Evaluating emissions and air quality implications of residential waste incineration.

In Europe mainly at winter season the PM levels exceed air quality limits, which correlated with the operation of solid-fired boilers. More and more people are returning to using these devices due to energy shortage caused by the pandemic and regional conflicts. In addition, the phenomena of co-burning fuels and municipal waste in residential boilers in primarily fuel poverty households increases further the amount of pollutants in the atmosphere. This study aims to correlate the quantity and quality of air pollutants with the type of fuel (wood and wastes) burned. Combustion experiments were conducted using oak fuel mixed with three waste groups: (1) plastics (PP, HDPE, PET); (2) textiles (polyester-PES, cotton-COT); and (3) papers (cardboard-CARD, glossy coated paper-GCP, 84C/PAP). The addition of waste to wood fuel altered the morphology of emitted particles. While waste burning doesn't always increase particle quantity, it significantly raises PAH concentrations. A strong relationship exists between waste type, particle morphology, and PAH quality, where with lower molecular weight PAHs linked to tar agglomerates and higher ones to soot agglomerates with inorganic crystals.

Evaluation of flue gas emission factor and toxicity of the PM-bounded PAH from lab-scale waste combustion.

Atmospheric particulate matter (PM) has a significant threat not only to human health but also to our environment. In Hungary, 54% of PM10 comes from residential combustion, which also includes the practice of household waste burning. Therefore, this work aims to investigate the quality of combustion through the flue gas concentrations (CO, CO2, O2) and to identify and evaluate the negative impacts of PM and PAHs generated during controlled lab-scale combustion of different mixed wastes (cardboard and glossy paper, polypropylene and polyethylene terephthalate, polyester and cotton). Mixed wastes were burnt in a lab-scale tubular furnace at different temperatures with 180 dm3/h air flow rate. Chemical analyses were coupled with ecotoxicological tests using the bioluminescent bacterium Vibrio fischeri. Ecotoxicity was expressed as toxic unit (TU) values, toxic equivalent factors (TEF) were also presented. During the combustion same amount of O2 enters the reaction, but a different amount CO2 is generated due to the C content of the sample. The waste with highest C-content related to the highest CO2 emission. Increasing the combustion temperature produces more PM-bound PAHs, which remains the same composition in the case of plastic and textile groups. The TU of solid contaminants decreases with increasing combustion temperature and increases with the minerals which are left behind in the water from the solid contaminants.

Investigation of gaseous and solid pollutants emitted from waste tire combustion at different temperatures.

Consumer society requires the continuous evolution of products, thus generating a lot of waste. The automotive industry has also undergone significant development, generating 1.5 billion used tires worldwide every year. Landfilling of tires is prohibited and their disposal is therefore a major issue. Although many studies deal with the utilization of tire as a fuel, there is limited research that would specifically describe the relationship between pollutant emissions from tire combustion and the relationship between emitted pollutants and firebox temperature. Based on this, this work aims to investigate flue gas concentrations (CO, CO2, NOx, and SO2) and solid pollutants from tire burned in a lab-scale electrical furnace at firebox temperature from 650 to 900 °C. The decomposition of the CaCO3 filler during the combustion of the tire has been detected with thermal analytical investigation and combustion experiments. In the case of the CO flue gas pollutant, a second maximum concentration is observed due to the presence of CaCO3. With the increasing firebox temperature, the size of solid particles decreases, and the mesh structure formed becomes denser. At the same time, the concentration of emitted solid PAHs decreases, dominated by aromatic compounds with smaller number of rings. However, the variation of firebox temperature does not affect the amount of benzo(b)fluoranthene and fluoranthene relative to the total concentration.