Improving capacity for phytoremediation of Vetiver grass and Indian mustard in heavy metal (Al and Mn) contaminated water through the application of clay minerals.

One of the consequences of mining is the release of heavy metals into the environment, especially water bodies. Phytoremediation of areas contaminated by heavy metals using Vetiver grass and Indian mustard is cost-effective and environmentally friendly. This study aimed at enhancing remediation of heavy metal contaminated water through the simultaneous hybrid application of clay minerals (attapulgite and bentonite) and Vetiver grass or Indian mustard. A 21-day greenhouse experiment was carried out to investigate the effectiveness of the clay minerals to improve heavy metal phytoremediation. The highest accumulation of aluminium (Al) by Vetiver grass was 371.8 mg/kg in the BT2.5VT treatment, while for Mn, the highest accumulation of 34.71 mg/kg was observed in the AT1VT treatment. However, Indian mustard showed no significant uptake of heavy metals, but suffered heavy metal toxicity despite the addition of clay minerals. From this study, it was evident that bentonite added at 2.5% (w/v) could improve the phytoremediation capacity of Vetiver grass for Al and Mn polluted water. The current laboratory-scale findings provided a basis for field trials earmarked for remediation in a post-mining coal environment in South Africa. This remediation approach can also be adopted in other places.

Bioflocculant produced by Bacillus velezensis and its potential application in brewery wastewater treatment.

This study was designed to evaluate the potential of bioflocculant producing strains isolated from wastewater sludge. According to the Plackett-Burman design, the response surface revealed glucose, magnesium sulfate, and ammonium sulfate as critical media components of the nutritional source, whereas the central composite design affirmed an optimum concentration of the critical nutritional source as 16.0 g/l (glucose), 3.5 g/l magnesium sulfate heptahydrate (MgSO4.7H2O), and 1.6 g/l ammonium sulfate ( (NH4)2SO4), yielding an optimal flocculation activity of 96.8%. Fourier Transformer Infrared Spectroscopy (FTIR) analysis confirmed the presence of hydroxyl, carboxyl and methoxyl in the structure of the bioflocculant. Additionally, chemical analysis affirmed the presence of mainly a polysaccharide in the main backbone of the purified bioflocculant with no detection of protein. Energy Dispersive X-ray analysis affirmed the presence of chlorine, phosphorous, oxygen and chlorine as representatives of elemental composition. Thermogravimetric (TGA) analysis revealed over 60% weight was retained at a temperature range of 700 °C. The purified bioflocculant remarkably removed chemical oxygen demand, biological oxygen demand and turbidity in brewery wastewater. This study suggested that the bioflocculant might be an alternate candidate for wastewater treatment.

Effectiveness of cattle dung biogas digestate on spinach growth and nutrient uptake.

New farming techniques should be introduced to improve yield quality and quantity while taking preservation of the environment into consideration. This study investigated effectiveness of cattle dung biogas digestate on spinach growth and nutrient uptake. Spinach was grown with cattle dung biogas digestate (BD), inorganic fertiliser (IF) and unfertilised control (CO) treatments under complete randomised design field conditions. Spinach planted under BD showed significantly higher growth in terms of plant height and number of leaves compared to spinach under CO and IF. A linear relationship between leaf numbers and leaf area index (LAI) (R2 0.691, p < 0.0001) was established for the study. Cattle dung biogas digestate (BD) plants produced significantly the longest roots followed by IF plants. The IF plants produced more biomass per rooting depth (0.85 g cm-1) than BD (0.61 g cm-1) and CO (0.35 g cm-1). Regarding macronutrient content of the spinach leaves, significant differences were only observed for potassium (K) in the order of IF (8.6 g kg-1), BD (6.8 g kg-1), and CO (6.7 g kg-1). Significantly higher amounts of zinc (Zn2+) accumulated in spinach leaves under BD compared to IF and CO. Fertilising spinach with BD improves growth and development just as much as IF. Additional benefits include improving nutrient content of the spinach, assisting with environmental preservation and decreasing production cost.

Evaluating the treatment of heavy metals in acidic wastewater by activated carbon.

The study investigated the use of activated carbon (AC), produced from pinewood, to remove copper, zinc and iron from modified landfill leachates. South Africa faces an imminent water crisis, hence the need to see wastewater as an important source that must be treated and reused to combat water deficits in future. The use of AC as a soil amendment for the removal of heavy metals (HM) is not well researched. This study aimed to determine the ideal amount of AC (5%, 10%, 15% and 20% [w/w]) to add to soil using leaching columns for optimum HM adsorption. Modified acidic wastewater (pH > 2) was leached through soil columns packed with sandy loam soil and different amounts of AC (5%, 10%, 15% and 20% [w/w]). The results indicated that all the columns efficiently removed 94% copper, 80% zinc and 99% iron. Even a small amount (5% w/w) of AC was effective in removing HMs and can thus be considered as a possible cost-effective treatment option for acidic wastewater.

Satellite-based application in drought disaster assessment using terra MOD13Q1 data across free state province, South Africa.

Terra MOD13Q1 satellite data were used to assess drought disaster events and its spatiotemporal patterns over the Free State Province, South Africa between 2001 and 2019. Moderate Resolution Imaging Spectroradiometer (MODIS) products and climate data downloaded from Application for Extracting and Exploring Analysis Ready Samples" (AppEEARS) and NASA: Prediction of Worldwide Energy Resource databases, respectively were used in the study area. After acquiring MODIS data with the area of interest extracted using field sample and the layers of interest: using Enhanced Vegetation Index (EVI) and pixel reliability and defining the output as GeoTIFF with geographic projection, R programming was used for the analysis. This study also evaluated Standardized Precipitation Index (SPI) to further identify meteorological drought, computed at various time scales utilising information acquired from the Global Drought Observatory database. The results show and identify the years that are water-stressed in the study area, which indicated that low vegetation abundance and high temperature in the Free State Province occurred in 2000, 2008, and 2009. The result also shows that the summer season over large parts of the study region is characterized by moderate to extreme drought while winter seasons have light drought conditions during the same time. Seasonal and inter-annual comparisons of drought events outlined in the Vegetation Condition Index (VCI) provided a useful tool for analysing the temporal and spatial evolution of regional drought and for estimating potential environmental impacts. Drought events occurrence in the study area is less frequent and milder in winter months while summer droughts of different years were more severe. The results of this study can also be used as a tool for monitoring droughts and support for decision making in the evaluation and management of regional drought, for disaster preparedness.

Drought disaster monitoring using MODIS derived index for drought years: A space-based information for ecosystems and environmental conservation.

Drought disaster is one of the major factors restricting the development of vegetation across a wide variety of environments. Monitoring the temporal and spatial dynamics of drought episodes in the study area is crucial for environmental and ecosystem conservation. This study assesses drought disaster by utilising space-based data and R programming for drought years 2003, 2007, 2012 and 2019 in the Free State Province, South Africa. Results revealed that the study area witnessed drought events in the year 2003 where March, August, September, October, November and December were more affected by drought disaster events. It was further observed that February and March were affected by extreme drought conditions in the year 2007. In year 2012, January, October, November and December, there exist moderate to severe drought conditions in the study area where some regions were more affected than the other. Finally, year 2019 witnessed variations in drought event distributions across the months with January, October and November witnessing severe to extreme drought conditions from about 0 to 30% drought values. Overall, this study shows that the 16-day Terra-MODIS composite and EVI products are sensitive to stressors associated with drought. The Vegetation Condition Monitoring Index (VCI) based on MODIS is suited for monitoring drought disasters. The technique used in this study revealed the suitability of MODIS data for assessing drought conditions and their potential environmental impacts.

Systematic mapping of disaster risk management research and the role of innovative technology.

Globally, disaster risk management (DRM) has gone through a criterion transpose from static to a technology-based proactive approach in managing disasters including natural and anthropogenic disasters. This study aimed at exploring this research niche and to identify the main topical issues currently underway, such as the most disaster risk management techniques and prevalent geographical locations using scientometrics techniques. The result reveals that studies on DRM during the period of investigation witnessed an increase from early 2000 and peaking in 2017 followed by 2016 with a Kolmogorov-Smirnoff goodness-of-fit of 0.9672. More so, there exists a decline in year 2018 with about 144 published articles on DRM. However, research output fluctuated during the survey period between 1990 and 2004; for instance, the result shows that the research published on DRM in year 1990, 1991, 1992, 1993, 1994 and 1995 are six, seven, five, seven, three and seven articles, respectively. In this study, the contribution of different nations and country collaboration to different sub-categories of disasters was examined. Global distributions of scientific articles tailored to DRM research across different environmental and disaster issues that demonstrate the development of analytical tools used to detect them and the researchers' production from various nations in both developed and developing countries were evaluated. Despite the recurrence of climate-related disasters in some parts of the world, relevant studies, disaster impacts and support systems remain poorly understood and not well explored.

The Influence of Non-Engineered Municipal Landfills on Groundwater Chemistry and Quality in Bloemfontein, South Africa.

This study assessed the groundwater quality around two municipal solid waste landfill sites, in the city of Bloemfontein, Free State Province, South Africa. The two landfill sites are located in two contrasting geological terrains, with both lacking some basic facilities found in a well-designed landfill. A total of eight groundwater samples were collected from pollution monitoring boreholes near the two landfill sites, with five samples representing the northern landfill site and three samples representing the southern landfill site. The samples were collected in the autumn and winter seasons to assess any possible seasonal variations. They were analysed for physicochemical (pH, electrical conductivity (EC), total dissolve solids (TDS), chemical oxygen demand (COD) and total organic carbon (TOC)) and microbiological parameters (Escherichia coli, total coliform). The results of the analysis showed that the waters from both landfills were generally dominated by Ca, Mg, SO4, and HCO3 ions. Some of the major anions and cations in the water samples were above the South African National Standard (SANS241:2015) and World Health Organisation (WHO) permissible limits for drinking water. Majority of the boreholes had total dissolved solids and electrical conductivity values exceeding the SANS 241:2015 and WHO permissible limits. Piper trilinear plots for the two landfill sites showed that Ca(Mg)HCO3 water type predominates, but Ca(Mg)SO4 and Ca(Mg)Cl were also found. These water types were further confirmed with expanded Durov diagrams, indicating that that the boreholes represented a water type that is seldom found which is undergoing ion exchange, typical of sulphate contamination. From the SAR diagrams, boreholes in the northern landfill site had a high salinity hazard with only one borehole in the southern landfill site having a high salinity hazard. The geology was found to play a significant role in the distribution of contaminants into the groundwater systems in the study area. The study concluded that the northern landfill site had a poorer water quality in comparison to the southern landfill site based on the analysed physicochemical parameters. However, the southern landfill site showed significant microbial contamination, due to the elevated amount of E. coli and total coliform concentrations. The high permeability of the weathered dolerites in the northern landfill site might have enabled the percolation of contaminants into the groundwater resulting in the poorer water quality.

Investigating Industrial Effluent Impact on Municipal Wastewater Treatment Plant in Vaal, South Africa.

Industrial effluents with high concentrations of toxic heavy metals are of great concern because of their persistence and non-degradability. However, poor operation and maintenance of wastewater treatment infrastructure is a great concern in South Africa. In this study, physico-chemical parameters and heavy metals (HMs) concentration of wastewater from five different industries, Leeuwkuil wastewater treatment plant (WWTP) inflow and effluent, and Vaal River water samples were monitored between January and September 2017, to investigate the correlation between heavy metal pollution and the location of industries and ascertain the effectiveness of the municipal WWTP. Physico-chemical variables such as pH, biological oxygen demand (BOD), dissolved oxygen (DO), chemical oxygen demand (COD), total dissolved solids (TDS) and electrical conductivity (EC) exhibited both temporal and spatial variations with the values significantly higher in the industrial samples. Inductively coupled plasma optical emission spectrometry (ICP-OES) results also showed that aluminium (Al), copper (Cu), lead (Pb) and zinc (Zn) were significantly higher in industrial effluents (p < 0.05), with only Zn and Al exhibiting significant seasonal variability. Statistical correlation analysis revealed a poor correlation between physicochemical parameters and the HMs compositional quality of wastewater. However, toxic HMs (Zn, Cu and Pb) concentrations in treated wastewater from WWTP were above the permissible limits. Although the WWTP was effective in maintaining most of the wastewater parameters within South African Green drop Standards, the higher Cu, Zn, Pb and COD in its final effluent is a concern in terms of Vaal river health and biological diversity. Therefore, we recommend continuous monitoring and maintenance of the WWTPs infrastructure in the study area.

Comparative nutrient leaching capability of cattle dung biogas digestate and inorganic fertilizer under spinach cropping condition.

A field experiment was used to determine leaching capability of biogas digestate used as soil amendment in comparison to inorganic fertilizer under spinach cropping condition. The biogas digestate used in this experiment was obtained from a biogas production plant that used cattle dung as feedstock. Spinach was cultivated under three treatments, namely, biogas digestate (BD), inorganic fertilizer (IN) and control (no fertilizer or biogas digestate). All the treatments were replicated three times. Irrometer soil solution access tubes were inserted in the middle of each plot for the collection of the nutrient leachates. The leaf area of spinach was significantly higher in IN treatment than BD and control at the harvest stage; BD produced higher fresh mass (479 g/plant) than IN (468 g/plant) and control (201 g/plant). The leachates of inorganic fertilizer showed higher nutrient concentration compared to biogas digestate and control treatments. Twenty-eight days after transplanting, the leachate consisted of 3670.7, 12.12 and 8.5 mg/l of ammonium and 408, 83 and 39 mg/l of phosphate at IN, BD and control treatments, respectively. The study demonstrates that cattle dung biogas digestate can be applied on soil as fertilizer for crops with little or no environmental consequences to water resources and still have the same product quality as inorganic fertilizer.

A community survey of the pattern and determinants of household sources of energy for cooking in rural and urban south western, Nigeria.

INTRODUCTION: The use of solid fuels for cooking is associated with indoor pollution and lung diseases. The objective of the study was to determine the pattern and determinants of household sources of energy for cooking in rural and urban South Western, Nigeria. METHODS: We conducted a cross sectional study of households in urban (Ado-Ekiti) and rural (Ido-Ekiti) local council areas from April to July 2010. Female respondents in the households were interviewed by trained interviewers using a semi-structured questionnaire. RESULTS: A total of 670 households participated in the study. Majority of rural dwellers used single source of energy for cooking (55.6%) and urban dwellers used multiple source of energy (57.8%). Solid fuel use (SFU) was higher in rural (29.6%) than in urban areas (21.7%). Kerosene was the most common primary source of energy for cooking in both urban and rural areas (59.0% vs.66.6%) followed by gas (17.8%) and charcoal (6.6%) in the urban areas, and firewood (21.6%) and charcoal (7.1%) in the rural areas. The use of solid fuel was strongly associated with lack of ownership of dwellings and larger household size in urban areas, and lower level of education and lower level of wealth in the rural areas. Kerosene was associated with higher level of husband education and modern housing in urban areas and younger age and indoor cooking in rural areas. Gas was associated with high income and modern housing in the urban areas and high level of wealth in rural areas. Electricity was associated with high level of education, availability of electricity and old age in urban and rural areas respectively. CONCLUSION: The use of solid fuel is high in rural areas, there is a need to reduce poverty and improve the use of cleaner source of cooking energy particularly in rural areas and improve lung health.

Pattern of respiratory diseases seen among adults in an emergency room in a resource-poor nation health facility.

INTRODUCTION: There is a paucity of information on utilisation of emergency medical services in Nigeria. This study was conducted to determine the pattern of respiratory diseases seen among adults in an emergency room(ER) and their mortality within twenty- four hours in a health facility in Nigeria. METHODS: We carried out a retrospective study on adult patients that presented with respiratory condition from November 2004 to December 2010 at the emergency room of Federal Medical Centre Ido-Ekiti, south western, Nigeria. RESULTS: A total of 3671 cases were seen, 368 were respiratory cases accounting for 10.2 % of the total emergency room visitations. The male to female patients ratio was 1.2:1 and their mean was 49 9 ± 20.3 years. Pneumonia (34.5%) was the most common cases seen in the ER, followed PTB (29.4%), acute asthma (24.5%) , acute exacerbation of COPD (10.3%), upper airway tract obstruction and malignant pleural effusion were 0.5% respectively. Fourteen of the PTB cases (3.8%) were complicated by cor-pulmonale, 9(2.5%) by pleural effusion, 4(1.1%) by massive haemoptysis and 2(0.5%) by pneumothorax. Twenty-four hours mortality was 7.4% and 44.4% of the death was due to PTB, 37.0% was due to pneumonia and 14.8% due to acute asthma attack. The overall mortalities also had a bimodal age group distribution as the highest death was recorded in ages 30-39 and ≥ 70 years. CONCLUSION: Pneumonia and PTB were the leading respiratory diseases among adults causing of emergency room visit and early mortality in this health facility in Nigeria.

Influence of diffuse and chronic metal pollution in water and sediments on edible seafoods within Ondo oil-polluted coastal region, Nigeria.

The bioconcentration levels of 3 non-essential elements (Pb, Cd and Ni) have been investigated in three different seafoods; Fish (Tilapia zilli), Crab (Callinectes sapidus) and periwinkle (Littorina littorea), to investigate the ecosystem health status in Ondo oil-polluted coastal region, Nigeria. The seafood samples were chosen based on their popularity as a food source and the potential of the species to contain high levels of metals based on past research results. Metal concentrations in the biota showed marked interspecific differences with C. sapidus recording the highest concentrations of all the metals. The bioconcentration factor (BCF) showed that C. sapidus and T. zilli have the greatest potential to concentrate Cd (BCF = 3-10) and Pb (BCF = 11-84) respectively. Lead uptake from both water and sediment (BCF ≈ BSAF: 0.003-0.018) were abysmally low in L. littorea as compared with other organisms. The high concentrations of Pb in fish species, effective bioaccumulation of Cd in species of crab and periwinkles, as well as very high BSAF of Ni found in species of crab indicated a strong influence from anthropogenic pollutant source on the biotic community. Oil pollution appears to be a major source of bioavailable metal contaminants for the selected biota. The study shows that C. sapidus and L. littorea can effectively compartmentalize potentially toxic metals such as Cd, Pb and Ni within their tissues. In terms of toxicity, C. sapidus had Cd concentrations greater than the 3,000 ng/g limit set by the Commission of the European Communities while Pb concentration exceeded their limits in both C. sapidus and T. zilli. All levels of Ni were below the U.S. Food and Drug Administration action levels for these metals in fish, crustaceans and shellfish. The study revealed anthropogenic enrichment of the metals studied which can possibly pose potential threats to the ecology of the area.