Interplay between oceanic subduction and continental collision in building continental crust.

Generation of continental crust in collision zones reflect the interplay between oceanic subduction and continental collision. The Gangdese continental crust in southern Tibet developed during subduction of the Neo-Tethyan oceanic slab in the Mesozoic prior to reworking during the India-Asia collision in the Cenozoic. Here we show that continental arc magmatism started with fractional crystallization to form cumulates and associated medium-K calc-alkaline suites. This was followed by a period commencing at ~70 Ma dominated by remelting of pre-existing lower crust, producing more potassic compositions. The increased importance of remelting coincides with an acceleration in the convergence rate between India and Asia leading to higher basaltic flow into the Asian lithosphere, followed by convergence deceleration due to slab breakoff, enabling high heat flow and melting of the base of the arc. This two-stage process of accumulation and remelting leads to the chemical maturation of juvenile continental crust in collision zones, strengthening crustal stratification.

Magmatic record of India-Asia collision.

New geochronological and geochemical data on magmatic activity from the India-Asia collision zone enables recognition of a distinct magmatic flare-up event that we ascribe to slab breakoff. This tie-point in the collisional record can be used to back-date to the time of initial impingement of the Indian continent with the Asian margin. Continental arc magmatism in southern Tibet during 80-40 Ma migrated from south to north and then back to south with significant mantle input at 70-43 Ma. A pronounced flare up in magmatic intensity (including ignimbrite and mafic rock) at ca. 52-51 Ma corresponds to a sudden decrease in the India-Asia convergence rate. Geological and geochemical data are consistent with mantle input controlled by slab rollback from ca. 70 Ma and slab breakoff at ca. 53 Ma. We propose that the slowdown of the Indian plate at ca. 51 Ma is largely the consequence of slab breakoff of the subducting Neo-Tethyan oceanic lithosphere, rather than the onset of the India-Asia collision as traditionally interpreted, implying that the initial India-Asia collision commenced earlier, likely at ca. 55 Ma.

[Raman active vibrations of aluminosilicates].

Raman spectra of aluminosilicate minerals, namely kyanite, andalusite, and sillimanite and K2O-Al2O3-SiO2 glasses were recorded. Four alumino-silicon tetrahedral model clusters were calculated by self-consistent (SCF) molecular orbital ab-ini-tio calculation of the quantum chem (QC) method. The result shows a decrease tendency in Raman frequencies in the 800-1200 cm(-1) frequency region with increase in four-coordinated Al content, which is assigned to the Si--Onb symmetry stretching vibrations. The Raman spectra in the 700-800 cm(-1) frequency region is attributed to Al-Onb symmetry stretching vibrations.