1.
Chem Commun (Camb)
; 49(11): 1109-11, 2013 Feb 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-23282950
RESUMEN
A V(III) thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V(III)-Cl species (major one) and a V(IV) binding to a CH(2) containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.