Applications of carbon quantum dots in electrochemical energy storage devices.

Supercapacitors (SCs), including electric double-layer capacitors (EDLCs), pseudocapacitors, and hybrid capacitors, are esteemed for their high power density and attractive features such as robust safety, fast charging, low maintenance, and prolonged cycling lifespan, sparking significant interest. Carbon quantum dots (CQDs) are fluorescent nanomaterials with small size, broad excitation spectrum, stable fluorescence, and adjustable emission wavelengths. They are widely used in optoelectronics, medical diagnostics, and energy storage due to their biocompatibility, low toxicity, rich surface functional groups, abundant electron-hole pairs, large specific surface area, and tunable heteroatom doping. In this short review, we briefly discussed the advantages and disadvantages of bottom-up and top-down of CQD synthesis methods. The arc-discharge technique, laser ablation technique, plasma treatment, ultrasound synthesis technique, electrochemical technique, chemical exfoliation, and combustion are among the initial top-down approaches. The subsequent section delineates waste-derived and bottom-up methods, encompassing microwave synthesis, hydrothermal synthesis, thermal pyrolysis, and the metal-organic framework template-assisted technique. In addition, this short review focuses on the operational mechanism of supercapacitors, their properties, and the utilization of CQDs in supercapacitors.

Influence of Sputtering Temperature of TiO2 Deposited onto Reduced Graphene Oxide Nanosheet as Efficient Photoanodes in Dye-Sensitized Solar Cells.

Renewable solar energy is the key target to reduce fossil fuel consumption, minimize global warming issues, and indirectly minimizes erratic weather patterns. Herein, the authors synthesized an ultrathin reduced graphene oxide (rGO) nanosheet with ~47 nm via an improved Hummer's method. The TiO2 was deposited by RF sputtering onto an rGO nanosheet with a variation of temperature to enhance the photogenerated electron or charge carrier mobility transport for the photoanode component. The morphology, topologies, element composition, crystallinity as well as dye-sensitized solar cells' (DSSCs) performance were determined accordingly. Based on the results, FTIR spectra revealed presence of Ti-O-C bonds in every rGO-TiO2 nanocomposite samples at 800 cm-1. Besides, XRD revealed that a broad peak of anatase TiO2 was detected at ~25.4° after incorporation with the rGO. Furthermore, it was discovered that sputtering temperature of 120 °C created a desired power conversion energy (PCE) of 7.27% based on the J-V plot. Further increase of the sputtering temperature to 160 °C and 200 °C led to excessive TiO2 growth on the rGO nanosheet, thus resulting in undesirable charge recombination formed at the photoanode in the DSSC device.

Development of graphene based nanocomposites towards medical and biological applications.

Graphene and its derivative materials present high potential towards medical and biological applications, including drug delivery and bioimaging, due to their exceptional properties such as thermal conductivity and high specific surface area. The main focus of this work is to review the current development of graphene materials and the derivatives for biocompatible, bioimaging and drug delivery applications. Also, the synthesis methods with variation of graphene nanocomposites and the functionalisation will be further explained. For the graphene approaches, chemical vapour deposition (CVD) is the best-known technique to make high-quality graphene sheet by growth route with mass production. By considering the organic graphene nanocomposites, the biocompatibility and cytotoxic effects against graphene nanocomposites were evaluated for biomedical employments such as high quality bioimaging and effective drug delivery for cancer treatments. For example, graphene oxide incorporated with PEG and loaded with SN 38 for camptothecin analolgue as anticancer drug and revealed high cytotoxicity has an effect of 1000 times better effect than CPT in HCT-116 cells. Their drug delivery ability for both in-vivo and in-vitro applications compared to the controlled drugs such as doxorubicin (DOX) will be discussed accordingly. The graphene and its deriavatives possess some intriguing properties, which will lead to drug delivery due to strong biocompatibility and cyctotoxic effect towards biomedicine applications.

Influence of Temperature Reaction for the CdSe-TiO2 Nanotube Thin Film Formation via Chemical Bath Deposition in Improving the Photoelectrochemical Activity.

In this present work, we report the deposition of cadmium selenide (CdSe) particles on titanium dioxide (TiO2) nanotube thin films, using the chemical bath deposition (CBD) method at low deposition temperatures ranging from 20 to 60 °C. The deposition temperature had an influence on the overall CdSe-TiO2 nanotube thin film morphologies, chemical composition, phase transition, and optical properties, which, in turn, influenced the photoelectrochemical performance of the samples that were investigated. All samples showed the presence of CdSe particles in the TiO2 nanotube thin film lattice structures with the cubic phase CdSe compound. The amount of CdSe loading on the TiO2 nanotube thin films were increased and tended to form agglomerates as a function of deposition temperature. Interestingly, a significant enhancement in photocurrent density was observed for the CdSe-TiO2 nanotube thin films deposited at 20 °C with a photocurrent density of 1.70 mA cm-2, which was 17% higher than the bare TiO2 nanotube thin films. This sample showed a clear surface morphology without any clogged nanotubes, leading to better ion diffusion, and, thus, an enhanced photocurrent density. Despite having the least CdSe loading on the TiO2 nanotube thin films, the CdSe-TiO2 nanotube thin films deposited at 20 °C showed the highest photocurrent density, which confirmed that a small amount of CdSe is enough to enhance the photoelectrochemical performance of the sample.

An investigation of the stirring duration effect on synthesized graphene oxide for dye-sensitized solar cells.

This study investigates the effects of stirring duration on the synthesis of graphene oxide (GO) using an improved Hummers' method. Various samples are examined under different stirring durations (20, 40, 60, 72, and 80 h). The synthesized GO samples are evaluated through X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. The GO sample with 72 h stirring duration (GO72) has the highest d-spacing in the XRD results, highest atomic percentage of oxygen in EDX (49.57%), highest intensity of oxygen functional group in FTIR spectra, and highest intensity ratio in Raman analysis (ID/IG = 0.756). Results show that GO72 with continuous stirring has the highest degree of oxidation among other samples. Electrochemical impedance spectroscopy analysis shows that GO72-titanium dioxide (TiO2) exhibits smaller charge transfer resistance and higher electron lifetime compared with the TiO2-based photoanode. The GO72 sample incorporating TiO2 nanocomposites achieves 6.25% photoconversion efficiency, indicating an increase of more than twice than that of the mesoporous TiO2 sample. This condition is fully attributed to the efficient absorption rate of nanocomposites and the reduction of the recombination rate of TiO2 by GO in dye-sensitized solar cells.

Development of hydrophobic reduced graphene oxide as a new efficient approach for photochemotherapy.

Nowadays, chemotherapy is one of the crucial and common therapies in the world. So far, it has been revealed to be highly promising, yet patients suffer from the consequences of severe negative medical dosages. In order to overcome these issues, the enhancement of photothermal chemotherapy with reduced graphene oxide (rGO) as a photothermal agent (PTA) is widely utilised in current medical technologies. This is due to its high near-infrared region (NIR) response, in vitro or in vivo organism biocompatibility, low risk of side effects, and effective positive results. Moreover, rGO not only has the ability to ensure that selective cancer cells have a higher mortality rate but can also improve the growth rate of recovering tissues that are untouched by necrosis and apoptosis. These two pathways are specific diverse modalities of cell death that are distinguished by cell membrane disruption and deoxyribonucleic acid (DNA) disintegration of the membrane via phosphatidylserine exposure in the absence of cell membrane damage. Therefore, this review aimed to demonstrate the recent achievements in the modification of rGO nanoparticles as a PTA as well as present a new approach for performing photochemotherapy in the clinical setting.

Facile Synthesis of High Quality Graphene Oxide from Graphite Flakes Using Improved Hummer's Technique.

Graphene is a promising candidate for making next-generation nanotechnology devices due to its outstanding properties in terms of physical, chemical, mechanical aspects. Based on the theoretical point of view, graphene is a two-dimensional (2D) crystal structure with sp2 hybridized carbon atoms arrangement and has attracted extensive attention in a considerable number of applications such as solar energy, sensor and energy storage, naming a few. Herein, graphene oxide (GO) is synthesized from graphite flakes using the Improved Hummer's method. The results demonstrated the comparison of synthesized GO samples based on stirred duration of 6 h and 72 h. The FTIR results proved that the 72 h GO sample was well-bonded with the C-O functional group, signifying the successful synthesis of GO under an extended stirred duration. The FESEM images showed that the synthesized GO was well-arranged in crystal lattice of graphene sheets whereas the EDX result showed that higher atomic % of Oxygen, O2 was obtained with a longer stirred duration due to the high opportunity for oxygenated bonded to occur on the C-C functional group.