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1.
Dalton Trans ; 53(8): 3523-3533, 2024 Feb 20.
Artículo en Inglés | MEDLINE | ID: mdl-38275124

RESUMEN

Among transition metals, cobalt ions exhibit superior catalytic activity in the peroxymonosulfate (PMS) degradation of pollutants. However, practical application is hindered by their high rate of ion leaching and the propensity for particle reunion issues. In this study, a novel cobalt metal-organic framework catalyst, denoted as CUST-565 ([Co3(BTB)2(BIPY)2]·4.5H2O·DMA), was synthesized via a one-step solvothermal method. The obtained crystal was employed as a catalyst to activate PMS for degrading two pollutants, methyl orange (MO) and rhodamine B (RhB), in wastewater. The catalyst demonstrated efficacy in PMS, achieving 97% degradation of MO and 98% degradation of RhB within 30 min at an initial concentration of 20.0 mg L-1. Additionally, various factors affecting dye degradation, including PMS dosage, catalyst dosage, temperature, initial pH, and coexisting anions, were investigated. Radical quenching experiments confirmed the presence of sulfate radicals (SO4˙-), hydroxyl radicals (HO˙), superoxide radicals (O2˙-), and singlet oxygen (1O2) in the system. After four cycles, CUST-565 retained its ability to catalytically degrade approximately 80% of the pollutants. These observed stability and reusability properties, corroborated by a series of characterization analyses before and after use, suggest that CUST-565 exhibits reliable performance. This work contributes to the development of cobalt-PMS catalysts for efficiently degrading dyes in wastewater.

2.
Opt Express ; 23(26): 34007-22, 2015 Dec 28.
Artículo en Inglés | MEDLINE | ID: mdl-26832058

RESUMEN

Compressive light field display based on multi-layer LCDs is becoming a popular solution for 3D display. Decomposing light field into layer images is the most challenging task. Iterative algorithm is an effective solver for this high-dimensional decomposition problem. Existing algorithms, however, iterate from random initial values. As such, significant computation time is required due to the deviation between random initial estimate and target values. Real-time 3D display at video rate is difficult based on existing algorithms. In this paper, we present a new algorithm to provide better initial values and accelerate decomposition of light field video. We utilize internal coherence of single light field frame to transfer the ignorance-to-target to a much lower resolution level. In addition, we explored external coherence for further accelerating light field video and achieved 5.91 times speed improvement. We built a prototype and developed parallel algorithm based on CUDA.

3.
Opt Express ; 22(20): 24081-95, 2014 Oct 06.
Artículo en Inglés | MEDLINE | ID: mdl-25321983

RESUMEN

We propose a dictionary-based dense light field acquisition technique. This technique captures light field successfully from a sparse camera array with no mask or any other optical modifications on cameras. Light rays in wider field are captured by our system to achieve larger disparity and higher angular resolution. We also accelerate the reconstruction of light field significantly by a local sliding window which applies median filter only in disaster areas and acquire satisfactory quality. In our experiments, light field with 7x7 views at resolution of 384x512 is restored from 5 cameras with PSNR of 33.0192dB with a computing time of 1.85 hours on a consumer-grade desktop computer.

4.
Opt Express ; 20(12): 13208-14, 2012 Jun 04.
Artículo en Inglés | MEDLINE | ID: mdl-22714349

RESUMEN

Divergence angle of antenna is an important parameter in laser optical communication. It determines the power of the receiver terminal. In this paper, the influence of temperature on the divergence angle is discussed. Theoretical analysis and experiment results demonstrate that the relationship between the variance of temperature and of divergence angle is linear.

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