Effect of the Addition of Fique Bagasse Cellulose Nanoparticles on the Mechanical and Structural Properties of Plastic Flexible Films from Cassava Starch.

One of the activities most representative of the agricultural sector in Colombia is the production of biodegradable fique fiber. The efficiency of the defiberization process of the fique leaves is very low since a mere 4% of the total weight of the leaf (cabuya) is used and marketed. The remaining 96%, composed of fique juice and bagasse, is considered to be waste and discarded, impacting the environment. The aim of this work was to study fique bagasse as a source of cellulose nanoparticles (CNCs). CNCs were obtained by acid hydrolysis and added at 10% to films made from cassava thermoplastic starch (TPS) by the casting method. Structural changes in the CNCs, TPS, and their mixtures were characterized by FTIR-ATR and their morphology and particle size by SEM and TEM microscopy, respectively. Thermal properties were analyzed using DSC and TGA, along with their effect on mechanical properties. Changes in the FTIR spectra indicated that the chemical method adequately removed hemicellulose and lignin from the fiber surface of fique bagasse. The CNCs showed a diameter and length of 7.5 ± 3.9 and 52.7 ± 18.1 nm, respectively, and TPS 10% CNC obtained an increase in mechanical strength of 116%. The obtainment of CNCs from lignocellulosic materials can thus be viewed as a favorable option for the subsequent reinforcement of a polymeric matrix.

A review of trends in the development of bionanocomposites from lignocellulosic and polyacids biomolecules as packing material making alternative: A bibliometric analysis.

Contamination caused by the accumulation of petrochemical-based plastics has reached worrying magnitudes and led to the development of biopolymers as an option to mitigate the problem. This work thus presents a bibliometric analysis of all that concerns the development of such bionanocomposite materials, using ScientoPy and SciMAT software to establish associations between the number of published documents, countries, institutions and most relevant topics. The bionanocomposites topic was found to throw up the biggest number of documents associated (2008) with the different types of raw materials and methods used to obtain nanoparticles and their combination with biopolymeric materials, the result known as a "bionancomposite*". Analysis of the documents related to the application for development of packaging materials from biological molecules, carbohydrate polymers, compounds, conjugates, gels, glucans, hydrogels, membranes, mucilage (source unspecified), mucoadhesives, paper, polymers, polysaccharide, saccharides etc, is also presented, emphasizing mechanical, thermal and barrier properties, which, due to the inclusion of nanoparticles mainly from natural sources of cellulose, show increases of up to 30%. The inclusion of nanoparticles, especially those derived from cellulose sources, generally seeks to increase the properties of bionanocomposite materials. Regarding an increase in mechanical properties, specifically tensile strength, inclusions at percentages not exceeding 10 wt% can register increases that exceed 30% were reported.