Magnetic Fe3O4/bamboo-based activated carbon/UiO-66 composite as an environmentally friendly and effective adsorbent for removal of Bisphenol A.

The magnetic Fe3O4/bamboo-based activated carbon/Zr-based metal-organic frameworks composite (Fe3O4/BAC/UiO-66) was prepared by hydrothermal method. The as-prepared material was analyzed via TEM, XRD, FT-IR, BET-BJH, VSM and XPS techniques, the results showed that it had good dispersion and magnetic separation capacity (Ms = 44.06 emu∙g-1). Then, the adsorption properties of materials for bisphenol A (BPA) were studied. The results revealed that the removal efficiency of 50 mg·L-1 BPA by 0.1 g of adsorbent can reach 87.18-95% in a wide pH range. Langmuir isotherm model and pseudo-second-order kinetic well fitted the adsorption data. The thermodynamic data indicated that the adsorption process was spontaneous and endothermic. Moreover, BAC as a supporter and UiO-66 as the functional part in the ternary composite may have a synergistic effect, which was beneficial for the removal of contaminants. The Fe3O4/BAC/UiO-66 can be simply separated from the water using its strong magnetism after finish adsorption process, which effectively avoids secondary contamination.

A study on the performance of a novel adsorbent UiO-66 modified by a nickel on removing tetracycline in wastewater.

In the present study, Ni-UiO-66 was synthesized to improve the adsorption efficiency of tetracycline (TC) in wastewater treatment. To this end, nickel doping was performed in the preparation process of UiO-66. The synthesized Ni-UiO-66 was characterized by XRD, SEM and EDS, BET, FTIR, TGA, and XPS for obtaining the lattice structure, surface topography, specific surface area, surface functional groups, and thermostability. More specifically, Ni-UiO-66 has a removal efficiency and adsorption capacity of up to 90% and 120 mg g-1, respectively, when used to treat TC. The presence of ions HCO3-, SO42-, NO3- and PO43- slightly affects the TC adsorption. A 20 mg L-1 humic acid reduces the removal efficiency from 80% to 60%. The performed analyses revealed that Ni-UiO-66 had similar adsorption capacity in wastewater with different ion strengths. The variation of adsorption capacity with the adsorption time was fitted using a pseudo-second-order kinetic equation. Meanwhile, it is found that the adsorption reaction occurs only on the monolayer of the UiO-66 surface so the adsorption process can be simulated using the Langmuir isotherm model. The thermodynamic analysis indicates that the adsorption of TC is an endothermic reaction. Electrostatic attraction, hydrogen-bond interaction, and π-π interaction might be the main reasons for the adsorption. The synthesized Ni-UiO-66 has well adsorption capacity and stable structure. Accordingly, it is expected to achieve a good prospect in industrial applications and wastewater treatment plants.

Oxygen-saturation-related functional parameter as a biomarker for diabetes mellitus-extraction method and clinical validation.

Purpose: To develop a computational method for oxygen-saturation-related functional parameter analysis of retinal vessels based on traditional color fundus photography, and to explore their characteristic alterations in type 2 diabetes mellitus (DM). Methods: 50 type 2 DM patients with no-clinically detectable retinopathy (NDR) and 50 healthy subjects were enrolled in the study. An optical density ratio (ODR) extraction algorithm based on the separation of oxygen-sensitive and oxygen-insensitive channels in color fundus photography was proposed. With precise vascular network segmentation and arteriovenous labeling, ODRs were acquired from different vascular subgroups, and the global ODR variability (ODRv) was calculated. Student's t-test was used to analyze the differences of the functional parameters between groups, and regression analysis and receiver operating characteristic (ROC) curves were used to explore the discrimination efficiency of DM patients from healthy subjects based on these functional parameters. Results: There was no significant difference in the baseline characteristics between the NDR and healthy normal groups. The ODRs of all vascular subgroups except the micro venule were significantly higher (p<0.05, respectively) while ODRv was significantly lower (p<0.001) in NDR group than that in healthy normal group. In the regression analysis, the increased ODRs except micro venule and decreased ODRv were significantly correlated with the incidence of DM, and the C-statistic for discrimination DM with all ODR is 0.777 (95% CI 0.687-0.867, p<0.001). Conclusion: A computational method to extract the retinal vascular oxygen-saturation-related optical density ratios (ODRs) with single color fundus photography was developed, and increased ODRs and decreased ODRv of retinal vessels could be new potential image biomarkers of DM.

Transition Metal ß-Diketonate Adhesion Promoters in Epoxy-Anhydride Resin.

Epoxy to copper adhesion supports the reliability of numerous structures in electronic packaging. Compared to substrate pre-treatment, processing and cost considerations are in favor of adhesion promoters loaded in epoxy formulations. In this work, first row transition metal ß-diketonates present such a compelling case when added in epoxy/anhydride resins: over 30% (before moisture aging) and 50% (after moisture aging) enhancement in lap shear strength are found using Co(II) and Ni(II) hexafluoroacetylacetonate. From extensive X-ray photoelectron spectroscopy (XPS) analyses on the adhesively failed sample surfaces, increased population of oxygen-containing functional groups, especially esters, is linked to the adhesion improvement. Assisted by XPS depth profile on the fractured epoxy side and in situ Fourier-transform infrared spectroscopy (FTIR), the previously discovered latent cure characteristics endowed by the metal chelates interacting with phosphine catalysts are regarded pivotal for pacing the anhydride consumption and allowing interfacial esterification reactions to occur. Further examinations on the XPS binding energy shifts and dielectric properties of the doped epoxy also reveal metal-polymer coordination that contribute to the adhesion and moisture resistance properties. These findings should stimulate future research of functional additives targeting at cure kinetics control and polar group coordination ideas for more robust epoxy-Cu joints.

Melamine-graphene epoxy nanocomposite based die attach films for advanced 3D semiconductor packaging applications.

With the ultra-fast development of personal portable electronic devices, it is important to explore new die attach film (DAF) materials in the limited mounting area and height in order to meet the requirements of a high packaging density and a high operating speed. Graphene-based epoxy nanocomposites are becoming one of the most promising candidates for the next generation of DAFs combining the ultra-high thermal conductivity of graphene, and ultra-strong adhesion of epoxy polymers. However, poor dispersion and weak interfacial connections, due to the overly smooth surface of graphene nanosheets, are still pressing issues that limit their industrial applications. Additionally, pristine graphene nanosheets have only a small effect on improving the glass transition temperature (Tg) of epoxy composites to meet the requirements of DAFs. In this work, melamine-functionalized graphene is synthesized by using a nondestructive ball milling process, which results in greater dispersion and enhancement of the interfacial connections between graphene and epoxy resins demonstrated by both experimental and simulation results. In particular, the aromatic triazine rings of melamine increase Tg in the cured resin, thus improving the thermal stability of DAFs. The melamine-graphene (M-G) epoxy nanocomposites synthesized have a high Tg of 172 °C and an out-of-plane thermal conductivity of 1.08 W m-1 K-1 at 10 wt% loading. This is 6.4 multiples higher than that of neat epoxy. Moreover, M-G epoxy nanocomposites exhibit superb thermal stability, an effective low coefficient of thermal expansion (CTE), low moisture adsorption, and a useful high electrical resistivity. In the DAF performance test, involving experimentation and modeling, the samples present a better cooling capability and heat dissipation. This supports the idea that our findings have potential to be applied in the next generation of DAFs for high-power and high-density 3D packaging.

Response surface methodology optimization for the synthesis of N, S-codoped carbon dots and its application for tetracyclines detection.

In this study, using a convenient one-pot microwave-assisted method, we rapidly fabricated a N, S-codoped fluorescent carbon dots (NSCDs) through using citric acid (CA) and d-penicillamine (DPA) for the detection of tetracyclines (TC). To rapidly and efficiently optimize the various synthesis parameters and significantly decrease the number of experimental runs, the effect of the synthesis factors on quantum yield (QY) by NSCDs was implemented through means of response surface methodology (RSM). The as-synthesized NSCDs presented superior photoluminescence stability with a strong quantum yield (QY) of 91.55% under optimal conditions, which was consistent with the predicted value using RSM. The fluorescence intensity of the NSCDs could be quenched effectively after adding TC by the inner filter effect (IEE) and photoinduced electron transfer (PET). Thus, the determination of TC by using NSCDs as a facile fluorescent probe was constructed in the range of 0.2-70 µM with a limit detection of 0.072 µM. Moreover, this detection approach has been utilized to detect TC in actual samples with satisfactory results.

Melt Processable Novolac Cyanate Ester/Biphenyl Epoxy Copolymer Series with Ultrahigh Glass-Transition Temperature.

The rapid progress in silicon carbide (SiC)-based technology for high-power applications expects an increasing operation temperature (up to 250 °C) and awaits reliable packaging materials to unleash their full power. Epoxy-based encapsulant materials failed to provide satisfactory protection under such high temperatures due to the intrinsic weakness of epoxy resins, despite their unmatched good adhesion and processability. Herein, we report a series of copolymers made by melt blending novolac cyanate ester and tetramethylbiphenyl epoxy (NCE/EP) that have demonstrated much superior high-temperature stability over current epoxies. Benefited from the aromatic, rigid backbone and the highly functional nature of the monomers, the highest values achieved for the copolymers are as follows: glass-transition temperature (Tg) above 300 °C, decomposition onset above 400 °C, and char yield above 45% at 800 °C, which are among the highest of the known epoxy chemistry by far. Moreover, the high-temperature aging (250 °C) experiments showed much reduced mass loss of these copolymers compared to the traditional high-temperature epoxy and even the pure NCE in the long term by suppressing hydrolysis degradation mechanisms. The copolymer composition, i.e., NCE to EP ratio, has found to have profound impacts on the resin flowability, thermomechanical properties, moisture absorption, and dielectric properties, which are discussed in this paper with in-depth analysis on their structure-property relationships. The outstanding high-temperature stability, preferred and adjustable processability, and the dielectric properties of the reported NCE/EP copolymers will greatly stimulate further research to formulating robust epoxy molding compounds (EMCs) or underfill for packaging next-generation high-power electronics.

Field study to characterize customer flow and ventilation rates in retail buildings in Shenzhen, China.

Reduction of the customers' exposure risk of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) in the retail buildings, i.e., supermarkets and small shops where residents purchase daily necessities is of prime importance during pandemic. In this study, the main influencing factors of the exposure risk of SARS-CoV-2, namely the occupant density, dwell time, and fresh air volume per person, were on-sited measured in 5 supermarkets and 21 small shops in Shenzhen, China. The small shops with an occupant area per person of 4.7 m2/per presented a more crowded environment than the supermarkets with an occupant area per person of 18.8 m2/per. The average dwell time of customers in the supermarkets linearly increased with the floor area and its probability distribution was fitted well by the Gamma distribution with a shape parameter of 3.0. The average dwell time of customers in the supermarkets was relatively longer than the combination of five types of small shops. In addition, the measured average outdoor air change rate of the small shops by natural ventilation was 10.7 h-1, while that of the supermarkets by mechanical ventilation was only 0.7 h-1. Correspondingly, the CO2 concentration in the small shops was 100-150 ppm lower than the supermarkets. The small shops provided an average fresh air volume per person of 216 m3/(h·per), far exceeding the supermarkets with a value of 95 m3/(h·per).

A field study on indoor environment quality of Chinese inpatient buildings in a hot and humid region.

In this research, objective physical measurements and subjective questionnaire surveys are used to investigate the indoor environment quality of Chinese inpatient buildings. The relative humidity in the inpatient buildings reaches 65%-75% during summer, resulting in the regular appearance of microbial growth on indoor surfaces. The average outdoor air change rate measured through the CO2 concentration decay method in the sampled inpatient rooms is 1.1 h-1, which is 45% below the standard threshold. The CO2 concentration in over 99% of the functional spaces is below the threshold of 1000 ppm. However, the dissatisfaction rate of the air freshness is higher than 25%, owing to the characteristics of healthcare activities. Insufficient fresh air volume and high supply air humidity ratio of the outdoor air system result in the inadequate dehumidification capacity and the over-humid environment in the inpatient buildings. From the perspective of indoor TVOC and PM2.5 concentration, a hospitable IAQ is achieved in the inpatient buildings. In the nurse unit, the illumination levels in public areas, such as patient corridors and nurse stations, are inadequate. The average noise levels (A) in the inpatient rooms and nurse stations are 50.7 and 61.6 dB, respectively, which exceeds the Chinese standard. According to the subjective survey, the dissatisfaction rates of overall IEQ in the summer for patients and visitors are 7.9% and 10.4%, respectively, while for staff it is 34.8%. Statistical analysis reveals that the satisfaction levels of the patient with the IEQ are higher than that of the visitor and staff.

Processing and characterization of silver-filled conductive polysulfide sealants for aerospace applications.

Polysulfide (PS) rubbers have been widely used as high performance sealants to line or seal aircraft fuel tanks. However, safety concerns arise when electrostatic charges are built up due to the motion of flammable fuels. In this report, electrically conductive sealants were designed in order to dissipate these hazardous charges. Silver fillers with various sizes and surface coatings were incorporated into a polysulfide matrix to make conductive sealants. The low electrical conductivity of the sealants led to the assumption that unique filler-resin interactions occurred at their interfaces. To verify this assumption, various characterization methods were employed to investigate the chemical, thermal, morphological, electrical, and mechanical properties of the sealants. In addition, carbon fillers and other room temperature-cured polymer resins were used for comparative study. The systematic analysis revealed that the formation of coordination compounds at silver/PS interfaces could block electron conduction pathways between fillers. Based on the chemical understanding, post cure thermal annealing was utilized to break the coordinated bonds and restore high conductivity (>106 S m-1) of the sealants. Conductivity change as a function of annealing temperature and time was also explored to optimize processing conditions.

Experimental demonstration of a few-mode Raman amplifier with a flat gain covering 1530-1605 nm.

We design and experimentally demonstrate a few-mode Raman amplifier over the C+L band with a flat on-off gain of ∼4 dB, for the first time, to the best of our knowledge. A state-of-the-art gain bandwidth of 75 nm (1530-1605 nm) is achieved. The wavelength-dependent gain for both LP01 and LP11 modes is about 0.6 dB, and the maximum mode-dependent gain is less than 0.3 dB. Mode-division multiplexed optical transmissions are performed over 75 km few-mode fiber assisted by the proposed Raman amplifier. Due to the low noise Raman amplification, more than 3.3 dB optical signal-to-noise ratio enhancement has been obtained with a significantly improved bit-error rate of about two orders.

Broadband and low-loss mode scramblers using CO2-laser inscribed long-period gratings.

We demonstrate broadband and low-loss three-mode and six-mode scramblers employing CO2-laser inscribed long-period gratings (LPGs) for space-division multiplexing. Step-index (SI) few-mode fibers are used to avoid mode coupling to the cladding modes. We characterize the mode scramblers using a swept-wavelength interferometer. Mode-dependent loss (MDL) and modal transfer matrices over the C+L band are presented. Demonstrated LPGs with negligible MDL and low insertion loss contributed to high-performance CO2-laser inscription. The total MDLs induced by the SI fiber with LPGs in three-mode and six-mode scramblers are measured to be 2 and 4 dB, respectively.

Second-order few-mode Raman amplifier for mode-division multiplexed optical communication systems.

We experimentally demonstrate and investigate, for first time to our best knowledge, a second-order few-mode Raman amplifier for low noise distributed fiber amplification. The 1455 and 1360 nm pumps are both injected into the few-mode fiber (FMF) in the forms of two degenerate LP11 modes in the backward direction. Within the band from 1542 to 1558 nm, maximum on-off gains of 4 dB are achieved for both LP01 and LP11 modes, and the differential modal gain (DMG) is less than 0.4 dB. The noise figure (NF) improvements at 1550 nm for LP01 and LP11 modes are 1.2 dB and 1.1 dB, respectively, compared with the conventional first-order pumping scheme. The lowest NFs of less than -2 dB are achieved for both modes. We build an optical time-domain reflectometer (OTDR) in the few-mode distributed Raman amplifier (FM-DRA) to measure the signal evolutions, and the results indicate a proof-of-concept low noise amplification for second-order pumping with respect to the conventional first-order pumping case. Due to the second-order pumping, broadened Raman amplification band has been observed with improved gain flatness for both LP01 and LP11 modes, which is also of great importance in the optical communication systems. The second-order FM-DRA can be used potentially in future high capacity mode-division multiplexing (MDM) optical communication systems.