1.
Org Biomol Chem
; 4(17): 3325-36, 2006 Sep 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-17036122
RESUMEN
Key steps in the synthesis of the C1-C16 polyketide fragment of ionomycin were the nucleophilic addition of an organocuprate to a neutral (eta3-allyl)iron complex and the construction of a beta-diketone moiety by the Rh-catalysed rearrangement of an alpha-diazo-beta-hydroxyketone.
