MOFs-Derived Strategy and Ternary Alloys Regulation in Flower-Like Magnetic-Carbon Microspheres with Broadband Electromagnetic Wave Absorption.

Broadband electromagnetic (EM) wave absorption materials play an important role in military stealth and health protection. Herein, metal-organic frameworks (MOFs)-derived magnetic-carbon CoNiM@C (M = Cu, Zn, Fe, Mn) microspheres are fabricated, which exhibit flower-like nano-microstructure with tunable EM response capacity. Based on the MOFs-derived CoNi@C microsphere, the adjacent third element is introduced into magnetic CoNi alloy to enhance EM wave absorption performance. In term of broadband absorption, the order of efficient absorption bandwidth (EAB) value is Mn > Fe = Zn > Cu in the CoNiM@C microspheres. Therefore, MOFs-derived flower-like CoNiMn@C microspheres hold outstanding broadband absorption and the EAB can reach up to 5.8 GHz (covering 12.2-18 GHz at 2.0 mm thickness). Besides, off-axis electron holography and computational simulations are applied to elucidate the inherent dielectric dissipation and magnetic loss. Rich heterointerfaces in CoNiMn@C promote the aggregation of the negative/positive charges at the contacting region, forming interfacial polarization. The graphitized carbon layer catalyzed by the magnetic CoNiMn core offered the electron mobility path, boosting the conductive loss. Equally importantly, magnetic coupling is observed in the CoNiMn@C to strengthen the magnetic responding behaviors. This study provides a new guide to build broadband EM absorption by regulating the ternary magnetic alloy.

Visualizing Nanoscale Interlayer Magnetic Interactions and Unconventional Low-Frequency Behaviors in Ferromagnetic Multishelled Structures.

Precise manipulation of van der Waals forces within 2D atomic layers allows for exact control over electron-phonon coupling, leading to the exceptional quantum properties. However, applying this technique to diverse structures such as 3D materials is challenging. Therefore, investigating new hierarchical structures and different interlayer forces is crucial for overcoming these limitations and discovering novel physical properties. In this work, a multishelled ferromagnetic material with controllable shell numbers is developed. By strategically regulating the magnetic interactions between these shells, the magnetic properties of each shell are fine-tuned. This approach reveals distinctive magnetic characteristics including regulated magnetic domain configurations and enhanced effective fields. The nanoscale magnetic interactions between the shells are observed and analyzed, which shed light on the modified magnetic properties of each shell, enhancing the understanding and control of ferromagnetic materials. The distinctive magnetic interaction significantly boosts electromagnetic absorption at low-frequency frequencies used by fifth-generation wireless devices, outperforming ferromagnetic materials without multilayer structures by several folds. The application of magnetic interactions in materials science reveals thrilling prospects for technological and electronic innovation.

The activation of oxygen through oxygen vacancies in BiOCl/PPy to inhibit toxic intermediates and enhance the activity of photocatalytic nitric oxide removal.

Photocatalysis is regarded as a promising technology for indoor air purification. Despite much effort, the inhibition of toxic intermediates and the promotion of nitric oxide (NO) oxidation activity still limit real applications due to catalyst design constraints. In order to circumvent this issue, oxygen vacancies were fabricated through a strong interaction between BiOCl and polypyrrole (PPy) based on computational predictions. Oxygen vacancies worked as sites to activate O2 molecules, and the relative barrier energies of NO oxidation were significantly reduced due to the O2 activation process. With the oxygen vacancy modification, the oxidizability of BiOCl was improved, and the generation of the superoxide radical (˙O2-) was promoted on BiOCl/PPy, while the hydroxyl radical (˙OH) remained unchanged under visible light irradiation. As a result, the efficiency of NO oxidation increased from 12% to 28%, while the NO2 production was inhibited completely. Finally, in situ diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) investigations were conducted to shed light on the mechanism of the NO oxidation process. This work provides an in-depth understanding of the interaction between oxygen vacancies and O2 during the NO oxidation process, which offers a scheme to control the oxidation reaction.