Development and characterization of semi-refined iota carrageenan/fish gelatin-based biocomposite film incorporated with SiO2/ZnO nanoparticles.

Food packaging based on natural polymers from polysaccharides and proteins can be an alternative to replace conventional plastics. In the present study, semi-refined iota carrageenan (SRIC) and fish gelatin (FG) were used as polymer matrix film with different concentration ratios (0.5:1.5 %, 1.0:1.0 % and 1.5:0.5 % w/w) and SiO2-ZnO nanoparticles were incorporated as fillers with the same concentration in all formulas (0.5:1.5 % w/w carrageenan-fish gelatin). This study aimed to develop films for food packaging applications with desirable physical, mechanical, optical, chemical, and microbiological properties. The results showed that incorporating SiO2-ZnO nanoparticles significantly (p < 0.05) improved the films' elongation at break, UV-screening properties, and antimicrobial activity. Also, the films' thickness, degradability, and transparency significantly (p < 0.05) increased with the higher concentration of fish gelatin addition in the SRIC matrix polymer. The best formula was obtained on the SRIC-FG film at the ratio of 1.5:0.5 % w/w, which performed excellent antimicrobial activity. Thus, semi-refined iota carrageenan/fish gelatin-based biocomposite film incorporated with SiO2-ZnO nanoparticles can be potentially developed as eco-friendly and intelligent food packaging materials to resolve traditional plastic-related issues and prevent food waste.

Synthesis, Characterization, and Performance of Semi-Refined Kappa Carrageenan-Based Film Incorporating Cassava Starch.

This paper reports the incorporation of cassava starch (CS) at various concentrations into a previously developed ZnO/SiO2-semi-refined kappa carrageenan-based film (SRκC) bionanocomposite and evaluates its performance as minced chicken edible packaging. The incorporation of CS into SRκC-based films aims to provide multifunctional food packaging with enhanced surface morphology, thickness, mechanical properties, and transparency. The effect of the incorporation of various mixing ratios of CS and SRκC (CS:SRκC ratios of 1:3, 1:1, and 3:1) was investigated. The results show that the surface morphology, thickness, and mechanical properties of the SRκC-based films are increased by incorporating CS. Interestingly, a significant shelf-life improvement of up to 6 days is obtained for the application of the CS:SRκC 1:3 film as minced chicken packaging. It is concluded that the incorporation of CS into SRκC-based film is promising for extending the shelf life of minced chicken samples.

Development and Characterization of Semi-Refined Iota Carrageenan/SiO2-ZnO Bionanocomposite Film with the Addition of Cassava Starch for Application on Minced Chicken Meat Packaging.

In the current study, film based on semi-refined ι-carrageenan/cassava starch (SRiC/CS) incorporated with SiO2-ZnO nanoparticles was fabricated and characterized to deal with serious environmental problems resulting from plastic packaging materials. This study aimed to evaluate film properties with the variation of SRiC/CS proportions of bionanocomposite films for application to minced chicken meat packaging. Increasing CS portion contributed to increased transparency, reduced surface roughness, and decreased mechanical properties of films. The variable significantly (p < 0.05) increased the water vapor permeability (WVP) and reduced the water solubility of films. The incorporation of the nanoparticles significantly (p < 0.05) increased UV screening, decreased WVP, and enhanced the antimicrobial activity of films. Furthermore, the substitution of 0.5 wt% (weight percentage) CS provided the best film characteristics. Based on the color and the total volatile base nitrogen (TVBN) results, SRiC film incorporated with the nanoparticles preserved minced chicken quality up to six days. Thus, the developed films are desirable for biodegradable food packaging.

Enhanced multi functionality of semi-refined iota carrageenan as food packaging material by incorporating SiO2 and ZnO nanoparticles.

This paper reports the incorporation of SiO2-ZnO nanoparticles (NPs) into semi-refined iota carrageenan-based (SRIC) film as active food packaging. The dispersion of the nanoparticles was performed using a bead milling method and the films were prepared using the solution casting method. The incorporation of SiO2-ZnO NPs into SRIC films aims to provide multifunctional food packaging with enhanced water vapor barrier properties, UV-screening, and antimicrobial activity. The effect of the incorporation of SiO2 NPs, ZnO NPs, and the mixtures of SiO2-ZnO NPs varied in SiO2/ZnO ratios (SiO2-ZnO 1:1, 1:2, and 1:3) were investigated. The results showed that the tensile strength, water vapor barrier performance, UV-screening, and antimicrobial activity of the SRIC film were increased by the addition of either SiO2 or ZnO NPs alone. Interestingly, when the mixtures of SiO2-ZnO were incorporated, more significant improvement was observed. Also, the bio-degradability and solubility of all the SRIC films were confirmed. It was concluded that the SiO2-ZnO NPs incorporated into SRIC film provided multifunctional activities and acted as a promising active food packaging material.

Antioxidant activity and quality attributes of white chocolate incorporated with Cinnamomum burmannii Blume essential oil.

White chocolate is often considered as an unhealthy product with low phenolic content and antioxidant activity since it does not contain cocoa liquor. In this study, investigation on the phytochemical composition of cinnamon essential oil as well as its potential use to improve the antioxidant activity of white chocolate were carried out. The effect of the essential oil incorporation on the quality attributes of white chocolate was also examined. The results show that cinnamon essential oil was rich in cinnamaldehyde and exhibited antioxidant activity. The incorporation of cinnamon essential oil at a level of 0.1% (w/w) increased the antioxidant activity of the white chocolate more than twofold without significant effect on its hardness, melting properties and colour. However, a slight alteration on the flow behaviour of the white chocolate was observed. This study clearly shows that natural cinnamon essential oil could be an alternative to synthetic additives in foods to improve their antioxidant activity.

Sensory and physicochemical characteristics of dark chocolate bar with addition of cinnamon (Cinnamomum burmannii) bark oleoresin microcapsule.

Indonesia is one of the world's most prominent producers of cocoa and cinnamon. Dark chocolate bars and Cinnamomum burmannii are rich in antioxidants. The addition of a cinnamon oleoresin to a dark chocolate bar has not been previously studied due to its strong consistency and sticky texture. Microencapsulation was used to cover the undesirable properties of oleoresin, and the addition of cinnamon bark oleoresin microcapsules was expected to improve the functional properties and influence the characteristics of dark chocolate bars. This study aimed to determine the effects of adding various concentrations of cinnamon bark oleoresin microcapsules (4%/F1, 6%/F2, and 8%/F3) to dark chocolates bars on their sensory, physical, and chemical characteristics and to define the best formula of a dark chocolate bar. The results showed that various concentrations of cinnamon bark oleoresin microcapsules led different trends for each evaluation, and the best formula resulted from the addition of cinnamon bark oleoresin microcapsules to a dark chocolate bar (8%) that is accepted by the panellists. This bar had the hardest texture, the highest total phenol and antioxidant activities, and the lowest moisture content, and it was classified as having a high potency of vitamin E (tocopherol).

Effect of drying and milling modes on the quality of white rice of an Indonesian long grain rice cultivar.

BACKGROUND: Many studies have revealed the susceptibility of long grain rice to breaking during milling, while others have demonstrated the variation in the yield of head rice due to different rough rice drying methods. Thus, this study aims to determine appropriate drying and milling methods to improve the head rice yield and nutritional quality of long grain rice. METHODS: A series of drying experiments were performed on rough paddy rice employing shallow bed, oven and sun drying methods. Then, the dried rough rice grains were milled with various dehusking (H), separation (S) and polishing (P) configurations to obtain white rice. The resulting batches of white rice were analyzed and compared in terms of head rice yield, broken rice yield, brewer yield, whiteness and nutritional quality. RESULTS: Milling configurations strongly affected the total, head rice, broken rice and brewer yields. The configuration of one dehusking, one separation and one polishing (H – S – P) resulted in the highest milling and head rice yields. Although the whiteness of the rice samples was significantly affected by the milling configuration, their values fell within an acceptable range preferred by consumers in Southeast Asia (39–47). The milling of dried rough rice obtained from shallow bed and sun drying using a concrete floor and white tarpaulin resulted in a comparable total (65%) and head rice yield (51%). However, the milling of rough rice dried using an oven and sun drying on black tarpaulin resulted in a slightly lower total yield (64.50%) and head rice yield (50.50%). The moisture, ash, protein and lipid contents of the white rice were significantly lower than those of manually dehulled rice, whereas the carbohydrate and amylose contents of the white rice were significantly higher. CONCLUSIONS: Application of shallow bed or sun drying on a concrete floor followed by milling with the H – S – P configuration produced the highest head rice yield with an acceptable whiteness and nutritional composition. These combined postharvest technologies are simple, efficient and economical for both small- and large-scale applications. Further research on consumer acceptance and on the nutritional and cooking qualities of the white rice obtained from these combined postharvest technologies is essential.

Interaction between natural antioxidants derived from cinnamon and cocoa in binary and complex mixtures.

Cinnamon and cocoa are known to be valuable sources of bioactive phytochemicals, mainly the polyphenols. This paper investigates the potential antioxidant activity of cinnamon and cocoa extract and the interaction of their mixtures by various in vitro tests. Moreover, the combination effect of their constituents in a binary mixture was studied. Two representative active compounds of chocolate (epicatechin, catechin) were combined with seven of cinnamon (gallic acid, tannic acid, quercetin, sinapic acid, cinnamic acid, eugenol and cinnamaldehyde) in multilevel ratios. The results indicate that the addition of the cinnamon extract significantly increased the antioxidant activity of the cocoa extract. The interaction ranged from synergetic to antagonistic. The interaction was less synergetic when cinnamon extract was added in higher proportion. The interaction of their constituents substantially influenced the antioxidant activity of the mixture and was dependent on the ratio. The kinetics' study could elucidate how the polyphenols work in a mixture.

Purification, characterization, and cDNA cloning of a novel lectin from the green alga, Codium barbatum.

A novel lectin (CBA) was isolated from the green alga, Codium barbatum, by conventional chromatographic methods. The hemagglutination-inhibition profile with sugars and glycoproteins indicated that CBA had preferential affinity for complex type N-glycans but not for monosaccharides, unlike the other known Codium lectins specific for N-acetylgalactosamine. CBA consisted of an SS-linked homodimer of a 9257-Da polypeptide containing seven cysteine residues, all of which were involved in disulfide linkages. The cDNA of the CBA subunit coded a polypeptide (105 amino acids) including the signal peptide of 17 residues. The calculated molecular mass from the deduced sequence was 9705 Da, implying that the four C-terminal amino acids of the CBA proprotein subunit were post-translationally truncated to afford the mature subunit (84 amino acids). No significantly similar sequences were found during an in silico search, indicating CBA to be a novel protein. CBA is the first Codium lectin whose primary structure has been elucidated.