Effects of neonicotinoid insecticides on transport of non-degradable agricultural film microplastics.

Mulch film microplastics (MPs) could act as a vector for agricultural chemicals due to their long-term presence in farmland environments. As a result, this study focuses on the adsorption mechanism of three neonicotinoids on two typical agricultural film MPs, polyethylene (PE) and polypropylene (PP), as well as the effects of neonicotinoids on the MPs transport in quartz sand saturated porous media. The findings revealed that the adsorption of neonicotinoids on PE and PP was a combination of physical and chemical processes, including hydrophobic, electrostatic and hydrogen bonding. Acidity and appropriate ionic strength (IS) were favorable conditions for neonicotinoid adsorption of on MPs. The results of column experiments showed that the presence of neonicotinoids, particularly at low concentrations (0.5 mmol L-1), could promote the transport of PE and PP in the column by improving the electrostatic interaction and hydrophilic repulsion of particles. The neonicotinoids would be adsorbed on MPs through hydrophobic action preferentially, whereas excessive neonicotinoids could cover the hydrophilic functional groups on the surface of MPs. Neonicotinoids reduced the response of PE and PP transport behavior to pH changes. 0.005 mol L-1 NaCl ameliorated the migration of MPs by increasing their stability. Because of its highest hydration ability and the bridging effect of Mg2+, Na+ had the most prominent transport promoting effect on PE and PP in MPs-neonicotinoid. This study shows that the increased environmental risk caused by the coexistence of microplastic particles and agricultural chemicals is unneglectable.

Systematic Research on the Transport of Ball-Milled Biochar in Saturated Porous Media: Effect of Humic Acid, Ionic Strength, and Cation Types.

Ball-milled biochar (BMBC) is a typical engineering material that has promising application prospects in remediating contaminated soil and water. It is fundamental to rate the transport behaviors of BMBC in the underground environment before extensive use. In this study, the effects of the ubiquitous cations (Na+, Mg2+, and Al3+) and model organic matter (humic acid) on the transport of BMBC were investigated using laboratory column experiments. The results demonstrated the facilitated effect of HA on the transport of BMBC due to the negatively charged surface and steric effect under neutral conditions. HA and ionic strength manifested an antagonistic effect on the transport of BMBC, where the presence of one could weaken the effect from the other. We also found the charge reversal of the BMBC surface in the presence of Mg2+, thus enhancing the deposition of BMBC onto the medium surface. On the other hand, the charge reversal from Al3+-coupled acid conditions led to the restabilization and transport of BMBC in porous media. Therefore, the rational usage of BMBC is indispensable and more attention should be paid to the composition and change in underground water that might facilitate the transport of BMBC and thus lead to negative environmental implications.