RESUMEN
The traditional textile use of wool as a valuable renewable material needs alternative applications in order to, besides sheep milk and meat, valorize currently unnecessary wool. Each type of product containing sheep wool requires wool with customized properties. Finding suitable physical and chemical modifications needed to develop new products while minimizing harmful side effects is a challenge for scientists. The presented review provides a brief overview of works published over the last decade associated with innovative wool scouring, dyeing, antifelting, and modification of its structure without the ambition to present complete, detailed data.
RESUMEN
In this work, the effect of prewetting native and electron beam-modified wool on the resulting sorption of Cu(II) from wool solutions was studied. The following conditions and combinations were applied: 6 mM and 50 mM solutions, prewetting time 0-24 h, contact time 1-24 h. The sorption results showed that wetting the wool before sorption from the low concentrated solution can fundamentally improve the efficiency of the separation process. The opposite result was achieved when applying a more concentrated solution; that is, prewetting slightly reduced the sorptivity. The reasons for such results are discussed. The application of these findings can be used to optimize the separation process in technological practice, however, will require solute specification.
RESUMEN
Sheep wool irradiated by an electron beam was tested for adsorption of Cr(III) and Cu(II) from binary solutions within the same concentration of each cation from 15 to 35 mmol·dm-3. The wool sorptivity examination was aimed at searching the effect of the dose absorbed by wool on simultaneous sorption of these cations due to surface and bulk changes. The partners affected each other under these conditions. In the whole concentration range, the sorptivity of nonirradiated wool (0 kGy) for Cu(II) fluctuated within the range of 14.5-20.7 mg·g-1, while sorptivity for Cr(III) ranged from 14.8 to 7.5 mg·g-1. However, sorptivity for Cu(II) was always superior to Cr(III). At a 24 kGy dose, the wool sorptivity for both cations decreased approximately by half and tended to converge, whereby at 20 mmol·dm-3, a slight predominance for Cr(III) was already observed. However, the sorptivity of 100 kGy dosed wool acquired a clear predominance for Cr(III) over Cu(II) in the entire concentration range, showing some leveling around 14.5 mg·g-1. Sorptivity for Cu(II) was suppressed and increased nonlinearly with concentrations from 1.7 to 10.2 mg·g-1. It was concluded that optimally dosed wool could provide a special adsorbent suitable to control preferential sorption of some cations from binary solutions.
