Improvement of bio-based polyurethane and its optimal application in controlled release fertilizer.

In the past decades, polyurethane has emerged as a new material that has been widely developed and applied in coated controlled release fertilizers (CRFs). Particularly in recent years, the excessive consumption of petroleum resources and increasing demand for sustainable development have resulted in considerable interest in bio-based polyurethane coated controlled-release fertilizers. This review article focuses on the application and progress of environmentally friendly bio-based materials in the polyurethane-coated CRF industry. We also explore prospects for the green and sustainable development of coated CRFs. Using animal and plant oils, starch, lignin, and cellulose as raw materials, polyols can be produced by physical, chemical, and biological means to replace petroleum-based materials and polyurethane film coating for CRFs can be prepared. Various modifications can also improve the hydrophobicity and degradability of polyurethane film. A growing body of research on bio-based polyurethane has revealed its great potential in the production and application of coated CRFs. The purpose of this review is to highlight the practicality of bio-based materials in the application of polyurethane-coated CRFs and to clarify their current limitations.

Mineral-Soil-Plant-Nutrient Synergisms of Enhanced Weathering for Agriculture: Short-Term Investigations Using Fast-Weathering Wollastonite Skarn.

Enhanced weathering is a proposed carbon dioxide removal (CDR) strategy to accelerate natural carbon sequestration in soils via the amendment of silicate rocks to agricultural soils. Among the suitable silicates (such as basalt and olivine), the fast-weathering mineral wollastonite (CaSiO3) stands out. Not only does the use of wollastonite lead to rapid pedogenic carbonate formation in soils, it can be readily detected for verification of carbon sequestration, but its weathering within weeks to months influences soil chemistry and plant growth within the same crop cycle of its application. This enables a variety of short-term experimental agronomic studies to be conducted to demonstrate in an accelerated manner what could take years to be observed with more abundant but slower weathering silicates. This study presents the results of three studies that were conducted to investigate three distinct aspects of wollastonite skarn weathering in soils in the context of both agricultural and horticultural plants. The first study investigated the effect of a wide range of wollastonite skarn dosages in soil (1.5-10 wt.%) on the growth of green beans. The second study provides insights on the role of silicon (Si) release during silicate weathering on plant growth (soybeans and lettuce). The third study investigated the effect of wollastonite skarn on the growth of spring rye when added to soil alongside a nitrogen-based coated fertilizer. The results of these three studies provide further evidence that amending soil with crushed silicate rocks leads to climate-smart farming, resulting in inorganic carbon sequestration, as well as better plant growth in agricultural (soybean and spring rye) and horticultural (green bean and lettuce) crops. They also demonstrate the value of working with wollastonite skarn as a fast-weathering silicate rock to accelerate our understanding of the mineral-soil-plant-nutrient synergism of enhanced weathering.

Controlled release fertilizers (CRFs) for climate-smart agriculture practices: a comprehensive review on release mechanism, materials, methods of preparation, and effect on environmental parameters.

Fertilizers play an essential role in increasing crop yield, maintaining soil fertility, and provide a steady supply of nutrients for plant requirements. The excessive use of conventional fertilizers can cause environmental problems associated with nutrient loss through volatilization in the atmosphere, leaching to groundwater, surface run-off, and denitrification. To mitigate environmental issues and improve the longevity of fertilizer in soil, controlled release fertilizers (CRFs) have been developed. The application of CRFs can reduce the loss of nutrients, provide higher nutrient use efficiency, and improve soil health simultaneously to achieve the goals of climate-smart agricultural (CSA) practices. The major findings of this review paper are (1) CRFs can prevent direct exposure of fertilizer granule to soil and prevent loss of nutrients such as nitrate and nitrous oxide emissions; (2) CRFs are less affected by the change in environmental parameters, and that can increase longevity in soil compared to conventional fertilizers; and (3) CRFs can maintain required soil nitrogen levels, increase water retention, reduce GHG emissions, lead to optimum pH for plant growth, and increase soil organic matter content. This paper could give good insights into the ongoing development and future perspectives of CRFs for CSA practices.