in wastewater: Occurrence, analysis and treatment methods.

Metformin is a wonder drug used as an anti-hypoglycemic medication; it is also used as a cancer suppression medicament. Metformin is a first line of drug choice used by doctors for patients with type 2 diabetes. It is used worldwide where the drug's application varies from an anti-hypoglycemic medication to cancer oppression and as a weight loss treatment drug. Due to its wide range of usage, metformin and its byproducts are found in waste water and receiving aquatic environment. This leads to the accumulation of metformin in living beings and the environment where excess concentration levels can lead to ailments such as lactic acidosis or vitamin B12 deficiency. This drug could become of future water treatment concerns with its tons of production per year and vast usage. As a result of continuous occurrence of metformin has demanded the need of implementing and adopting different strategies to save the aquatic systems and the exposure to metformin. This review discuss the various methods for the elimination of metformin from wastewater. Along with that, the properties, occurrence, and health and environmental impacts of metformin are addressed. The different analytical methods for the detection of metformin are also explained. The main findings are discussed with respect to the management of metformin as an emerging contaminants and the major recommendations are discussed to understand the major research gaps.