RESUMEN
Achieving atomic precision in nanostructured materials is essential for comprehending formation mechanisms and elucidating structure-property relationships. Within the realm of nanoscience and technology, atomically precise ligand-protected noble metal nanoclusters (NCs) have emerged as a rapidly expanding area of interest. These clusters manifest quantum confinement-induced optoelectronic, photophysical, and chemical properties, along with remarkable catalytic capabilities. Among coinage metals, silver distinguishes itself for the fabrication of stable nanoclusters, primarily due to its cost-effectiveness compared to gold. This minireview provides an overview of recent advancements since 2020 in synthetic methodologies and ligand selections toward attaining NCs boasting a minimum of two free valence electrons. Additionally, it explores strategies for fine-tuning optical properties. The discussion extends to surface reactivity, elucidating how exposure to ligands, heat, and light induces transformations in size and structure. Of paramount significance are the applications of silver NCs in catalytic reactions for energy and chemical conversion, supplemented by in-depth mechanistic insights. Furthermore, the review delineates challenges and outlines future directions in the NC field, with an eye toward the design of new functional materials and prospective applications in diverse technologies, including optoelectronics, energy conversion, and fine chemical synthesis.
RESUMEN
The assembly of cluster units in a distinct manner can give rise to nanoclusters exhibiting unique geometrical structures and properties. Herein, we present a one-pot synthesis and structural characterization of a AuAg alloy cluster, [Au9Ag6(CîCR)10(DPPM)2Cl2](PPh4), denoted as Au9Ag6 (where HCîCR is 3,5-bis(trifluoromethyl)phenylacetylene, and DPPM is bis(diphenylphosphino)methane). Single-crystal X-ray diffraction data analysis reveals that Au9Ag6 features a distinctive Au7Ag6 bi-decahedral core, formed by a twisted assembly of two Au4Ag3 decahedra sharing one vertex. The Au4Ag3 building blocks are bridged by two gold atoms on opposite sides of the bi-decahedral core. The Au9Ag6 cluster is monoanionic and it is stabilized by two chloride, two DPPM and ten alkynyl ligands. This cluster represents the first instance of a cluster of clusters built upon decahedral units.
RESUMEN
Manipulating the atomic-level structure of the subshell of a nanocluster while preserving the inner and outer shell structure is challenging. We present the synthesis and molecular structure of an alkynyl-protected Au34Ag27 nanocluster, which exhibits distinct third shell atomic arrangement, electronic structure, and optical properties from those of the Au34Ag28 nanocluster.
