Experimental study on evaluation and optimization of heavy metals adsorption on a novel amidoximated silane functionalized Luffa cylindrica.

This study aimed to synthesize an amidoximated Luffa cylindrica (AO-LC) bioadsorbent, and evaluate its efficiency in the adsorption of heavy metals from the aqueous solutions. For this purpose, NaOH solution was used to alkaline treatment of Luffa cylindrica (LC) fibers. The silane modification of LC was performed using 3-(trimethoxysilyl)propyl methacrylate (MPS). Polyacrylonitrile (PAN)/LC biocomposite (PAN-LC) was synthesized by PAN grafting onto the MPS-modified LC (MPS-LC). Finally, the AO-LC was obtained by the amidoximation of PAN-LC. The chemical structures, morphology, and thermal properties of biocomposites were characterized by the infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and field emission scanning electron microscopy. The results showed a successful grafting of MPS and PAN on the surface of LC. The order of heavy metals adsorption on AO-LC was: Pb2+ > Ag+ > Cu2+ > Cd2+ > Co2+ > Ni2+. The effects of operational parameters on the Pb2+ adsorption were studied using Taguchi experimental design method. Statistical analysis of the results showed that the initial Pb2+ concentration and the bioadsorbent dosage significantly affect the adsorption efficiency. The adsorption capacity and removal percentage of Pb2+ ions were obtained as 18.88 mg/g and 99.07%, respectively. The Langmuir isotherm and Pseudo-second order kinetics models were found to be better compatible with experimental data as a consequence of the isotherm and kinetics analysis.

Application of TOPSIS algorithm in describing bacterial cellulose-based composite hydrogel performance in incorporating methylene blue as a model drug.

A multi-component hydrogel was developed using bacterial cellulose, alginate, and gelatin with the aid of glycerol as trihydric alcohol which participates in re-distribution of hydrogen bonds in the test system. FTIR, XRD, SEM, and TGA as instrumental techniques were used to structurally characterize the physical/chemical properties of the formed composite hydrogel. By using an exponential equation, swelling behavior of the hydrogel was evaluated. By incorporating a model drug (methylene blue-MB) in the formed hydrogel, experiments were directed to study release characteristics of the MB where the medium solution for the release was prepared at four different pHs. The maximum cumulative drug release at pH 2.8, 6, 7.4, and 9 were 42.8, 63, 80, and 84.5%, respectively. Data fitting process was carried out using five kinetic models (Korsmeyer-Peppas, Higuchi, Hopfenberg, zero-order, and first-order equations) and the preferred kinetic model at each pH was estimated by applying TOPSIS algorithmic technique. The adsorption capacity of the hydrogel in relation to MB was determined while thermodynamic properties of this relationship were quantified ([Formula: see text] and [Formula: see text]). The results of the present study were in favor of the potential usage of the developed composite hydrogel in drug delivery systems.

Performance Comparison of Polymeric and Silica-Based Multi-Bed Pervaporation Membrane Reactors during Ethyl Levulinate Production.

A detailed numerical study of ethyl levulinate (EtLA) production with levulinic acid (LA) and ethanol (Et) in a multi-bed traditional reactor (MB-TR) and a silica-based and polymeric multi-bed pervaporation membrane reactors (MB-PVMR) was conducted and the efficiency of each design was studied under different operation conditions. Due to water production in the EtLA production process, water removal by a pervaporation system may improve process performance. Our results showed that MB-PVMR had higher performance compared with MB-TR. In addition, the silica membrane was more effective in water removal compared with the polymeric membrane. Therefore, higher LA conversion was achievable by a silica-based multi-bed pervaporation membrane reactor (SMB-PVMR). All the results were evaluated for percentage of water removal and LA conversion, based on variations in the Et/LA molar ratio, feed molar flow, reaction zone temperature, and catalyst loading. The results showed that water removal was higher than 95% and LA conversion of about 95% was attained by SMB-PVMR.

A Theoretical Analysis on a Multi-Bed Pervaporation Membrane Reactor during Levulinic Acid Esterification Using the Computational Fluid Dynamic Method.

Pervaporation is a peculiar membrane separation process, which is considered for integration with a variety of reactions in promising new applications. Pervaporation membrane reactors have some specific uses in sustainable chemistry, such as the esterification processes. This theoretical study based on the computational fluid dynamics method aims to evaluate the performance of a multi-bed pervaporation membrane reactor (including poly (vinyl alcohol) membrane) to produce ethyl levulinate as a significant fuel additive, coming from the esterification of levulinic acid. For comparison, an equivalent multi-bed traditional reactor is also studied at the same operating conditions of the aforementioned pervaporation membrane reactor. A computational fluid dynamics model was developed and validated by experimental literature data. The effects of reaction temperature, catalyst loading, feed molar ratio, and feed flow rate on the reactor's performance in terms of levulinic acid conversion and water removal were hence studied. The simulations indicated that the multi-bed pervaporation membrane reactor results to be the best solution over the multi-bed traditional reactor, presenting the best simulation results at 343 K, 2 bar, catalyst loading 8.6 g, feed flow rate 7 mm3/s, and feed molar ratio 3 with levulinic acid conversion equal to 95.3% and 91.1% water removal.

Recent Progresses in Application of Membrane Bioreactors in Production of Biohydrogen.

Biohydrogen is a clean and viable energy carrier generated through various green and renewable energy sources such as biomass. This review focused on the application of membrane bioreactors (MBRs), emphasizing the combination of these devices with biological processes, for bio-derived hydrogen production. Direct biophotolysis, indirect biophotolysis, photo-fermentation, dark fermentation, and conventional techniques are discussed as the common methods of biohydrogen production. The anaerobic process membrane bioreactors (AnMBRs) technology is presented and discussed as a preferable choice for producing biohydrogen due to its low cost and the ability of overcoming problems posed by carbon emissions. General features of AnMBRs and operational parameters are comprehensively overviewed. Although MBRs are being used as a well-established and mature technology with many full-scale plants around the world, membrane fouling still remains a serious obstacle and a future challenge. Therefore, this review highlights the main benefits and drawbacks of MBRs application, also discussing the comparison between organic and inorganic membranes utilization to determine which may constitute the best solution for providing pure hydrogen. Nevertheless, research is still needed to overcome remaining barriers to practical applications such as low yields and production rates, and to identify biohydrogen as one of the most appealing renewable energies in the future.

Experimentation and CFD modeling of continuous degradation of formaldehyde by immobilized Ralstonia eutropha in a semi-pilot-scale plug flow bioreactor.

This study focuses on continuous formaldehyde (FA) biodegradation by Ralstonia eutropha immobilized on polyurethane foam in a semi-pilot-scale plug flow packed-bed bioreactor. The stepwise increasing of the influent FA concentration from 43.9 to 1325.1 mg L-1 was studied in the bioreactor during 70 days of operation. A complete removal of FA was achieved for inlet concentration up to 425.5 mg L-1 and the initial specific biodegradation rate reached to its maximum value about 44.3 mg gcell-1 h-1 at 425.5 mg L-1. However, further increase of inlet concentration resulted in decrease of the biodegradation performance of the immobilized cells due to the inhibitory effect of FA on the enzymatic system involved in the biodegradation process. Based on kinetic modeling results, the Luong equation with the following constants could best describe the behavior of the bio-system: maximum specific FA biodegradation rate (qmax) of 124 mg gcell-1 h-1, half-saturation constant (KS) of 337.2 mg L-1, maximum degradable FA concentration (Smax) of 1582 mg L-1, and shape factor (n) of 1.49. Also, three-dimensional simulation of the bioreactor was performed using an integrated computational fluid dynamics (CFD) approach that takes into account both the biokinetic constants of the immobilized system as well as the fluid properties under steady-state condition. Eulerian computations successfully anticipated the concentration gradients through the reactor for different inlet FA concentrations, and uniform vertical velocity pathlines and non-dispersed plug flow inside the reactor were verified by the presented velocity distribution and flow streamlines.

Bioelectrochemical BTEX removal at different voltages: assessment of the degradation and characterization of the microbial communities.

BTEX compounds (Benzene, Toluene, Ethylbenzene and Xylenes) are toxic hydrocarbons that can be found in groundwater due to accidental spills. Bioelectrochemical systems (BES) are an innovative technology to stimulate the anaerobic degradation of hydrocarbons. In this work, single chamber BESs were used to assess the degradation of a BTEX mixture at different applied voltages (0.8V, 1.0V, 1.2V) between the electrodes. Hydrocarbon degradation was linked to current production and to sulfate reduction, at all the tested potentials. The highest current densities (about 200mA/m2 with a maximum peak at 480mA/m2) were observed when 0.8V were applied. The application of an external voltage increased the removal of toluene, m-xylene and p-xylene. The highest removal rate constants at 0.8V were: 0.4±0.1days-1, 0.34±0.09days-1 and 0.16±0.02days-1, respectively. At the end of the experiment, the microbial communities were characterized by high throughput sequencing of the 16S rRNA gene. Microorganisms belonging to the families Desulfobulbaceae, Desulfuromonadaceae and Geobacteraceae were enriched on the anodes suggesting that both direct electron transfer and sulfur cycling occurred. The cathodic communities were dominated by the family Desulfomicrobiaceae that may be involved in hydrogen production.

Photocatalytic Degradation of p-Nitrophenol in an Annular Column Photoreactor and the Intermediates.

The photocatalytic degradation of p-nitrophenol using a titanium dioxide suspension was studied in an annular column photoreactor operating in batch recycle mode with an aerated reservoir tank. The dependency of the process efficiency on the initial PNP concentration was quantitatively defined using an exponential function. The degradation rate was highest at pH 7-7.2. The appearance of p-benzoquinone, p-hydroquinone, and phenol during the degradation process was confirmed by high-performance liquid chromatography analysis. The formation of similar intermediates during the microbial degradation of PNP has been reported previously. The formation of hydroxyl. radicals is predominant in the PNP photodegradation route, and fluctuations of the chemical oxygen demand may be indicative of the appearance of unidentified and probably nonbiodegradable intermediates formed during photocatalysis. These compounds likely contribute to the COD variations. Herein, the results of PNP removal via photocatalytic degradative reactions are discussed, and the intermediates are compared to those observed in enzymatic reactions.

Use of a packed-bed airlift reactor with net draft tube to study kinetics of naphthalene degradation by Ralstonia eutropha.

Biodegradation of naphthalene by Ralstonia eutropha (also known as Cupriavidus necator) in a packed-bed airlift reactor with net draft tube (PBALR-nd) was studied; the Kissiris pieces were the packing material. The reactor hydrodynamics has been characterized under abiotic conditions and the dependencies of the superficial gas velocity (U G) on the gas holdup (εG), liquid mixing time, and mass transfer coefficient were determined. The improving role of the net draft tube in this small column reactor (height 42 cm, ID 5 cm) was confirmed. The flow regime was described using the εG α U G (n) expression, and bubbly flow was observed in PBALR-nd at U G < 2.83 cm/s. In the second step of the present work, the kinetics of biodegradation was modeled using the Haldane and Aiba equations. The fitting of the experimental results to the models were done according to the nonlinear least square regression technique. The biokinetic constants (q m, K s, and K i) were estimated and q m as the specific biodegradation rate was equaled to 0.415 and 0.24 mgnaph./mgcell h for the Haldane and Aiba equations, respectively. The goodness of fit reported as R (2) and root-mean-square error (RMSE) showed the adequate fitness of the Haldane and Aiba models in predicting naphthalene biodegradation kinetics. On the basis of the HPLC results, a hypothetical pathway for the biodegradation was presented.