RESUMEN
Porous spindle-knot structures have been found in many creatures, such as spider silk and the root of the soybean plant, which show interesting functions such as droplet collection or biotransformation. However, continuous fabrication of precisely controlled porous spindle-knots presents a big challenge, particularly in striking a balance among good structural controllability, low-cost, and functions. Here, we propose a concept of a fiber-microfluidics phase separation (FMF-PS) strategy to address the above challenge. This FMF-PS combines the advantages of a microchannel regulated Rayleigh instability of polymer solution coated onto a fiber with the nonsolvent-induced phase separation of the polymer solution, which enables continuous and cost-effective production of porous spindle-knot fiber (PSKF) with well-controlled size and porous structures. The critical factors controlling the geometry and the porous structures of the spindle-knot by FMF-PS have been systematically investigated. For applications, the PSKF exhibited faster water droplet nucleation, growth, and maximum water collection capability, compared to the control samples, as revealed by in situ water collection growth curves. Furthermore, high-level fabrics of the PSKFs, including a two-dimensional network and three-dimensional architecture, have been demonstrated for both large-scale water collection and art performance. Finally, the PSKF is demonstrated as a programmable building block for surface nanopatterning.
RESUMEN
A polymer separator plays a pivotal role in battery safety, overall electrochemical performance, and cell assembly process. Traditional separators are separately produced from the electrodes and dominated by porous polyolefin thin films. In spite of their commercial success, today's separators are facing growing challenges with the increasing demand on the device safety and performance. As an attempt to address this urgent need, here, we propose a concept of in situ separator technology by manipulating the two-dimensional (2D) microfluid nanophase separation (2D-MFPS) of a poly(vinylidene difluoride)/lithium salt solution during drying. Particularly, nanophase separation is effectively regulated by low humidity, salt type, and compositions. For application studies, this 2D-MFPS is directly performed onto commercial electrodes under drying conditions with low humidity to fabricate a high-performance in situ separator with thickness and porous structures comparable to those of commercial Celgard separators. This in situ separator shows superior performance in high-temperature stability and wetting capability to a variety of liquid electrolytes. Finally, pouch cells with this in situ separator technology are successfully assembled with an extremely simplified separator-stacking-free process and demonstrate stable cycle performance due to the well-controlled porous structures and electrode-separator interface.
