Zinc Doping Induces Enhanced Thermoelectric Performance of Solvothermal SnTe.

The creation of hierarchical nanostructures can effectively strengthen phonon scattering to reduce lattice thermal conductivity for improving thermoelectric properties in inorganic solids. Here, we use Zn doping to induce a remarkable reduction in the lattice thermal conductivity in SnTe, approaching the theoretical minimum limit. Microstructure analysis reveals that ZnTe nanoprecipitates can embed within SnTe grains beyond the solubility limit of Zn in the Zn alloyed SnTe. These nanoprecipitates result in a substantial decrease of the lattice thermal conductivity in SnTe, leading to an ultralow lattice thermal conductivity of 0.50 W m-1 K-1 at 773 K and a peak ZT of ~0.48 at 773 K, marking an approximately 45 % enhancement compared to pristine SnTe. This study underscores the effectiveness of incorporating ZnTe nanoprecipitates in boosting the thermoelectric performance of SnTe-based materials.

Anion Exchange Membranes Based on Bis-Imidazolium and Imidazolium-Functionalized Poly(phenylene oxide) for Vanadium Redox Flow Battery Applications.

Although the Nafion membrane has a high energy efficiency, long service life, and operational flexibility when applied for vanadium redox flow battery (VRFB) applications, its applications are limited due to its high vanadium permeability. In this study, anion exchange membranes (AEMs) based on poly(phenylene oxide) (PPO) with imidazolium and bis-imidazolium cations were prepared and used in VRFBs. PPO with long-pendant alkyl-side-chain bis-imidazolium cations (BImPPO) exhibits higher conductivity than the imidazolium-functionalized PPO with short chains (ImPPO). ImPPO and BImPPO have a lower vanadium permeability (3.2 × 10-9 and 2.9 × 10-9 cm2 s-1) than Nafion 212 (8.8 × 10-9 cm2 s-1) because the imidazolium cations are susceptible to the Donnan effect. Furthermore, under the current density of 140 mA cm-2, the VRFBs assembled with ImPPO- and BImPPO-based AEMs exhibited a Coulombic efficiency of 98.5% and 99.8%, respectively, both of which were higher than that of the Nafion212 membrane (95.8%). Bis-imidazolium cations with long-pendant alkyl side chains contribute to hydrophilic/hydrophobic phase separation in the membranes, thus improving the conductivity of membranes and the performance of VRFBs. The VRFB assembled with BImPPO exhibited a higher voltage efficiency (83.5%) at 140 mA cm-2 than that of ImPPO (77.2%). These results of the present study suggest that the BImPPO membranes are suitable for VRFB applications.

Stretchable, rapid self-healing guar gum-poly(acrylic acid) hydrogels as wearable strain sensors for human motion detection based on Janus graphene oxide.

Wearable strain sensors have received widespread attention in research fields due to their applications in human motion detection. In this manuscript, the fabrication of functionalized Janus graphene oxide (GO) nanosheets were used by Pickering emulsion template. Polypyrrole (PPy) and poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) were asymmetrically grafted on the two sides of GO (GO@PPy/PDMAEMA Janus NS), which successfully applied to synthesize Janus NS/guar gum-poly(acrylic acid) (GG-PAA) self-healing nanocomposite hydrogels. The outstandingly improved self-healing efficiency (92.8% for 2 h) and mechanical properties (strength of 4.12 MPa and toughness of 873.8%) of nanocomposite hydrogels were mainly supported by the collaborative effect of reversible electrostatic interactions, multiple hydrogen bonds and metal-ligand coordination. Moreover, the hydrogels exhibited strain sensitivity and could be able to monitor a variety of human motions, which have outstanding application prospects in wearable flexible sensors.

Fabrication of self-healing nanocomposite hydrogels with the cellulose nanocrystals-based Janus hybrid nanomaterials.

Janus nanomaterials possess remarkable prospects in the design of a series of smart materials with unique asymmetric properties. In this work, surface functionalized Janus cellulose nanocrystalline-type (CNCs-type) nanomaterials were manufactured by Pickering emulsion template and the construction of self-healing nanocomposite hydrogels has been realized. During emulsification, the mussel-inspired chemistry was employed to develop Janus nanocomposites. The extension of molecular chain of poly-lysine (PLL) and the polydopamine (PDA) coating were grafted on different sides of CNCs. Afterwards, the prepared nanocomposites were added to poly (acrylic acid) (PAA)-based hydrogels which formed by in-situ polymerization. The collaborative effect of metal-ligand coordination between the molecular chain of PLL, PDA coating, PAA chains and metal ions endowed the nanocomposite hydrogels with excellent mechanical properties (8.8 MPa) and self-healing efficiency (88.9%). Therefore, the synthesized Janus CNCs-PDA/PLL nanocomposites are expected to have diverse application in the development of smart materials with self-healing ability.

Highly Durable Ether-Free Polyfluorene-Based Anion Exchange Membranes for Fuel Cell Applications.

The preparation of anion exchange membranes (AEMs) with excellent chemical and dimensional stability and high conductivity faces several challenges. In the present work, a novel ether-free durable polyfluorene (PF) without fluorine-bearing pendant piperidinium groups was synthesized by the Suzuki cross-coupling reaction. Alkyl groups were introduced into the backbone of PF to enhance the solubility and flexibility of PF-based AEMs, and the transparent and flexible polymer membrane showed a high conductivity of 80.44 mS cm-1 and excellent alkaline stability in 2 M KOH solution at 80 °C. Although the membrane possesses a high ion exchange capacity (IEC) (2.49 mequiv g-1), it exhibits a low swelling ratio (9.4% at 80 °C), excellent mechanical properties, and dimensional stability. The H2/O2 single cell assembled with PFPE-Pi exhibited a maximum power density of 661 mW cm-2 at a current density of 1280 mA cm-2 at 80 °C. The present work provides a simple and effective strategy for the preparation of ether-free polyfluorene-based AEMs with high conductivity, excellent mechanical properties, and dimensional stability for application in alkaline fuel cells.

Anion-Exchange Membranes for Alkaline Fuel-Cell Applications: The Effects of Cations.

Alkaline anion-exchange membrane fuel cells (AEMFCs) are attracting much attention because of their potential use of nonprecious electrocatalysts. The anion-exchange membrane (AEM) is one of the key components of AEMFCs. An ideal AEM should possess high hydroxide conductivity and sufficient long-term durability at elevated temperatures in high-pH solutions. Herein, recent progress in research into the alkaline stability behavior of cations (including quaternary ammonium, imidazolium, guanidinium, pyridinium, tertiary sulfonium, phosphonium, benzimidazolium, and pyrrolidinium) and their analogous AEMs, which have been investigated by both experimental studies and theoretical calculations, is reviewed. Effects, including conjugation, steric hindrance e, σ-π hyperconjugation, and electrons, on the alkaline stability of cations and their analogous AEMs have been discussed. The aim of this article is to provide an overview of some key factors for the future design of novel cations and their analogous AEMs with high alkaline stability.

A Novel Capturing Method for Quantification of Extra-Cellular Nanovesicles.

Extracellular vesicles (EVs), secreted by cells and found in body fluids play important roles in intercellular communication. Therefore, EVs are receiving increasing attention as potential biomarkers in the diagnosis and prognosis of various diseases. However, the detection and the quantification of EVs are hampered by the nanometer scale of these particles and by the lack of optimized quantification methods. Atomic force microscopy (AFM) is a powerful technology that can detect small particles. Here we report a 3D capture method for sample preparation of AFM which improves the accuracy, sensitivity and reproducibility for EVs' detection, compared to conventional sample preparation methods. By shaking a mica plate in EV solution, all the EVs were captured onto the 2D surface. The majority of the captured particles have a size ranging from 10 to 120 nm, which correlates with size data obtained from transmission electron microscopy studies. This novel sample preparation method has high adaptability potential and can also be applied to other organic and inorganic nanoparticles.

Purification of Biotinylated Proteins Using Single Walled Carbon Nanotube-Streptavidin Complexes.

In this study, Single walled carbon nanotube (SWNT)-streptavidin complexes were used to capture and purify biotinylated proteins, including bio-GFP and bio-DBS using a pull-down method. The purification conditions were systematically studied, including surface blocking of SWNT using chicken egg albumin (CEA), the ratio of SWNT-streptavidin complexes to the cell lysate, as well as the centrifugation speed. Optimization of the protein purification using SWNT-streptavidin complexes shows the possibility of carbon nanotubes as a promising candidate for protein purification applications. The SWNT-streptavidin could be used as a scaffold to analyze protein structure directly by cryo-transmission electron microscopy, which provides better understanding in protein­protein interactions and biological processes.

Improving the alkaline stability of imidazolium cations by substitution.

Imidazolium cations are promising candidates for preparing anion-exchange membranes because of their good alkaline stability. Substitution of imidazolium cations is an efficient way to improve their alkaline stability. By combining density functional theory calculations with experimental results, it is found that the LUMO energy correlates with the alkaline stability of imidazolium cations. The results indicate that alkyl groups are the most suitable substituents for the N3 position of imidazolium cations, and the LUMO energies of alkyl-substituted imidazolium cations depend on the electron-donating effect and the hyperconjugation effect. Comparing 1,2-dimethylimidazolium cations (1,2-DMIm+) and 1,3-dimethylimidazolium cations (1,3-DMIm+) with the same substituents reveals that the hyperconjugation effect is more significant in influencing the LUMO energy of 1,3-DMIms. This investigation reveals that LUMO energy is a helpful aid in predicting the alkaline stability of imidazolium cations.

The effect of ALD-Zno layers on the formation of CH3NH3PbI3 with different perovskite precursors and sintering temperatures.

ZnO films deposited by atomic layer deposition at 70 °C were used to fabricate perovskite solar cells, and a conversion efficiency of 13.1% was obtained. On the ZnO layer, CH3NH3PbI3 was formed at room temperature using CH3NH3I and PbCl2 precursors, which is in contrast to the reported results.

High-temperature solid-state dye-sensitized solar cells based on organic ionic plastic crystal electrolytes.

Organic ionic plastic crystal, 1-ethyl-1-methyl pyrrolidinium iodide (P(12) I), is employed as the solid-state electrolytes for dye-sensitized solar cells. The fabricated solid-state devices show an overall power conversion efficiency of ~5.8% under AM 1.5 radiation (50 mW/cm(2) ) and excellent long-term stability at 80 °C.