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This work reports a high-performance InGaN-based red-emitting LED with a strain-release interlayer (SRI) consisting of an InGaN stress-release layer (SRL) and an AlN dislocation confinement layer (DCL) in unintentionally doped GaN (u-GaN). The SRL introduces a tensile strain which could decrease the in-plane compressive stress of the u-GaN layer, while the DCL could reduce the dislocation density and thus improve the crystal quality of the u-GaN layer. Consequently, a high-efficiency InGaN-based red-emitting LED with a peak wavelength of 651â nm and an external quantum efficiency of 6.04% is realized. In addition, the room-temperature photoluminescence (PL) mapping emission wavelength is uniform across a 4-inch wafer with a standard deviation of 3.3â nm. Therefore, the proposed SRI offers good potential for mass-producing high-performance and long-wavelength InGaN-based red-emitting LEDs.
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Metal halide perovskite materials, which combine outstanding physical properties, large absorption coefficient, tailored composition, and low-cost solution-processing, have aroused wide attention for use in various optoelectronic devices. Recently, perovskite single crystals have been rapidly outpacing traditional semiconductor materials in the field of radiation detection. As a prerequisite, achieving high-quality single crystals under controllable solution-phase growth must be tackled to fulfill their full potential as a new paradigm in this stagnated field. This Perspective summarizes the advances in X-ray detectors based on lead halide perovskite single crystals, presenting a comprehensive picture of the relationship among composition engineering, synthesis, and device properties. Additionally, we share our thoughts on several outstanding challenges of perovskite single crystals as promising X-ray detectors and propose possible approaches to the unresolved issues. We anticipate that this Perspective can open up new opportunities to improve their optoelectronic properties, which confers fascinating photonics applications with above and beyond state-of-the-art performance.
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Visible and infrared persistent phosphors have gained considerable attention in recent years and are being widely used as glow-in-the-dark materials in dark environments. In contrast, the progress in persistent phosphors emitting at the other end of the spectrum, i.e., the shorter-wavelength ultraviolet-C (UVC; 200-280 nm), is rather slow. Here we report the design and synthesis of a well-performing Pr3+-doped UVC emissive persistent phosphor, Lu2SiO5:Pr3+, which exhibits intense UVC persistent luminescence peaking at 270 nm and a long persistence time of more than 12 h after excitation with a 254 nm UV lamp. Besides, the UVC persistent luminescence of a UV pre-irradiated sample can be repeatedly revived after repeated short-illumination with low-energy white light via a process called photostimulated persistent luminescence. Owing to the distinct spectral features of UVC light and the self-sustained luminescence properties, the UVC persistent luminescence of the Lu2SiO5:Pr3+ persistent phosphor can be clearly monitored and imaged using a corona camera in bright environments including direct sunlight and indoor light. The Lu2SiO5:Pr3+ persistent phosphor is expected to find promising applications in the covert optical tagging field.
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This work reports the realization of Gd3+ persistent luminescence in the narrowband ultraviolet-B (NB-UVB; 310-313 nm) through persistent energy transfer from a sensitizer of Pr3+, Pb2+ or Bi3+. We propose a general design concept to develop Gd3+-activated NB-UVB persistent phosphors from Pr3+-, Pb2+- or Bi3+-activated ultraviolet-C (200-280 nm) or ultraviolet-B (280-315 nm) persistent phosphors, leading to the discovery of ten Gd3+ NB-UVB persistent phosphors such as Sr3Gd2Si6O18:Pr3+, Sr3Gd2Si6O18:Pb2+ and Y2GdAl2Ga3O12:Bi3+ as well as five ultraviolet-B persistent phosphors such as Y3Al2Ga3O12:Pr3+, Sr3Y2Si6O18:Pb2+ and Y3Al2Ga3O12:Bi3+. The persistent energy transfer from the sensitizers to Gd3+ is very efficient and the Gd3+ NB-UVB afterglow can last for more than 10 hours. This study expands the persistent luminescence research to the NB-UVB as well as the broader ultraviolet-B spectral regions. The NB-UVB persistent phosphors may act as self-sustained glowing NB-UVB radiation sources for dermatological therapy.
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Gadolinio/química , Luminiscencia , Rayos Ultravioleta , Transferencia de Energía , HumanosRESUMEN
Correction for 'Cu2O template synthesis of high-performance PtCu alloy yolk-shell cube catalysts for direct methanol fuel cells' by Sheng-Hua Ye et al., Chem. Commun., 2014, 50, 12337-12340, DOI: 10.1039/C4CC04108A.
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INTRODUCTION: Uterine fibroids are a common benign genital tumor disease in gynecological diseases. It is mainly a change in physical function caused by the growth of smooth muscle cells in the factor uterus. Modern medicine's treatment of this disease is based on the dependence of uterine fibroids on sex hormones. Treatment with antiprogestin and estrogen drugs can reduce the volume of fibroids or slow the rate of increase in volume, thereby achieving the goal of alleviating clinical symptoms. In order to meet the needs of the majority of women of childbearing age and to maintain fertility, acupuncture treatment of uterine fibroids has a broad prospect for development. METHODS/DESIGN: This study plans to select 60 cases that meet the corresponding selection criteria. According to the random principle, they will be divided into intervention group and control group, with 30 cases in each group. The general information, fibroid size, and TCM syndrome scores of the two groups of patients will be compared before treatment. In terms of treatment, the intervention group will be given acupuncture combined therapy; the control group will be given Chinese patent medicine. The treatment cycles in both groups will be three menstrual cycles. After the treatment is completed, the data of the relevant curative effect indicators are analyzed by using SPSS software to draw conclusions. DISCUSSION: We aim to provide higher evidence-based medical evidence for acupuncture treatment of uterine fibroids. TRIAL REGISTRATION: ClinicalTrials.gov, ChiCTR2000030438, Registered on March 01, 2020.
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Terapia por Acupuntura/métodos , Medicamentos Herbarios Chinos/uso terapéutico , Leiomioma/terapia , Neoplasias Uterinas/terapia , Adolescente , Adulto , China , Femenino , Conductas Relacionadas con la Salud , Humanos , Leiomioma/tratamiento farmacológico , Leiomioma/patología , Ciclo Menstrual , Persona de Mediana Edad , Calidad de Vida , Proyectos de Investigación , Índice de Severidad de la Enfermedad , Método Simple Ciego , Neoplasias Uterinas/tratamiento farmacológico , Neoplasias Uterinas/patología , Adulto JovenRESUMEN
Visible-light and infrared-light persistent phosphors are extensively studied and are being used as self-sustained glowing tags in darkness. In contrast, persistent phosphors for higher-energy, solar-blind ultraviolet-C wavelengths (200-280 nm) are lacking. Also, persistent tags working in bright environments are not available. Here we report five types of Pr3+-doped silicates (melilite, cyclosilicate, silicate garnet, oxyorthosilicate, and orthosilicate) ultraviolet-C persistent phosphors that can act as self-sustained glowing tags in bright environments. These ultraviolet-C persistent phosphors can be effectively charged by a standard 254 nm lamp and emit intense, long-lasting afterglow at 265-270 nm, which can be clearly monitored and imaged by a corona camera in daylight and room light. Besides thermal-stimulation, in bright environments, photo-stimulation also contributes to the afterglow emission and its contribution can be dominant when ambient light is strong. This study expands persistent luminescence research to the ultraviolet-C wavelengths and brings persistent luminescence applications to light.
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Red/near-infrared/short-wave infrared multi-band persistent phosphors are developed by doping Pr3+ into MgGeO3 and CdSiO3 hosts, which emit intense, very-long-lasting (>120 h) persistent luminescence at around 625 nm, 900 nm and 1085 nm after ultraviolet light excitation. The penetration power of these three wavelengths in chicken breast follows the order of 1085 nm > 900 nm > 625 nm.
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Current fluorescent nanoparticles-based tracer sensing techniques for oilfield applications suffer from insufficient sensitivity, with the tracer detection limit typically at the several hundred ppm level in untreated oil/water mixtures, which is mainly caused by the interference of the background fluorescence from the organic residues in crude oil under constant external excitation. Here we report the use of a persistent luminescence phenomenon, which enables an external excitation-free and thus background fluorescence-free measurement condition, for ultrahigh-sensitivity crude oil sensing. By using LiGa5O8:Cr(3+) near-infrared persistent luminescent nanoparticles as a tracer nanoagent, we achieved a tracer detection limit at the single-digit ppb level (down to 1 ppb concentration of nanoparticles) in high oil fraction (up to 65 wt.%) oil/water mixtures via a convenient, CCD camera-based imaging technique without any pretreatment or phase separation of the fluid samples. This detection limit is about four to five orders of magnitude lower than that obtained using conventional spectral methods. This study introduces a new type of tracer nanoagents and a new detection method for water tracer sensing in oil reservoir characterization and management.
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We report a new phonon-assisted upconversion excitation design that enables the excitation energy to be lower than the persistent luminescence emission energy in persistent phosphors. We demonstrate this upconversion excitation concept in Zn3Ga2GeO8:Cr(3+) near-infrared persistent phosphor by achieving Cr(3+) 700 nm persistent emission using 800 or 980 nm laser diode excitation. Depending on the sample temperature, the excitation photon energy can be tuned, and the persistent luminescence intensity can be adjusted. Depending on the excitation power, the upconversion trap filling process involves either one photon (for filling low-energy traps) or two photons (for filling high-energy traps). Our research provides a major step toward manipulating the electronic excitation in persistent luminescence, which has implication for many applications.
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Rayos Infrarrojos , Luminiscencia , Óxidos/química , Fonones , Transporte de Electrón , Galio/química , Germanio/química , Zinc/químicaRESUMEN
We extend the persistent luminescence into the ultraviolet spectral region by developing a new ultraviolet persistent phosphor Sr2MgGe2O7:Pb(2+). The Sr2MgGe2O7:Pb(2+) phosphor exhibits strong persistent luminescence peaking at 370 nm and a long persistence time of >12 h after excitation. The phosphor also exhibits a photo-stimulated persistent luminescence capability.
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The trivalent ytterbium (Yb3+) ion has been extensively used as an emitter in short-wave infrared (SWIR) lasers, a sensitizer to activate other lanthanide ions for up-conversion luminescence, and a spectral converter in Ln3+-Yb3+ doubly doped quantum cutting phosphors. Here we report a new function of the Yb3+ ion-as an efficient emitting center for SWIR persistent luminescence. We have developed the first real SWIR persistent phosphor, MgGeO3:Yb3+, which exhibits very-long persistent luminescence at around 1000 nm for longer than 100 h. The MgGeO3:Yb3+ phosphor is spectrally transparent to visible/near-infrared light (~400-900 nm) and is a promising ultraviolet-to-SWIR spectral convertor. The MgGeO3:Yb3+ phosphor also exhibits a photostimulated persistent luminescence capability, where the SWIR persistent emission in an ultraviolet-light pre-irradiated sample can be rejuvenated by low-energy light (white or red light) stimulation. The MgGeO3:Yb3+ phosphor is expected to have promising applications in biomedical imaging, night-vision surveillance and photovoltaics.
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The 8-layered shifted hexagonal perovskite compound Ba8ZnNb6O24 was isolated via controlling the ZnO volatilization, which features long-range B-cation ordering with nanometer-scale separation by â¼1.9 nm of octahedral d(10) cationic (Zn(2+)) layers within the purely corner-sharing octahedral d(0) cationic (Nb(5+)) host. The long-range ordering of the B-site vacancy and out-of-center distortion of the highly-charged d(0) Nb(5+) that is assisted by the second-order Jahn-Teller effect contribute to this unusual B-cation ordering in Ba8ZnNb6O24. A small amount (â¼15%) of d(10) Sb(5+) substitution for Nb(5+) in Ba8ZnNb6-xSbxO24 dramatically transformed the shifted structure to a twinned structure, in contrast with the Ba8ZnNb6-xTaxO24 case requiring 50% d(0) Ta(5+) substitution for Nb(5+) for such a shift-to-twin transformation. Multiple factors including B-cationic sizes, electrostatic repulsion forces, long-range ordering of B-site vacancies, and bonding preferences arising from a covalent contribution to the B-O bonding that includes out-of-center octahedral distortion and the B-O-B bonding angle could subtly contribute to the twin-shift phase competition of B-site deficient 8-layered hexagonal perovskites Ba8B7O24. The ceramics of new shifted Ba8ZnNb6O24 and twinned Ba8ZnNb5.1Sb0.9O24 compounds exhibited good microwave dielectric properties (εr â¼ 35, Qf â¼ 36 200-43 400 GHz and τf â¼ 38-44 ppm/°C).
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Photodynamic therapy is a promising treatment method, but its applications are limited by the shallow penetration of visible light. Here, we report a novel X-ray inducible photodynamic therapy (X-PDT) approach that allows PDT to be regulated by X-rays. Upon X-ray irradiation, the integrated nanosystem, comprised of a core of a nanoscintillator and a mesoporous silica coating loaded with photosensitizers, converts X-ray photons to visible photons to activate the photosensitizers and cause efficient tumor shrinkage.
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Preparaciones de Acción Retardada/administración & dosificación , Nanocápsulas/efectos de la radiación , Neoplasias Experimentales/tratamiento farmacológico , Fotoquimioterapia/métodos , Fármacos Fotosensibilizantes/administración & dosificación , Supervivencia Celular/efectos de los fármacos , Supervivencia Celular/efectos de la radiación , Preparaciones de Acción Retardada/química , Preparaciones de Acción Retardada/efectos de la radiación , Luz , Nanocápsulas/química , Nanocápsulas/ultraestructura , Neoplasias Experimentales/patología , Fármacos Fotosensibilizantes/química , Resultado del Tratamiento , Terapia por Rayos X/métodos , Rayos XRESUMEN
Up-conversion luminescence and long-persistent luminescence are two well-studied, special luminescence processes. By combining the unique features of these two luminescence processes, here we design a new luminescence process called up-converted persistent luminescence (UCPL), which enables us to generate persistent luminescence having an emission energy higher than the excitation energy. Guided by the UCPL concept, we create the first UCPL phosphor Zn3Ga2GeO8:1%Cr3+, 5%Yb3+, 0.5%Er3+ by incorporating an up-converting ion pair Yb3+/Er3+ into a Zn3Ga2GeO8:1%Cr3+ near-infrared persistent phosphor. After being excited by a 980 nm laser, the phosphor emits long-lasting (>24 h) near-infrared persistent emission peaking at 700 nm. The UCPL concept and the associated phosphors are expected to have important implications for several fields such as biomedical imaging.
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Eu(2+)-activated phosphors are being widely used in illuminations and displays. Some of these phosphors feature an extremely broad and red-shifted Eu(2+) emission band; however, convincing explanation of this phenomenon is lacking. Here we report a new localized/delocalized emitting state of Eu(2+) ions in a new hexagonal EuAl(2)O(4) phosphor whose Eu(2+) luminescence exhibits a very large bandwidth and an extremely large Stokes shift. At 77 K, two luminescent sites responsible for 550 nm and 645 nm broadband emissions are recognized, while at room temperature only the 645 nm emission band emits. The 645 nm emission exhibits a typical radiative lifetime of 1.27 µs and an unusually large Stokes shift of 0.92 eV. We identify the 645 nm emission as originating from a new type of emitting state whose composition is predominantly that of localized 4f(6)5d character but which also contains a complementary component with delocalized conduction-band-like character. This investigation provides new insights into a unique type of Eu(2+) luminescence in solids whose emission exhibits both a very large bandwidth and an extremely large Stokes shift.
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In vivo fluorescence imaging suffers from suboptimal signal-to-noise ratio and shallow detection depth, which is caused by the strong tissue autofluorescence under constant external excitation and the scattering and absorption of short-wavelength light in tissues. Here we address these limitations by using a novel type of optical nanoprobes, photostimulable LiGa5O8:Cr(3+) near-infrared (NIR) persistent luminescence nanoparticles, which, with very-long-lasting NIR persistent luminescence and unique photo-stimulated persistent luminescence (PSPL) capability, allow optical imaging to be performed in an excitation-free and hence, autofluorescence-free manner. LiGa5O8:Cr(3+) nanoparticles pre-charged by ultraviolet light can be repeatedly (>20 times) stimulated in vivo, even in deep tissues, by short-illumination (~15 seconds) with a white light-emitting-diode flashlight, giving rise to multiple NIR PSPL that expands the tracking window from several hours to more than 10 days. Our studies reveal promising potential of these nanoprobes in cell tracking and tumor targeting, exhibiting exceptional sensitivity and penetration that far exceed those afforded by conventional fluorescence imaging.
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Diagnóstico por Imagen/métodos , Mediciones Luminiscentes , Nanopartículas/administración & dosificación , Imagen Óptica/métodos , Animales , Encéfalo/patología , Línea Celular , Supervivencia Celular/efectos de los fármacos , Compuestos de Cromo/administración & dosificación , Compuestos de Cromo/toxicidad , Ácido Gálico/administración & dosificación , Ácido Gálico/análogos & derivados , Ácido Gálico/toxicidad , Compuestos de Litio/administración & dosificación , Compuestos de Litio/toxicidad , Macrófagos/efectos de los fármacos , Ratones , Nanopartículas/efectos de la radiación , Nanopartículas/toxicidad , Rayos UltravioletaRESUMEN
Novel PtCu alloy yolk-shell cubes were fabricated via the disproportionation and displacement reactions in Cu2O yolk-shell cubes, and they exhibit significantly improved catalytic activity and durability for methanol electrooxidation.
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F, Ca co-doped TiO2 was synthesized by a facile one-step hydrothermal method. After doping with F, electrons can be simultaneously excited from valence band to the F doping energy level. The smaller crystal size caused by doping with Ca can exhibit more powerful redox ability and the efficient separation of photogenerated hole-electron pairs. Therefore, F, Ca co-doped TiO2 exhibited enhanced photocatalytic activity.
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The morphogenesis of the silica cell walls (called frustules) of unicellular algae known as diatoms is one of the most intriguing mysteries of the diatoms. To study frustule morphogenesis, optical, electron and atomic force microscopy has been extensively used to reveal the frustule morphology. However, since silica frustules are opaque, past observations were limited to outer and fracture surfaces, restricting observations of interior structures. Here we show that opaque silica frustules can be converted into electronically transparent graphene replicas, fabricated using chemical vapor deposition of methane. Chemical vapor deposition creates a continuous graphene coating preserving the frustule's shape and fine, complicated internal features. Subsequent dissolution of the silica with hydrofluoric acid yields a free-standing replica of the internal and external native frustule morphologies. Electron microscopy renders these graphene replicas highly transparent, revealing previously unobserved, complex, three-dimensional, interior frustule structures, which lend new insights into the investigation of frustule morphogenesis.