Decoding Active Sites for Highly Efficient Semihydrogenation of Acetylene in Palladium-Copper Nanoalloys.

Accurately decoding the three-dimensional atomic structure of surface active sites is essential yet challenging for a rational catalyst design. Here, we used comprehensive techniques combining the pair distribution function and reverse Monte Carlo simulation to reveal the surficial distribution of Pd active sites and adjacent coordination environment in palladium-copper nanoalloys. After the fine-tuning of the atomic arrangement, excellent catalytic performance with 98% ethylene selectivity at complete acetylene conversion was obtained in the Pd34Cu66 nanocatalysts, outperforming most of the reported advanced catalysts. The quantitative deciphering shows a large number of active sites with a Pd-Pd coordination number of 3 distributed on the surface of Pd34Cu66 nanoalloys, which play a decisive role in highly efficient semihydrogenation. This finding not only opens the way for guiding the precise design of bimetal nanocatalysts from atomic-level insight but also provides a method to resolve the spatial structure of active sites.

Fe(OH)x modified ultra-small Ru nanoparticles for highly efficient hydrogen evolution reaction and its application in water splitting.

Developing highly active electrocatalysts for overall water splitting is of remarkable significance for industrial production of H2. Herein, exceptionally active Fe(OH)x modified ultra-small Ru nanoparticles on Ni(OH)2 nanosheets array (Fe(OH)x-Ru/Ni(OH)2) for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are reported. The Fe(OH)x-Ru/Ni(OH)2 nanosheets array prepared with Fe/Ru molar ratio of 5 only requires extremely low overpotentials of 61, 127 and 170 mV to reach current densities of 100, 500 and 800 mA cm-2 in 1 M KOH, respectively, exceeding Pt/C catalyst (75, 160 and 177 mV). Meanwhile, the Fe(OH)x/Ni(OH)2 nanosheets array derived from Fe(OH)x-Ru/Ni(OH)2 exhibits excellent OER activity. It gains current densities of 100, 500 and 800 mA cm-2 at considerably low overpotentials of 265, 285 and 296 mV, respectively, much lower than those of RuO2 and most reported electrocatalysts. The introduction of Fe(OH)x significantly improves the HER activity of Ru nanoparticles by tunning the electronic structure and forming interfaces between Ru and Fe(OH)x. Dramatically, the integrated alkaline electrolyzer based on Fe(OH)x-Ru/Ni(OH)2 and Fe(OH)x/Ni(OH)2 nanosheets array pair just needs 1.649 V to yield a current density up to 500 mA cm-2, exceeding most reported water-splitting electrocatalysts. The strategy reported in this work can be facilely extended to prepare other similar Ru based materials and their derivatives with outstanding catalytic performance for water splitting.

Facile preparation of Au-loaded mesoporous In2O3 nanoparticles with improved ethanol sensing performance.

The in situ monitoring of toxic volatile organic compound gases using metal oxide-based gas sensors is still challenging. Herein, mesoporous In2O3 nanoparticles, assembled using smaller nanoparticles, were synthesized via a facile solvothermal method and used to load Au nanoparticles to prepare mesoporous Au/In2O3 for ethanol detection. The obtained In2O3 and Au/In2O3 were meticulously analysed by XRD, SEM, BET, TEM and XPS techniques. It was revealed that Au nanoparticles were uniformly distributed on mesoporous In2O3 nanoparticles. Notably, the obtained mesoporous 1% Au/In2O3 is highly sensitive to ethanol gas at an optimal working temperature of 180 °C, showing a response of 55 to 50 ppm of ethanol, which is considerably higher compared to that of In2O3 nanoparticles. The significantly enhanced sensitivity results from the electronic and chemical sensitization effects of Au nanoparticles. Moreover, the mesoporous Au/In2O3 nanoparticles also showed eminent selectivity, short response/recovery time, low detection limit, good linear relationship, superb repeatability, and wonderful long-term stability, suggesting that Au/In2O3 nanoparticles have great potential application for in situ monitoring of ethanol gas.

Atomic Three-Dimensional Investigations of Pd Nanocatalysts for Acetylene Semi-hydrogenation.

Deciphering the three-dimensional (3D) insight into nanocatalyst surfaces at the atomic level is crucial to understanding catalytic reaction mechanisms and developing high-performance catalysts. Nevertheless, better understanding the inherent insufficiency of a long-range ordered lattice in nanocatalysts is a big challenge. In this work, we report the local structure of Pd nanocatalysts, which is beneficial for demonstrating the shape-structure-adsorption relationship in acetylene hydrogenation. The 5.27 nm spherical Pd catalyst (Pdsph) shows an ethylene selectivity of 88% at complete acetylene conversion, which is much higher than those of the Pd octahedron and Pd cube and superior to other reported monometallic Pd nanocatalysts so far. By virtue of the local structure revelation combined with the atomic pair distribution function (PDF) and reverse Monte Carlo (RMC) simulation, the atomic surface distribution of the unique compressed strain of Pd-Pd pairs in Pdsph was revealed. Density functional theory calculations verified the obvious weakening of the ethylene adsorption energy on account of the surface strain of Pdsph. It is the main factor to avoid the over-hydrogenation of acetylene. The present work, entailing shape-induced surface strain manipulation and atomic 3D insight, opens a new path to understand and optimize chemical activity and selectivity in the heterogeneous catalysis process.

Multi-omics analysis of the oncogenic role of optic atrophy 1 in human cancer.

OBJECTIVE: To investigate the prognostic significance of optic atrophy 1 (OPA1) in pan-cancer and analyze the relationship between OPA1 and immune infiltration in cancer. RESULTS: OPA1 exhibited high expression levels or mutations in various types of tumor cells, and its expression levels were significantly correlated with the survival rate of tumor patients. In different tumor tissues, there was a notable positive correlation between OPA1 expression levels and the infiltration of cancer-associated fibroblasts in the immune microenvironment. Additionally, OPA1 and its related genes were found to be involved in several crucial biological processes, including protein phosphorylation, protein import into the nucleus, and protein binding. CONCLUSION: OPA1 is highly expressed or mutated in numerous tumors and is strongly associated with protein phosphorylation, patient prognosis, and immune cell infiltration. OPA1 holds promise as a novel prognostic marker with potential clinical utility across various tumor types. METHODS: We examined OPA1 expression in pan-cancer at both the gene and protein levels using various databases, including Tumor Immune Estimation Resource 2.0 (TIMER 2.0), Gene Expression Profiling Interactive Analysis (GEPIA2), UALCAN, and The Human Protein Atlas (HPA). We utilized the Kaplan-Meier plotter and GEPIA datasets to analyze the relationship between OPA1 expression levels and patient prognosis. Through the cBioPortal database, we detected OPA1 mutations in tumors and examined their relationship with patient prognosis. We employed the TIMER 2.0 database to explore the correlation between OPA1 expression levels in tumor tissue and the infiltration of cancer-associated fibroblasts in the immune microenvironment. Furthermore, we conducted a gene search associated with OPA1 and performed enrichment analysis to identify the main signaling pathways and biological processes linked to them.

Metal-Organic Framework-Derived Ni-S/C Catalysts for Selective Alkyne Hydrogenation.

A carbon matrix-supported Ni catalyst with surface/subsurface S species is prepared using a sacrificial metal-organic framework synthesis strategy. The resulting highly dispersed Ni-S/C catalyst contains surface discontinuous and electron-deficient Niδ+ sites modified by p-block S elements. This catalyst proved to be extremely active and selective for alkyne hydrogenation. Specifically, high intrinsic activity (TOF = 0.0351 s-1) and superior selectivity (>90%) at complete conversion were achieved, whereas an analogous S-free sample prepared by the same synthetic route performed poorly. That is, the incorporation of S in Ni particles and the carbon matrix exerts a remarkable positive effect on catalytic behavior for alkyne hydrogenation, breaking the activity-selectivity trade-off. Through comprehensive experimental studies, enhanced performance of Ni-S/C was ascribed to the presence of discontinuous Ni ensembles, which promote desorption of weakly π-bonded ethylene and an optimized electronic structure modified via obvious p-d orbital hybridization.

NiFe-LDH-Decorated Ti-Doped Hematite Photoanode for Enhancing Solar Water-Splitting Efficiency.

Ti-doped α-Fe2O3 nanorods were prepared by a facile hydrothermal method, followed by a NiFe-LDH catalyst that was electrodeposited on the doped α-Fe2O3 nanorods to structure an integrating photoanode Ti:Fe2O3/NiFe-LDH for improving solar PEC water-splitting efficiency. The structure and properties of electrode materials were characterized and the PEC properties of photoanodes were measured. The results show that the photocurrent density of the photoanode enhances 11.25 times at 1.23 V (vs RHE) and the IPCE value enhances 4.10 times at 420 nm compared with pristine α-Fe2O3. The enhancement is attributed to the separating of photogenerated electron-hole, the increase of carrier density, and the acceleration of the carrier transfer rate due to the dual action of doping and catalysis.

Bi nanoparticles modified the WO3/ZnWO4 heterojunction for photoelectrochemical water splitting.

The novel ternary photoanode was successfully prepared by Bi nanoparticles (Bi NPs) modified on type II heterojunction of WO3-ZnWO4 using the simple and effective drop casting and chemical impregnation methods. The photoelectrochemical (PEC) experimental tests revealed that the photocurrent density of the ternary photoanode of WO3/ZnWO4(2)/Bi NPs reaches 3.0 mA/cm2 at 1.23 V (vs. RHE), which is 6 times of the WO3 photoanode. The incident photon-to-electron conversion efficiency (IPCE) at 380 nm wave length reaches 68%, which increases 2.8 times compared to WO3 photoanode. The observed enhancement can be attributed to the formation of type II heterojunction and modification of Bi NPs. The former broadens the absorption range for visible light and improves the carrier separation efficiency, while the latter enhances the light capture ability through the local surface plasmon resonance (LSPR) effect of Bi NPs and the generation of hot electrons.

NiFePB-modified ZnO/BiVO4 photoanode for PEC water oxidation.

Photoelectrochemical (PEC) water splitting has been recognized as the most promising approach for directly converting solar energy into chemical energy, and substantial efforts have been made to develop a highly efficient and low-cost photoanode for enhancement of PEC water splitting efficiency due to sluggish water oxidation reaction kinetics. A ternary NiFePB-modified ZnO/BiVO4 heterojunction photoanode was simply assembled by low-temperature hydrothermal, metal-organic decomposition and electrodeposition methods to improve the water splitting efficiency; its photocurrent density for water oxidation reached 1.66 mA cm-2 at 1.23 V (vs. RHE); in comparison, that of ZnO is only 0.4 mA cm-2. The onset potential manifests a cathodic shift of ∼283 mV compared to ZnO. The IPCE and the ABPE respectively are 3.1 and 6.4 times those of ZnO, respectively. This improvement is ascribed to the efficient separation of photogenerated electrons and holes by the formation of a heterojunction between ZnO and BiVO4 and the enhancement in the oxygen evolution reaction kinetics by the decoration of the co-catalyst NiFePB as a hole acceptor.

A Carbon-Negative Hydrogen Production Strategy: CO2 Selective Capture with H2 Production.

We reported a strategy of carbon-negative H2 production in which CO2 capture was coupled with H2 evolution at ambient temperature and pressure. For this purpose, carbonate-type Cux Mgy Fez layered double hydroxide (LDH) was preciously constructed, and then a photocatalysis reaction of interlayer CO3 2- reduction with glycerol oxidation was performed as driving force to induce the electron storage on LDH layers. With the participation of pre-stored electrons, CO2 was captured to recover interlayer CO3 2- in presence of H2 O, accompanied with equivalent H2 production. During photocatalysis reaction, Cu0.6 Mg1.4 Fe1 exhibited a decent CO evolution amount of 1.63 mmol g-1 and dihydroxyacetone yield of 3.81 mmol g-1 . In carbon-negative H2 production process, it showed an exciting CO2 capture quantity of 1.61 mmol g-1 and H2 yield of 1.44 mmol g-1 . Besides, this system possessed stable operation capability under simulated flu gas condition with negligible performance loss, exhibiting application prospect.

Process coupling of CO2 reduction and 5-HMF oxidation mediated by defect-enriched layered double hydroxides.

Aiming at the comprehensive utilization of waste carbon resources and renewable carbon resources, we put forward the photocatalytic coupling process of CO2 reduction and 5-hydroxymethylfurfural (5-HMF) oxidation mediated by the anionic compound of layered double hydroxides (LDHs). Specifically, a ZnNiFe-LDH was synthesized by co-precipitation method, during which CO2 was stored between LDH layers in the form of carbonate. Then, a certain amount of metal vacancies were introduced into LDH nanosheets by selectively etching Zn2+ ions. ICP-AES, EPR and XPS showed that the concentration of Zn vacancies gradually increased with the etching time prolonging, which thus optimized the electronic structure of LDH layers. Under the catalysis of the electron-rich metal cations and hydroxyl groups on the layers, the interlayer carbonate was in situ reduced into CO coupled accompanied with the 5-HMF oxidation to 2.5-furandiformaldehyde (DFF). Compared with the unetched ZnNiFe-LDHs, the CO and DFF yields over the LDHs etched for 3 h were increased by 2.84 and 2.82 times under UV-vis irradiation with a density of 500 mW cm-2. Finally, combined with isotope-labeled 13CO2 experiments and in situ FTIR characterization, we revealed the possible coupling mechanism and defect-induced performance enhancement mechanism.

Single Modified Posterior Approach through the Space of the Proximal Radioulnar Joint for Terrible Triad Injury: A Comparative Study.

OBJECTIVE: In order to reduce surgical scars and the risk of neurovascular injury for the treatment of terrible triad injuries of the elbow (TTI), minimally invasive and better therapeutic effect approaches are being explored to replace the conventional combined lateral and medial approach (CLMA). This study was performed to compare the clinical effect and security of the modified posterior approach (MPA) through the space of the proximal radioulnar joint vs the CLMA for treatment of TTI. METHODS: This study retrospectively analyzed 76 patients treated for TTI from January 2009 to December 2020 (MPA: n = 44; CLMA: n = 32). Treatment involved plate and screw fixation or Steinmann pin fixation for the radial head and ulnar coronoid process fractures. Surgeons only sutured the lateral ligament because the medial collateral ligament was usually integrated in the TTI. The continuous variables were compared by the independent Student t-test and the categorical variables by the χ2 -test or Fisher's exact test. RESULTS: Both groups of patients attained a satisfactory MEPS after the operation. The MEPS (MPA: 96.82 ± 6.04 vs CLMA: 96.56 ± 5.51) was not significantly different between the two groups (p > 0.05). However, the MPA resulted in better elbow flexion and extension (MPA: 123.98 ± 10.09 vs CLMA: 117.66 ± 8.29), better forearm rotation function (MPA: 173.41 ± 6.81 vs CLMA: 120.00 ± 12.18), and less intraoperative hemoglobin (MPA: 9.34 ± 5.64 vs CLMA: 16.5 ± 8.75) and red cell volume loss (MPA: 3.09 ± 2.20 vs CLMA: 6.70 ± 2.97) (All p < 0.05). Although the CLMA had a shorter surgery time (MPA: 171.73 ± 80.68 vs CLMA: 130.16 ± 71.50) (p < 0.05), it had a higher risk of neurologic damage (MPA: 0 vs CLMA: 4) (p < 0.05). Four patients developed forearm or hand numbness after the CLMA, but no patients developed numbness after the MPA. All 76 patients were followed up for 15 months postoperatively. CONCLUSION: The MPA through the space of the proximal radioulnar joint has more prominent advantages than the CLMA for TTI, including single scar, clear exposure, good fixation, lower risk of neurovascular injury, and better elbow joint motion. It is a safe and effective surgical approach that is worthy of clinical promotion.

Light-Induced Structural Dynamic Evolution of Pt Single Atoms for Highly Efficient Photocatalytic CO2 Reduction.

Revealing the structural evolution of the real active site during photocatalysis is very important for understanding the catalytic mechanism, but it remains a great challenge. By employing single atoms (SAs) as the mechanism research platform, we investigated the variation of the SA structure under light and the corresponding reaction pathway controlment mechanism. In particular, taking the defect anchoring strategy, Pt SAs are anchored on the metal ion vacancy-rich ZnNiTi layered double hydroxide-etched (ZnNiTi-LDHs-E) support. It is proved by CO-Fourier transform infrared and X-ray absorption fine structure characterization methods that the Pt SAs could gain photoelectrons to form cationic Pt(IV), electron-rich Pt(II), and near-neutral Ptδ+ species at different light intensities. By in situ inducing the above different Pt SAs in photocatalytic CO2 reduction, a dramatic product distribution is observed: (1) under weak light, Pt(IV) SAs cannot activate CO, so CO cannot be further transformed into hydrocarbons; (2) under the moderate light, electron-rich Pt(II) SAs could cooperate with adjacent LDH surface sites (Ni2+/Ti4+) to open up the C-C coupling route for C2H6 generation; and (3) Pt SAs in the state of near-neutral Ptδ+ could directly hydrogenate CO into CH4. This work reveals the structural evolution of Pt SAs in photocatalysis and the corresponding effect on catalytic performance, which provides a new idea for the construction of highly efficient photocatalysts.

Porous ZnCl2-Activated Carbon from Shaddock Peel: Methylene Blue Adsorption Behavior.

It is of great interest and importance to resource utilization of waste biomass to produce porous carbon for environmental treatments. Pore structure and properties of the obtained carbon mainly relate to carbonization conditions and biomass types. In this work, a series of porous, biomass-activated carbons (AC) were prepared using shaddock peel, with ZnCl2 as a pore-forming agent. The effect of carbonization temperature and the mass ratio between ZnCl2 and shaddock peel were thoroughly investigated. The material composition, surface chemical properties, and surface structures of samples were carefully characterized. The specific surface area and adsorption capacity to methylene blue (MB) of adsorbents were changed with the carbonization temperature and the mass ratios between ZnCl2 and shaddock peel; when the temperature was at 1000 °C and the mass ratio was equal to 2:1, the resulting adsorbent had the largest specific surface area of 2398.74 m2/g and average pore size of 3.04 nm, which showed the highest adsorption capacity to MB to be 869.57 mg/g. The adsorption processes of biomass AC adsorbent matched the pseudo-second-order kinetic model and Langmuir isotherm model. This efficient and environmentally friendly biomass AC adsorbent from shaddock peel, activated by ZnCl2, is a promising candidate for the treatment of water pollution.

Control of Local Electronic Structure of Pd Single Atom Catalyst by Adsorbate Induction.

Aiming at regulating and controlling the localized electronic states while maintaining the metal atoms in the isolation form, an in situ adsorbate induced strategy is proposed at a programmed temperature to activate Zr-based metal-organic framework (MOF) supported single Pd atom catalyst. It is discovered that in situ treatment environments trigger the change of lattice parameters in MOF materials by reaction heat effect, observed by in situ X-ray diffraction, spherical aberration-corrected electron microscope, and X-ray adsorption fine structure (XAFS). The as-obtained electron-deficient Pd single atoms are critical to the high intrinsic activity (turnover frequency of 0.132 s-1 ) and selectivity of 93% with the long-term stability in the semihydrogenation of acetylene, which can be comparable to the state-of-the-art Pd catalysts. This superior catalytic behavior correlates with the reduced C2 H4 desorption energy and the activation barriers for the hydrogenation, confirmed by density functional theory calculation.

rGO decorated ZnO/CdO heterojunction as a photoanode for photoelectrochemical water splitting.

A ternary photoanode of ZnO/CdO heterojunction decorated with reduced graphene oxide (rGO) was firstly fabricated by electrochemical deposition and thermal decomposition that is simple and effective compared with other method reported in literature. The structure and morphology of the photoanode were systematically characterized by various spectrum technologies. The photoanode expands the visible light absorption range to 428 nm, the photocurrent density reaches 1.15 mA·cm-2 at 1.23 V (vs. RHE) that is 3 times and 1.85 times of pure ZnO (0.38 mA·cm2) and ZnO/CdO (0.62 mA·cm2) photoanodes. The highest IPCE value reaches 42.63% at 380 nm. The enhancement is attributed to the architecture of semiconductor heterojunctions and the decoration of rGO nanosheets, the former promotes charge separation, while the latter accelerates electron transfer thus both synergistically enhance PEC water splitting efficiency. Here fabricated photoanode has never been reported before, only Cd and other metal elements doped ZnO photoanodes were reported in the literature.

Construction of a Unique Structure of Ru Sites in the RuP Structure for Propane Dehydrogenation.

It is an important task to develop low-cost and anticoking catalysts for the propane dehydrogenation (PDH) reaction. In this work, the P element is introduced to the Ru-based catalyst to obtain Ru sites with a unique structure and the obtained RuxPy (x/y = 2:1, 1:1, 1:2) catalysts are then employed in PDH. Density functional theory (DFT) results show that the addition of P leads to the formation of separated Ru sites and the adjustment of the valance band state of Ru. The upward shift of the d-band center leads to a reduction of the reaction energy barrier for dehydrogenation of propane and an enhancement of catalytic activity. The analysis of the competition between propylene deep dehydrogenation and propylene desorption for each catalyst shows that desorption of propylene is preferred on the RuP(112) surface. Considering both catalytic activity and propylene selectivity, the RuP catalyst is potential for the propane dehydrogenation reaction. On the RuP surface, the PDH reaction proceeds by the dehydrogenation of the H atom on the methylene group (isopropyl pathway), thus restraining the deep dehydrogenation of propylene. The RuxPy catalysts are also synthesized in experiments, and PDH evaluation shows that the RuP structure is a remarkable PDH catalyst with a stable structure, anticoking ability, and low cost.

Insights into the Role of Dual-Interfacial Sites in Cu/ZrO2 Catalysts in 5-HMF Hydrogenolysis with Isopropanol.

In this work, we synthesized a series of Cu/ZrO2 catalysts with tunable Vo-Cu0 (oxygen vacancy adjacent to Cu metal) and VZr-Cuδ+ (zirconium vacancy adjacent to electron-deficient Cu species) dual-interface sites and investigated the role of the dual-interface sites in the 5-hydroxymethylfurfural (5-HMF) hydrogenolysis reaction with isopropanol as the hydrogen source. By combining a series of in situ infrared characterization and catalytic performance analysis, it is identified that Vo-Cu0 interface sites were responsible for activating isopropanol dehydrogenation and C═O dissociation of 5-HMF, while the VZr-Cuδ+ interface sites were responsible for the dehydroxylation of an intermediate product 5-methyl-2-furfuryl alcohol (5-MFA). Specifically, C-OH was first deprotonated on the VZr at the VZr-Cuδ+ interface site to reduce the activation energy of 5-MFA dehydroxylation and then adjacent Cuδ+ promoted the dissociation of the C-O bond by enhancing the adsorption energy while elongating the C-O bond, as confirmed by the density functional theory calculations. Because the dual-interface sites provided separate sites for activating intermediate products and reactants, the coupling reaction caused by competitive adsorption is thus well avoided. Therefore, the optimized Cu/ZrO2 catalyst with the most VZr-Cuδ+ and moderate Vo-Cu0 sites exhibited 98.4% of 2,5-dimethylfuran yield under the conditions of 180 °C and self-vapor pressure.

Improvement of Selectivity in Acetylene Hydrogenation with Comparable Activity over Ordered PdCu Catalysts Induced by Post-treatment.

In this work, a simple post-treatment has been carried out on a solid palladium-copper alloy to enhance the ethylene selectivity without any loss of activity. In all catalysts, PdCu/C catalysts post-treated at 375 °C exhibit improved ethylene selectivity (86%) compared to the solid PdCu/C catalysts (61%) at 100% acetylene conversion with comparable catalytic activity. During the post-treatment, the average size of PdCu nanoparticles is maintained at 6.6-6.8 nm, and no obvious segregation is observed. X-ray photoelectron spectroscopy and in situ extended X-ray absorption fine structure (EXAFS) results display that Pd is in a metallic state for all PdCu catalysts before and after post-treatment. Moreover, the EXAFS fitting results show that the Pd-Pd bond is gradually replaced by the Pd-Cu bond. The good separation of Pd atoms by Cu is also proven by XRD characterization, which shows that a body-centered cubic PdCu structure with uniform distribution of Pd and Cu in a unit cell forms under 375 °C post-treatment. The rearrangement of Pd and Cu atoms has a limited impact on the surface Pd dispersion, avoiding the activity loss due to the decrease in Pd sites. The improved selectivity could be attributed to the isolation of Pd and the accompanied d-band center downshifting, which favors the desorption of π-bonded ethylene species.

Pine dendritic bismuth vanadate loaded on reduced graphene oxide for detection of low concentration triethylamine.

The volatile gas of Triethylamine (TEA) can cause environment pollution and lead to the serious hurt of the human respiratory system. Therefore, it is necessary to detect low concentrations of TEA in our daily lives rapidly. The hybrid of pine dendritic BiVO4/reduced graphene oxide (rGO) has been synthesized firstly by one step hydrothermal process. The gas sensing tests show that the 13.0 wt% rGO hybrid not only exhibits high response of 5.9 and rapid response of 11.4 s, but also exclusive selectivity and long-term stability to 10 ppm of TEA at the operating temperature of 180 °C. The formation of heterojunction and the incoporation of rGO are responsible for the improving sensing properties of the hybrid to TEA, the former results in reduction of the electron depletion layer at interface in hybrid, while the latter enhances the specific surface of the hybrid and accelerates the transfer of electrons. The research is expected to have wide application in the development of composite based gas sensors made of rGO/metal oxide semiconductors.