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Solution-processed silver nanowire (AgNW) networks have been considered as promising electrode candidates for next-generation electronic devices. However, they suffer from poor thermal and electrical stability and low mechanical properties, hindering their practical applications. In this work, graphene nanosheets are successfully introduced into AgNW via a facile one-step solvothermal process. Benefiting from increased conductive paths, the resultant AgNW/graphene films exhibit high electrical conductivity. More importantly, the interlocking NW morphology can be maintained under high temperature and applied voltage due to suppressed Ag migration, which is enabled by the introduction of graphene. This feature leads to enhanced thermal and electrical stability, making them suitable for use as transparent heaters. Furthermore, the composite films present excellent mechanical performance, and negligible resistance change is observed after 10 000 repeated bending cycles. To demonstrate their feasibility toward sensor applications, sandwiched strain sensors are designed, which can endure larger tensile strains and show higher sensitivity and repeatability compared with pure AgNW-based device. Furthermore, various hand gestures can be easily recognized by the resultant sensors based on unique combinations of sensing response. This work not only provides a low-cost method to realize large-scale synthesis of AgNW/graphene composites but also offers guidance to prepare high-performance electrodes for advanced electronics.
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Wearable and implantable active medical devices (WIMDs) are transformative solutions for improving healthcare, offering continuous health monitoring, early disease detection, targeted treatments, personalized medicine, and connected health capabilities. Commercialized WIMDs use primary or rechargeable batteries to power their sensing, actuation, stimulation, and communication functions, and periodic battery replacements of implanted active medical devices pose major risks of surgical infections or inconvenience to users. Addressing the energy source challenge is critical for meeting the growing demand of the WIMD market that is reaching valuations in the tens of billions of dollars. This review critically assesses the recent advances in energy harvesting and storage technologies that can potentially eliminate the need for battery replacements. With a key focus on advanced materials that can enable energy harvesters to meet the energy needs of WIMDs, this review examines the crucial roles of advanced materials in improving the efficiencies of energy harvesters, wireless charging, and energy storage devices. This review concludes by highlighting the key challenges and opportunities in advanced materials necessary to achieve the vision of self-powered wearable and implantable active medical devices, eliminating the risks associated with surgical battery replacement and the inconvenience of frequent manual recharging.
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Self-powered wearable devices with integrated energy supply module and sensitive sensors have significantly blossomed for continuous monitoring of human activity and the surrounding environment in healthcare sectors. The emerging of MXene-based materials has brought research upsurge in the fields of energy and electronics, owing to their excellent electrochemical performance, large surface area, superior mechanical performance, and tunable interfacial properties, where their performance can be further boosted via multi-interface engineering. Herein, a comprehensive review of recent progress in MXenes for self-powered wearable devices is discussed from the aspects of multi-interface engineering. The fundamental properties of MXenes including electronic, mechanical, optical, and thermal characteristics are discussed in detail. Different from previous review works on MXenes, multi-interface engineering of MXenes from termination regulation to surface modification and their impact on the performance of materials and energy storage/conversion devices are summarized. Based on the interfacial manipulation strategies, potential applications of MXene-based self-powered wearable devices are outlined. Finally, proposals and perspectives are provided on the current challenges and future directions in MXene-based self-powered wearable devices.
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Integrating hydrogel with other materials is always challenging due to the low mass content of hydrogels and the abundance of water at the interfaces. Adhesion through nanoparticles offers characteristics such as ease of use, reversibility, and universality, but still grapples with challenges like weak bonding. Here, a simple yet powerful strategy using the formation of nanoparticles in situ is reported, establishing strong interfacial adhesion between various hydrogels and substrates including elastomers, plastics, and biological tissue, even under wet conditions. The strong interfacial bonding can be formed in a short time (60 s), and gradually strengthened to 902 J m-2 adhesion energy within an hour. The interfacial layer's construction involves chain entanglement and other non-covalent interactions like coordination and hydrogen bonding. Unlike the permanent bonding seen in most synthetic adhesives, these nanoparticle adhesives can be efficiently triggered for removal by acidic solutions. The simplicity of the precursor diffusion and precipitation process in creating the interfacial layer ensures broad applicability to different substrates and nanoparticle adhesives without compromising robustness. The tough adhesion provided by nanoparticles allows the hydrogel-elastomer hybrid to function as a triboelectric nanogenerator (TENG), facilitating reliable electrical signal generation and output performance due to the robust interface.
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Engineering artificial mechanosensory hair cells offers a promising avenue for developing diverse biosensors spanning applications from biomedicine to underwater sensing. Unfortunately, current artificial sensory hair cells do not have the ability to simultaneously achieve ultrahigh sensitivity with low-frequency threshold detection (e.g., 0.1 Hz). This work aimed to solve this gap by developing an artificial sensory hair cell inspired by the vestibular sensory apparatus, which has such functional capabilities. For device characterization and response testing, the sensory unit was inserted in a 3D printed lateral semicircular canal (LSCC) mimicking the environment of the labyrinth. The sensor was fabricated based on platinum (Pt) thin film which was reinforced by carbon nanofibers (CNFs). A Pi-shaped hair cell sensor was created as the sensing element which was tested under various conditions of simulated head motion. Results reveal the hair cell sensor displayed markedly higher sensitivity compared to other reported artificial hair cell sensors (e.g., 21.47 mV Hz-1 at 60°) and low frequency detection capability, 0.1 Hz < f < 1.5 Hz. Moreover, like the LSCC hair cells in biology, the fabricated sensor was most sensitive in a given plane of rotational motion, demonstrating features of directional sensitivity.
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Human skin comprises multiple hierarchical layers that perform various functions such as protection, sensing, and structural support. Developing electronic skin (E-skin) with similar properties has broad implications in health monitoring, prosthetics, and soft robotics. While previous efforts have predominantly concentrated on sensory capabilities, this study introduces a hierarchical polymer system that not only structurally resembles the epidermis-dermis bilayer structure of skin but also encompasses sensing functions. The system comprises a polymeric hydrogel, representing the "dermis", and a superimposed nanoporous polymer film, forming the "epidermis". Within the film, interconnected nanoparticles mimic the arrangement of interlocked corneocytes within the epidermis. The fabrication process employs a robust in situ interfacial precipitation polymerization of specific water-soluble monomers that become insoluble during polymerization. This process yields a hybrid layer establishing a durable interface between the film and hydrogel. Beyond the structural mimicry, this hierarchical structure offers functionalities resembling human skin, which includes (1) water loss protection of hydrogel by tailoring the hydrophobicity of the upper polymer film; (2) tactile sensing capability via self-powered triboelectric nanogenerators; (3) built-in gold nanowire-based resistive sensor toward temperature and pressure sensing. This hierarchical polymeric approach represents a potent strategy to replicate both the structure and functions of human skin in synthetic designs.
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Biomimética , Dispositivos Electrónicos Vestibles , Humanos , Piel/química , Hidrogeles , AguaRESUMEN
Over the past few decades, flexible piezoelectric devices have gained increasing interest due to their wide applications as wearable sensors and energy harvesters. Poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE), as one of piezoelectric polymers, has caught considerable attention because of its high flexibility, high thermal stability, and biocompatibility. However, its relatively lower piezoelectricity limits its broader applications. Herein, we present a new approach to improving the piezoelectricity of PVDF-TrFE nanofibers by integrating barium titanate (BTO) nanoparticles. Instead of being directly dispersed into PVDF-TrFE nanofibers, the BTO nanoparticles were electrosprayed between the nanofiber layers to create a sandwich structure. The results showed that the sample with BTO sandwiched between PVDF-TrFE nanofibers showed a much higher piezoelectric output compared to the sample with BTO uniformly dispersed in the nanofibers, with a maximum of â¼ 457% enhancement. Simulation results suggested that the enhanced piezoelectricity is due to the larger strain induced in the BTO nanoparticles in the sandwich structure. Additionally, BTO might be better poled during electrospraying with higher field strength, which is also believed to contribute to enhanced piezoelectricity. The potential of the piezoelectric nanofiber mats as a sensor for measuring biting force and as a sensor array for pressure mapping was demonstrated.
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Thermoplastic polyurethane (TPU) has been widely used as the elastic polymer substrate to be combined with conductive nanomaterials to develop stretchable strain sensors for a variety of applications such as health monitoring, smart robotics, and e-skins. However, little research has been reported on the effects of deposition methods and the form of TPU on their sensing performance. This study intends to design and fabricate a durable, stretchable sensor based on composites of thermoplastic polyurethane and carbon nanofibers (CNFs) by systematically investigating the influences of TPU substrates (i.e., either electrospun nanofibers or solid thin film) and spray coating methods (i.e., either air-spray or electro-spray). It is found that the sensors with electro-sprayed CNFs conductive sensing layers generally show a higher sensitivity, while the influence of the substrate is not significant and there is no clear and consistent trend. The sensor composed of a TPU solid thin film with electro-sprayed CNFs exhibits an optimal performance with a high sensitivity (gauge factor ~28.2) in a strain range of 0-80%, a high stretchability of up to 184%, and excellent durability. The potential application of these sensors in detecting body motions has been demonstrated, including finger and wrist-joint movements, by using a wooden hand.
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The interface between structural electrodes and solid electrolytes plays a key role in the electrical-mechanical properties of energy storage structures. Herein, we present a surface functionalization method to improve the ion conduction efficiency at the interface between a structural electrode and a solid electrolyte that consists of a bi-continuous network of epoxy and ionic liquid (IL). Composite supercapacitors made with this electrolyte and carbon fiber (CF) electrodes coated with manganese dioxide (MnO2) demonstrate that treating the electrodes with the silane can increase the areal capacitance by 300% without degrading the tensile strength. The dual-phase electrolyte containing 40 wt % IL and 60 wt % epoxy exhibits the highest multifunctional performance, measured by the product of stiffness and ionic conductivity. The outstanding mechanical and energy storage properties demonstrate that the silane treatment of MnO2-coated CF fabric structural electrodes is a promising method for future high-performance structural composite supercapacitors.
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Wearable sensors are emerging as a new technology to detect physiological and biochemical markers for remote health monitoring. By measuring vital signs such as respiratory rate, body temperature, and blood oxygen level, wearable sensors offer tremendous potential for the noninvasive and early diagnosis of numerous diseases such as Covid-19. Over the past decade, significant progress has been made to develop wearable sensors with high sensitivity, accuracy, flexibility, and stretchability, bringing to reality a new paradigm of remote health monitoring. In this review paper, the latest advances in wearable sensor systems that can measure vital signs at an accuracy level matching those of point-of-care tests are presented. In particular, the focus of this review is placed on wearable sensors for measuring respiratory behavior, body temperature, and blood oxygen level, which are identified as the critical signals for diagnosing and monitoring Covid-19. Various designs based on different materials and working mechanisms are summarized. This review is concluded by identifying the remaining challenges and future opportunities for this emerging field.
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The lack of freshwater has been threatening many people who are living in Africa, the Middle East, and Oceania, while the discovery of freshwater harvesting technology is considered a promising solution. Recent advances in structured surface materials, metal-organic frameworks, hygroscopic inorganic compounds (and derivative materials), and functional hydrogels have demonstrated their potential as platform technologies for atmospheric water (i.e., supersaturated fog and unsaturated water) harvesting due to their cheap price, zero second energy requirement, high water capture capacity, and easy installation and operation compared with traditional water harvesting methods, such as long-distance water transportation, seawater desalination, and electrical dew collection devices in rural areas or individual-scale emergent usage. In this contribution, we highlight recent developments in functional materials for "passive" atmospheric water harvesting application, focusing on the structure-property relationship (SPR) to illustrate the transport mechanism of water capture and release. We also discuss technical challenges in the practical applications of the water harvesting materials, including low adaptability in a harsh environment, low capacity under low humidity, self-desorption, and insufficient solar-thermal conversion. Finally, we provide insightful perspectives on the design and fabrication of atmospheric water harvesting materials.
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Stretchable electronics that can elongate elastically as well as flex are crucial to a wide range of emerging technologies, such as wearable medical devices, electronic skin, and soft robotics. Critical to stretchable electronics is their ability to withstand large mechanical strain without failure while retaining their electrical conduction properties, a feat significantly beyond traditional metals and silicon-based semiconductors. Herein, we present a review of the recent advances in stretchable conductive polymer nanocomposites with exceptional stretchability and electrical properties, which have the potential to transform a wide range of applications, including wearable sensors for biophysical signals, stretchable conductors and electrodes, and deformable energy-harvesting and -storage devices. Critical to achieving these stretching properties are the judicious selection and hybridization of nanomaterials, novel microstructure designs, and facile fabrication processes, which are the focus of this Review. To highlight the potentials of conductive nanocomposites, a summary of some recent important applications is presented, including COVID-19 remote monitoring, connected health, electronic skin for augmented intelligence, and soft robotics. Finally, perspectives on future challenges and new research opportunities are also presented and discussed.
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Hybrid piezo-triboelectric nanogenerators constitute a new class of self-powered systems that exploit the synergy of piezoelectric and triboelectric mechanisms to improve energy harvesting efficencies and address the energy and power needs of portable and wearable electronic devices. The unique, synergistic electrical coupling mechanisms of piezoelectric and triboelectric effects increase the electric outputs and energy conversion efficiency of hybrid generators to beyond a linear summation of the contributions from individual triboelectric and piezoelectric mechanisms. Due to their large surface-area-to-volume ratios and outstanding mechanical, electronic and thermal properties, nanomaterials are favourable building blocks for constructing hybrid nanogenerators and represent a large family of flexible energy harvesting electronic structures and devices. Herein, we review the recent advances of hybrid piezo-triboelectric nanogenerators, with a particular focus on microstructure design, synergy mechanisms, and future research opportunities with significant potential for physiological monitoring, health care applications, transportation, and energy harvesting. The main strategies for improving electrical output performance are identified and examined, including novel nanostructures for increasing the contact area of the triboelectric pair, and nano-additives for enhancing the surface potential difference between the triboelectric pair and piezoelectric layers. Future applications and commercialization opportunities of these nanogenerators are also reviewed.
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A series of oil gels based on different types of ethylene-propylene-diene (EPDM) and styrene derivatives crosslinked with divinylbenzene (DVB) were synthesized by suspension polymerization. Effects of EPDM types and styrene derivatives on gel fraction, swelling ratio (q), solubility parameter (δ), average molecular weight between cross-links (M c), and oil absorption and oil retention of EPDM-based oil-absorptive gels were studied. Characterization of EPDM-based oil-absorptive gels with different styrene derivatives was performed by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and oil absorbency tests. The results showed that the double bond of the EPDM side chains was crosslinked with 4-tert-butyl styrene (t-BS), α-methyl styrene (α-MSt), styrene (St) or 4-methyl styrene (4-MSt) to form a three-dimensional network structure, respectively. Compared with the other three EPDM-based oil-absorptive gels, t-BS-EPDM-DVB (ESSB) has the best oil absorption and oil retention, which is mainly due to the fact that the substituent of t-BS is much larger than those of St, 4-MSt and α-MSt. The maximum oil absorption of the ESSB in chloroform was 23 g g-1. This investigation clearly distinguishes the influence of the synthetic raw materials of the EPDM-based oil-absorptive gels on their properties under study, which helps to optimize EPDM-based oil-absorptive materials according to actual applications.
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Wearable temperature sensors with high sensitivity, linearity, and flexibility are required to meet the increasing demands for unobtrusive monitoring of temperature changes indicative of the onset of infections and diseases. Herein, we present a new method for engineering highly sensitive and flexible temperature sensors made by sandwiching a poly(3,4-ethylenedioxythiophene):polystyrene (PEDOT:PSS) sensing film between two poly(dimethylsiloxane) (PDMS) substrates. Pre-stretching the sensor to a certain strain can create stable microcracks in the sensing layer that bestow high senstivity and linearity. The average length and density of the microcracks, which dictate the sensor's temperature sensitivity, can be engineered by controlling three key processing parameters, incuding (a) pre-stretching strain, (b) sulfuric acid treatment time, and (c) surface roughness of the substrate. For a given acid treatment time and surface roughness condition, the density and average length of the microcracks increase pre-stretching strain. A smooth PDMS substrate tends to yield long and straight cracks in the PEDOT:PSS film, compared to shorter microcracks with higher density on rough surfaces. Crack density can be further increased via sulfuric acid treatment with an optimum duration of approximately 3 h. Prolonged treatment would result in weak adhesion between the PEDOT:PSS film and the PDMS substrate, which in turn reduces the microcrack density but increases the crack length. By optimizing the three design parameters we have designed a high performance PEDOT:PSS-PDMS sensor that provides a combined high temperature sensitivity of 0.042 °C-1 with an excellent linearity of 0.998 (from 30 to 55 °C), better than the highest temperature sensitivity of PEDOT:PSS based sensors reported in the literature. With a good optical transparency, high temperature sensitivity, excellent linearity, and high flexibility, this microcrack-based sensor is a very promising wearable temperature-sensing solution.
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Técnicas Biosensibles/instrumentación , Compuestos Bicíclicos Heterocíclicos con Puentes/química , Polímeros/química , Poliestirenos/química , Dimetilpolisiloxanos/química , Conformación Molecular , Sensibilidad y Especificidad , Ácidos Sulfúricos/química , Propiedades de Superficie , Temperatura , Dispositivos Electrónicos VestiblesRESUMEN
Quantitative information on the magnitudes and directions of multiple contacting forces is crucial for a wide range of applications including human-robot interaction, prosthetics, and bionic hands. Herein we report a highly stretchable sensor integrating capacitive and piezoresistive mechanisms that can simultaneously determine multiple forces. The sensor consists of three layers in a sandwich design. The two facesheets serve as both piezoresistive sensors and electrodes for the capacitive sensor, with the core being a porous structure made by using a simple sugar particle template technique to give them high stretchability. The two facesheets contain segregated conductive networks of silver nanowires (AgNWs) and carbon nanofibers (CNFs). By measuring the changes in the electrical resistance of the facesheets and the capacitance between the facesheets, three separate mechanical stimuli can be determined, including normal pressure, in-plane stretch, and transverse shear force. The newly developed multidirectional sensor offers a significant opportunity for the next generation of wearable sensors for human health monitoring and bionic skin for robots.
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Nanocompuestos/química , Nanofibras/química , Nanocables/química , Dispositivos Electrónicos Vestibles , Carbono/química , Dimetilpolisiloxanos/química , Módulo de Elasticidad , Capacidad Eléctrica , Impedancia Eléctrica , Electrodos , Humanos , Porosidad , Presión , Plata/química , Resistencia a la TracciónRESUMEN
MXene/chitosan nanocoating for flexible polyurethane foam (PUF) was prepared via layer-by-layer (LbL) approach. MXene (Ti3C2) ultra-thin nanosheets were obtained through etching process of Ti3AlC2 followed by exfoliation. The deposition of MXene/chitosan nanocoating was conducted by alternatingly immersing the PUF into a chitosan solution and a Ti3C2 aqueous dispersion, which resulted in different number of bilayers (BL) ranging from 2, 5 and 8. Owing to the utilization of ultra-thin Ti3C2 nanosheets, the weight gain was only 6.9% for 8 BL coating of PUF, which minimised the unfavourable impact on the intrinsic properties of PUF. The Ti3C2/chitosan coating significantly reduced the flammability and smoke releases of PUF. Compared with unmodified PUF, the 8 BL coating reduced the peak heat release rate by 57.2%, alongside with a 65.5% reduction in the total heat release. The 8 BL coating also showed outstanding smoke suppression ability with total smoke release decreased by 71.1% and peak smoke production rate reduced by 60.3%, respectively. The peak production of CO and CO2 gases also decreased by 70.8% and 68.6%, respectively. Furthermore, an outstanding char formation performance of 37.2 wt.% residue was obtained for 8 BL coated PUF, indicating the excellent barrier and carbonization property of the hybrid coating.
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Aluminio/química , Quitosano/química , Retardadores de Llama , Poliuretanos/química , Titanio/química , Dióxido de Carbono/análisis , Monóxido de Carbono/análisis , Humo/análisisRESUMEN
Colloidal liquid metal alloys of gallium, with melting points below room temperature, are potential candidates for creating electrically conductive and flexible composites. However, inclusion of liquid metal micro- and nanodroplets into soft polymeric matrices requires a harsh auxiliary mechanical pressing to rupture the droplets to establish continuous pathways for high electrical conductivity. However, such a destructive strategy reduces the integrity of the composites. Here, this problem is solved by incorporating small loading of nonfunctionalized graphene flakes into the composites. The flakes introduce cavities that are filled with liquid metal after only relatively mild press-rolling (<0.1 MPa) to form electrically conductive continuous pathways within the polymeric matrix, while maintaining the integrity and flexibility of the composites. The composites are characterized to show that even very low graphene loadings (≈0.6 wt%) can achieve high electrical conductivity. The electrical conductance remains nearly constant, with changes less than 0.5%, even under a relatively high applied pressure of >30 kPa. The composites are used for forming flexible electrically-conductive tracks in electronic circuits with a self-healing property. The demonstrated application of co-fillers, together with liquid metal droplets, can be used for establishing electrically-conductive printable-composite tracks for future large-area flexible electronics.
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In this study, we synthesized a series of pH-sensitive and salt-sensitive N-succinyl-chitosan hydrogels with N-succinyl-chitosan (NSCS) and the crosslinker glycidoxypropyltrimethoxysilane (GPTMS) via a one-step hydrothermal process. The structure and morphology analysis of the NSCS and glycidoxypropyltrimethoxysilane-N-succinyl chitosan hydrogel (GNCH) revealed the close relation between the swelling behavior of hydrogels and the content of crosslinker GPTMS. The high GPTMS content could weaken the swelling capacity of hydrogels and improve their mechanical properties. The hydrogels show high pH sensitivity and reversibility in the range of pH 1.0 to 9.0, and exhibit on-off switching behavior between acidic and alkaline environments. In addition, the hydrogels perform smart swelling behaviors in NaCl, CaCl2, and FeCl3 solutions. These hydrogels may have great potential in medical applications.
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Quitosano/química , Hidrogeles , Calor , Hidrogeles/síntesis química , Hidrogeles/química , Concentración de Iones de HidrógenoRESUMEN
An ionic liquid, 1-allyl-3-methylimidazolium methyl phosphonate (Amim(MeO)PHO2), was synthesized and used to dissolve and regenerate cellulose under mild conditions. The dissolution mechanism of cellulose in Amim(MeO)PHO2 was investigated by in situ NMR spectroscopy under different conditions. Inorganic salt Na2PHO3 with an anion structure similar to that of Amim(MeO)PHO2 was added to form a Na2PHO3/Amim(MeO)PHO2 composite system. The effects of the composite system on the cellulose structure were investigated by Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray diffraction, and the measurement of the degree of polymerization. The results indicated that the regenerated cellulose was not derivatized; however, its thermal stability, crystallinity, and DP were lower than that of the original cellulose. Therefore, the dissolution mechanism of cellulose in Amim(MeO)PHO2, and its composite system with Na2PHO3 was investigated in this study, which might provide a simple guide for designing efficient and safe ionic liquids for the dissolution of cellulose.