Construction of Gold/Rhodium Freestanding Superstructures as Antenna-Reactor Photocatalysts for Plasmon-Driven Nitrogen Fixation.

Precisely controlling the architecture and spatial arrangement of plasmonic heterostructures offers unique opportunities to tailor the catalytic property, whereas the lack of a wet-chemistry synthetic approach to fabricating nanostructures with high-index facets limits their practical applications. Herein, we describe a universal synthetic strategy to construct Au/Rh freestanding superstructures (SSs) through the selective growth of ordered Rh nanoarrays on high-index-faceted Au nanobipyramids (NBPs). This synthetic strategy works on various metal nanocrystal substrates and can yield diverse Au/Rh and Pd/Rh SSs. Especially, the obtained Au NBP/Rh SSs exhibit high photocatalytic activity toward N2 fixation as a result of the spatially separated architecture, local electric field enhancement, and the antenna-reactor mechanism. Both theoretical and experimental results reveal that the Au NBPs can function as nanoantennas for light-harvesting to generate hot charge carriers for driving N2 fixation, while the Rh nanoarrays can serve as the active sites for N2 adsorption and activation to synergistically promote the overall catalytic activity in the Au NBP/Rh SSs. This work offers new avenues to rationally designing and constructing spatially separated plasmonic photocatalysts for high-efficiency catalytic applications.

A Pd-based plasmonic photocatalyst for nitrogen fixation through an antenna-reactor mechanism.

Plasmonic metal nanocrystals (e.g., Au, Ag, and Cu) hold great promise for driving photocatalytic reactions, but little is known about the plasmonic properties of Pd nanocrystals. Herein, we constructed a plasmonic Pd/Ru antenna-reactor photocatalyst through the controllable growth of a Ru nanoarray 'reactor' on a Pd nano-octahedron 'antenna' and demonstrated a plasmonic Pd-driven N2 photofixation process. The plasmonic properties of Pd nano-octahedrons were verified using finite-difference time-domain (FDTD) simulations and refractive index sensitivity tests in water-glycerol mixtures. Notably, the constructed plasmonic antenna-reactor nanostructures exhibited superior photocatalytic activities during N2 photofixation, with a maximum ammonia production rate of 117.5 ± 15.0 µmol g-1 h-1 under visible and near-infrared (NIR) light illumination. The mechanism can be attributed to the ability of the plasmonic Pd nanoantennas to harvest light to generate abundant hot electrons and the Ru nanoreactors to provide active sites for adsorption and activation of N2. This work paves the way for the development of Pd-based plasmonic photocatalysts for efficient N2 photofixation and sheds new light on the optimal design and construction of antenna-reactor nanostructures.

Steric hindrance-induced selective growth of rhodium on gold nanobipyramids for plasmon-enhanced nitrogen fixation.

The construction of an antenna-reactor plasmonic photocatalyst that is composed of a plasmonic and a catalytically active metal holds great promise in driving N2 photofixation, but its photocatalytic performance is highly dependent on the spatial distribution of the two components. Up to now, the fabrication of dumbbell-shaped nanostructures featuring spatially separated architecture has remained challenging. Herein, we develop a facile synthetic strategy for the site-selective growth of a Rh nanocrystal 'reactor' on two tips of an Au nanobipyramid (NBP) 'antenna' through the precise manipulation of steric hindrance toward Rh overgrowth. The obtained Au NBP/tip-Rh nanodumbbells (Au NBP/tip-Rh NDs) can function as an excellent antenna-reactor plasmonic photocatalyst for N2 photofixation. In this scenario, the Au nanoantenna harvests light and generates hot electrons under plasmon resonance, meanwhile the hot electrons are transferred to the active sites on Rh nanocrystals for N2 reduction. In comparison with that of classical core@shell nanostructures, the spatially separated architecture of the Au NBP/tip-Rh NDs facilitates charge separation, greatly improving the photocatalytic activity. This study sheds new light on the structure-function relationship for N2 photofixation and benefits the design and construction of spatially separated plasmonic photocatalysts.

CAP-YOLO: Channel Attention Based Pruning YOLO for Coal Mine Real-Time Intelligent Monitoring.

Real-time coal mine intelligent monitoring for pedestrian identifying and positioning is an important means to ensure safety in production. Traditional object detection models based on neural networks require significant computational and storage resources, which results in difficulty of deploying models on edge devices for real-time intelligent monitoring. To address the above problems, CAP-YOLO (Channel Attention based Pruning YOLO) and AEPSM (adaptive image enhancement parameter selection module) are proposed in this paper to achieve real-time intelligent analysis for coal mine surveillance videos. Firstly, DCAM (Deep Channel Attention Module) is proposed to evaluate the importance level of channels in YOLOv3. Secondly, the filters corresponding to the low importance channels are pruned to generate CAP-YOLO, which recovers the accuracy through fine-tuning. Finally, considering the lighting environments are varied in different coal mine fields, AEPSM is proposed to select parameters for CLAHE (Contrast Limited Adaptive Histogram Equalization) under different fields. Experiment results show that the weight size of CAP-YOLO is 8.3× smaller than YOLOv3, but only 7% lower than mAP, and the inference speed of CAP-YOLO is three times faster than that of YOLOv3. On NVIDIA Jetson TX2, CAP-YOLO realizes 31 FPS inference speed.

Restorable, enhanced, and multifaceted tunable optical properties in a coaxial quantum well driven by the electric field and intense laser field.

A new method for regulating optical properties of a coaxial cylindrical quantum well using the electric field and intense laser field is investigated in the effective mass approximation. By means of the finite difference method and the correct dressing effect of the confinement potential, the results show that the enhancement and recovery of optical absorption and refractive index change strongly depend on the multifaceted-cooperative regulation of the laser parameter, the electric field strength, the angle between the electric field and polarization direction of laser, and the barrier width. This is promising for the design of a new generation of highly polarization sensitive devices, optical repair equipments and optical phase modulators by adopting the multistage combination of electric and intense laser fields.

Data Sharing Mechanism of Sensors and Actuators of Industrial IoT Based on Blockchain-Assisted Identity-Based Cryptography.

The Industrial IoT is one of the key technologies to improve industrial production efficiency. The entire production process usually involves multiple production regions and numerous smart devices (sensors and actuators). The efficiency of the Industrial IoT is limited by this strong coupling relationship between the subsystem and the sensors and actuators. In this paper, to unleash the potential of Industrial IoT, a safe and reliable data sharing mechanism of sensors and actuators is proposed. We deployed distributed identity authentication and data proxy services in various regions. In the device authentication process, we used identity-based encryption algorithms, and we solved the trust problem between different regions by introducing a private blockchain. In addition, we designed the model of device capability (MDC) to describe the device, enabling it to be shared with a standard interface. Finally, we conducted many performance tests on the proposed mechanism. The test results verified the effectiveness and efficiency of the proposed mechanism.

Three-Dimensional Cuprous Lead Bromide Framework with Highly Efficient and Stable Blue Photoluminescence Emission.

Considering the instability and low photoluminescence quantum yield (PLQY) of blue-emitting perovskites, it is still challenging and attractive to construct single crystalline hybrid lead halides with highly stable and efficient blue light emission. Herein, by rationally introducing d10 transition metal into single lead halide as new structural building unit and optical emitting center, we prepared a bimetallic halide of [(NH4 )2 ]CuPbBr5 with new type of three-dimensional (3D) anionic framework. [(NH4 )2 ]CuPbBr5 exhibits strong band-edge blue emission (441 nm) with a high PLQY of 32 % upon excitation with UV light. Detailed photophysical studies indicate [(NH4 )2 ]CuPbBr5 also displays broadband red light emissions derived from self-trapped states. Furthermore, the 3D framework features high structural and optical stabilities at extreme environments during at least three years. To our best knowledge, this work represents the first 3D non-perovskite bimetallic halide with highly efficient and stable blue light emission.

A Resource Allocation Mechanism Based on Weighted Efficiency Interference-Aware for D2D Underlaid Communication.

Device-to-device (D2D) communication is a promising technique for direct communication to enhance the performance of cellular networks. In order to improve the system throughput and utilization of spectrum resource, a resource allocation mechanism for D2D underlaid communication is proposed in this paper where D2D pairs reuse the resource blocks (RBs) of cellular uplink users, adopting a matching matrix to disclose the results of resource allocation. Details of the proposed resource allocation mechanism focused are listed as: the transmit power of D2D pairs are determined by themselves with the distributed power control method, and D2D pairs are assigned to different clusters that are the intended user sets of RBs, according to the threshold of the signal-to-interference-plus-noise ratio (SINR). The weighted efficiency interference-aware (WE-I-A) algorithm is proposed and applied subsequently to promote the system throughput by optimizing the matching of D2D pairs and RBs, where each D2D pair is weighted based on the SINR to compete for the priority of RBs fairly. Simulation results demonstrate that the proposed algorithm contributes to a good performance on the system throughput even if the uplink state is limited.

Safety and efficacy of bone marrow-derived cells therapy on cardiomyopathy: a meta-analysis.

BACKGROUND: Controversial results still existed on the clinical utility of bone marrow-derived cells (BMCs) for cardiomyopathy (CMP). This study aims to reveal the true power of this promising approach by synthesizing all the available data on this subject matter. METHODS: Twenty studies including 1418 patients were identified from systematic search. Weighted mean differences for changes in left ventricular ejection fraction (LVEF), left ventricular end-diastolic volume (LVEDV), left ventricular end-systolic volume (LVESV), 6-min walk distance, and NYHA functional class were estimated with a random-effects model. Major adverse cardiovascular event (MACE), rehospitalization, all-cause mortality, and patients' quality of life were also calculated. RESULTS: Compared with the control group, BMC therapy resulted in greater LVEF (3.72%, 95% CI 2.31 to 5.13, P < 0.0001), 6-min walk distance (53.16, 95% CI 25.17 to 81.10, P = 0.0002), NYHA functional class (- 0.48, 95% CI - 0.65 to - 0.31, P < 0.0001), and smaller LVESV (- 16.79, 95% CI - 27.21 to - 6.38, P = 0.002). BMC treatment significantly reduced the mortality rate and improved patients' quality of life. No significant difference was found between the BMCs and control group in LVEDV, MACE, and rehospitalization rate. However, the outcomes showed a clear trend in favor of the BMC group. Subgroup analysis showed that LVEF improved greater in a subgroup of intracoronary infusion, BMSC, or higher cell dose. CONCLUSION: The results of the current meta-analysis suggest that BMC treatment for CMP is safe and feasible. This therapy was associated with persistent improvements in LV function, LV remodeling, functional class, patients' survival, and quality of life. Intracoronary infusion of high-dose (> 108) BMSC might be a better therapeutic option for CMP patients. Further evidences are needed to verify our results.