RESUMEN
A method to optimize the thermal deformation of an indirectly cryo-cooled silicon crystal monochromator exposed to intense X-rays at a low-emittance diffraction-limited synchrotron radiation source is presented. The thermal-induced slope error of the monochromator crystal has been studied as a function of heat transfer efficiency, crystal temperature distribution and beam footprint size. A partial cooling method is proposed, which flattens the crystal surface profile within the beam footprint by modifying the cooling contact area to optimize the crystal peak temperature. The optimal temperature varies with different photon energies, which is investigated, and a proper cooling strategy is obtained to fulfil the thermal distortion requirements over the entire photon energy range. At an absorbed power up to 300â W with a maximum power density of 44.8â Wâ mm-2 normal incidence beam from an in-vacuum undulator, the crystal thermal distortion does not exceed 0.3â µrad at 8.33â keV. This method will provide references for the monochromator design on diffraction-limited synchrotron radiation or free-electron laser light sources.
RESUMEN
Passive daytime radiative cooling (PDRC) technology provides an eco-friendly cooling strategy by reflecting sunlight reaching the surface and radiating heat underneath to the outer space through the atmospheric transparency window. However, PDRC materials face challenges in cooling performance degradation caused by outdoor contamination and requirements of easy fabrication approaches for scale-up and high cooling efficiency. Herein, a polymer composite coating of polystyrene, polydimethylsiloxane and poly(ethyl cyanoacrylate) (PS/PDMS/PECA) with superhydrophobicity and radiative cooling performance was fabricated and demonstrated to have sustained radiative cooling capability, utilizing the superhydrophobic self-cleaning property to maintain the optical properties of the coating surface. The prepared coating is hierarchically porous which exhibits an average solar reflectance of 96% with an average emissivity of 95% and superhydrophobicity with a contact angle of 160°. The coating realized a subambient radiative cooling of 12.9 °C in sealed air and 7.5 °C in open air. The self-cleaning property of the PS/PDMS/PECA coating helped sustain the cooling capacity for long-term outdoor applications. Moreover, the coating exhibited chemical resistance, UV resistance, and mechanical durability, which has promising applications in wider fields.
RESUMEN
A self-amplified spontaneous emission free-electron laser (FEL) is under construction at the Shanghai Soft X-ray Free-Electron Facility. Therefore, it is necessary to develop a suitable diagnostic tool capable of resolving the natural emission band of each FEL pulse. Thus, an online spectrometer with a plane mirror and plane variable-line-spacing grating at grazing incidence to monitor each single FEL pulse during the propagation of FEL radiation has been designed and is presented in this work. The method of ray tracing is used for monitoring incident radiation in order to understand spectral characteristics, and SHADOW, an X-ray optics simulation tool, and SRW, an X-ray optics wavefront tool, are applied to study the resolving power and focusing properties of the grating. The designed resolving power is â¼3 × 104 at 620â eV. Meanwhile, the effect of the actual slope error of mirrors on the ray-tracing results is also discussed. In order to provide further optimization for the choice of grating, a comparison of resolving powers between 2000â linesâ mm-1 and 3000â linesâ mm-1 gratings at different energies is analyzed in detail and radiation damage of mirrors as well as parameters such as the first-order diffraction angle ß, the exit-arm length r2, and the tilt angle θ between the focal plane and the diffraction arm are studied and optimized. This work has provided comprehensive designing methods and detailed data for the design of diagnostic spectrometers in soft X-ray FELs and will be favorable to the design of other similar instruments.
RESUMEN
Robustness of superhydrophobic materials has been gradually taken into consideration for practical applications; however, little attention has been paid to the impact resistance of the superhydrophobicity of the materials. The present study demonstrated a new route for improving the mechanical durability, especially the impact resistance, of the superhydrophobic materials. First, poly(styrene-co-butadiene)/poly(ethylene-vinyl acetate) (SBR/EVA) composite monoliths with microscale cellular structures were manufactured by vulcanization-foaming processes. Then the composite monoliths were treated with sandpaper to create nanostructures above the revealed micropores after removing the uppermost skin, forming micro/nanotextured surfaces and giving improvements in superhydrophobicity. Due to the elastomeric nature of SBR and EVA, the superhydrophobicity of the monoliths can be maintained even while the material is mechanically impacted or compressed, and wearing helps improvement or recovery of the superhydrophobicity because of the self-similarity of the cellular structure inside the monoliths. Additionally, the obtained superhydrophobic materials are resistant to acidic, alkali, and salt liquors as well as organic solvents and have easy healing capacity of superhydrophobicity with a simple sanding treatment when destroyed by exposure to oxygen plasma.
RESUMEN
Sulfur (S) cross-linking styrene butadiene rubber (SBR) foams show high shrinkage due to the cure reversion, leading to reduced yield and increased processing cost. In this paper, double cross-linking system by S and dicumyl peroxide (DCP) was used to decrease the shrinkage of SBR foams. Most importantly, the synergy of double cross-linking agents was reported for the first time to our knowledge. The cell size and its distribution of SBR foams were investigated by FESEM images, which show the effect of DCP content on the cell structure of the SBR foams. The relationships between shrinkage and crystalline of SBR foams were analyzed by the synergy of double cross-linking agents, which were demonstrated by FTIR, Raman spectra, XRD, DSC and TGA. When the DCP content was 0.6 phr, the SBR foams exhibit excellent physical and mechanical properties such as low density (0.223 g/cm3), reduced shrinkage (2.25%) and compression set (10.96%), as well as elevated elongation at break (1.78 × 103%) and tear strength (54.63 N/mm). The results show that these properties are related to the double cross-linking system of SBR foams. Moreover, the double cross-linking SBR foams present high electromagnetic interference (EMI) shielding properties compared with the S cross-linking SBR foams.
RESUMEN
Eiseniafoetida was selected to investigate the ecotoxicological effects of chlorotetracycline on the earthworm in soil. The results showed that 1, 10 and 100 mg · kg(-1) chlorotetracycline had no significant effects on earthworm's body mass after a 7-d exposure, but it was significantly inhibited by 10, 100 mg · kg(-1) chlorotetracycline after 21 days. The soluble protein content of earthworm was induced by 1, 10 and 100 mg · kg(-1) chlorotetracycline, and showed a positive response as the con- centration increased. Also, the earthworm treated by 1, 10 and 100 mg · kg(-1) chlorotetracycline induced the increases of SOD, POD and CAT activities to different degrees. The gene expression in earthworm changed significantly after a 28-d exposure. It is suggested that chlorotetracycline had a chronic ecotoxicological effect on earthworm, and the body mass, soluble protein, antioxidant en- zyme and gene expression could be used as the biomarkers to estimate chlorotetracycline toxicity.
Asunto(s)
Clortetraciclina/toxicidad , Oligoquetos/efectos de los fármacos , Contaminantes del Suelo/toxicidad , Animales , Biomarcadores , Ecotoxicología , SueloRESUMEN
AIM: To assess the efficacy of hemoperfusion (HP) in the treatment of the patients with acute severe dichlorvos (DDVP) poisoning. METHODS: One hundred and eight patients with acute severe DDVP poisoning in the two teaching hospitals were enrolled. Sixty-seven patients were treated with HP (HP group) and forty-one patients accepted traditional treatment only as the control. Serum concentration of DDVP was determined by gas chromatography. RESULTS: The duration of coma, impaired consciousness, ICU stay, and mechanical ventilation was significantly shorter in the HP group than that in the control. The cumulative dosages (mg) of atropine required either in the first 24 h on admission (442+/-436 vs 899+/-485 in the control, P<0.01) or within the hospital (568+/-574 vs 1228+/-982 in the control, P<0.01) were markedly reduced in the HP patients. The lower incidence of mechanical ventilation required (13.4 % vs 36.6 % P<0.01), respiratory muscular paralysis (4.5 % vs 17.1 %, P<0.05) and the lower mortality of death (7.5 % vs 34.1 %, P<0.01) were observed in the HP group. HP could accelerate the recovery of suppressed cholinesterase activity. After the procedure, the DDVP level was decreased from (11+/-4) to (7+/-3) mg/L in parallel with a decline in APACHE II Score or dopamine dose and a rise in Glasgow Coma Scale (P<0.05). In addition, the mean values of peak clearance and reduction rate were (87+/-17) mL/min and 44 %+/-11 %, respectively. CONCLUSION: The rapid fall in blood DDVP level and the dramatic clinical response suggest that HP is effective in the treatment of acute severe DDVP poisoning.