Polypyrrole Coating via Lemieux-von Rudloff Oxidation on Magnetite Nanoparticles for Highly Efficient Removal of Chromium(VI) from Wastewater.

An alternative way for the coating of polypyrrole (PPy) polymer on hydrophobic magnetite (Fe3O4) nanoparticles is reported here to capture toxic chromium ions, Cr (VI), present in water. Iron oxide magnetic nanoparticles (Fe3O4) were synthesized by the conventional coprecipitation technique using FeCl3·6H2O and FeSO4·7H2O iron precursors and subsequently modified with oleic acid (OA). Then OA-Fe3O4 hydrophobic nanoparticles were oxidized using the Lemieux-von Rudloff reaction to transfer OA into hydrophilic azelaic acid (AA) (HOOC(CH2)7COOH-modified magnetic nanoparticles (AA-Fe3O4). Finally, a PPy polymer coating was formed by a seeded polymerization of pyrrole, using AA-Fe3O4 as seeds. The average size of PPy/Fe3O4 nanocomposites is 12.33 nm and is almost spherical in shape. The surface composition is confirmed by FTIR and thermogravimetry analyses. An X-ray diffraction study confirmed the formation of highly crystalline Fe3O4 nanoparticles, and the crystallinity was retained after the surface modification. The adsorption study suggested that the Cr(VI) ion adsorption is highly pH-dependent and the maximum amount of adsorption is obtained at pH 2.0. The adsorption results revealed that the Langmuir model provided the best fit for the isotherm, with a maximum adsorption capacity reaching approximately 173.22 mg g-1 at 323 K. Spontaneous and endothermic adsorption processes were confirmed by evaluating the thermodynamic parameters obtained in this investigation. The kinetics study showed that the interaction between Cr(VI) ions and magnetic nanocomposites was directed by a pseudo-second-order rate process indicating chemisorption. The prepared PPy/Fe3O4 nanocomposites would be promising adsorbents to purify water by eliminating Cr(VI) metal ions from wastewater.

Facile Fabrication and Characterization of Amine-Functional Silica Coated Magnetic Iron Oxide Nanoparticles for Aqueous Carbon Dioxide Adsorption.

Surface active amine-functionalized silica coated magnetic iron oxide nanoparticles were prepared by a simple two-step process for adsorbing CO2 gas from aqueous medium. First, oleic acid (OA) coated iron oxide magnetic particles (denoted as Fe3O4-OA) were prepared by a simple coprecipitation method. Then, the surface of the Fe3O4-OA particles was coated with silica by using tetraethyl orthosilicate. Finally, aminated Fe3O4/SiO2-NH2 nanoparticles were concomitantly formed by the reactions of 3-aminopropyl triethoxysilane with silica-coated particles. The formation of materials was confirmed by Fourier transform infrared spectral analysis. Transmission electron microscopic analysis revealed both spherical and needle-shaped morphologies of magnetic Fe3O4/SiO2-NH2 particles with an average size of 15 and 68.6 nm, respectively. The saturation magnetization of Fe3O4/SiO2-NH2 nanoparticles was found to be 33.6 emu g-1, measured by a vibrating sample magnetometer at ambient conditions. The crystallinity and average crystallite size (7.0 nm) of the Fe3O4/SiO2-NH2 particles were revealed from X-ray diffraction data analyses. Thermogravimetric analysis exhibited good thermal stability of the nanoadsorbent up to an elevated temperature. Zeta potential measurements revealed pH-sensitive surface activity of Fe3O4/SiO2-NH2 nanoparticles in aqueous medium. The produced magnetic Fe3O4/SiO2-NH2 nanoparticles also exhibited efficient proton capturing activity (92%). The particles were used for magnetically recyclable adsorption of aqueous CO2 at different pH values and temperatures. Fe3O4/SiO2-NH2 nanoparticles demonstrated the highest aqueous CO2 adsorption efficiency (90%) at 40 °C, which is clearly two times higher than that of nonfunctionalized Fe3O4-OA particles.

Capturing Acidic CO2 Using Surface-Active Difunctional Core-Shell Composite Polymer Particles via an Aqueous Medium.

Multifunctional surface-active polymeric composites are attractive materials for the adsorption of various small molecules. Herein, dual-functionalized micron-sized surface-active composite polymer particles were prepared by a three-step process for CO2 adsorption. First, polystyrene (PS) seed particles were prepared via the dispersion polymerization of styrene. PS/P(MMA-AAm-EGDMA) composite polymer particles were then synthesized by aqueous seeded copolymerization of methyl methacrylate (MMA) and acrylamide (AAm) in the presence of an ethylene glycol dimethacrylate (EGDMA) cross-linker. Finally, the amide moieties of PS/P(MMA-AAm-EGDMA) composite particles were converted into an amine-functionalized composite by using the Hofmann degradation reaction. The presence of primary amine groups on the surface of aminated composite particles was confirmed by some conventional chemical routes, such as diazotization and Schiff's base formation reactions. The formation and functionality of the PS seed, PS/P(MMA-AAm-EGDMA), and aminated PS/P(MMA-AAm-EGDMA) composite polymer particles were confirmed by Fourier transform infrared (FTIR) spectra analyses. Scanning electron microscopy (SEM) analysis revealed spherical shape, size, and surface morphologies of the PS seed, reference composite, and aminated composites. The elemental surface compositions, surface porosity, pore volume, pore diameter, and surface area of both composite particles were evaluated by energy-dispersive X-ray (EDX) mapping, X-ray photoelectron spectroscopy, and Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) analyses. Dynamic light scattering (DLS) and ζ-potential measurements confirmed the pH-dependent surface properties of the functionalized particles. The amount of the adsorbed anionic emulsifier, sodium dodecyl sulfate (SDS), on the surface of aminated PS/P(MMA-AAm-EGDMA) is higher at pH 4 than that at pH 10. A vice versa result was found in the case of cationic surfactant, hexadecyltrimethylammonium bromide (HTABr), adsorption. Synthesized aminated composite particles were used as an adsorbent for CO2 adsorption via bubbling CO2 in an aqueous medium. The changes in dispersion pH were monitored continuously during the adsorption of CO2 under various conditions. The amount of CO2 adsorption by aminated composite particles was found to be 209 mg/g, which is almost double that of reference composite particles.

Vancomycin conjugated iron oxide nanoparticles for magnetic targeting and efficient capture of Gram-positive and Gram-negative bacteria.

Drug conjugated iron oxide magnetite (Fe3O4) nanoparticles are of great interest in the field of biomedicine. In this study, vancomycin (Van) conjugated magnetite (Fe3O4) nanoparticles were envisioned to capture and inhibit the growth of bacteria. Hydrophobic Fe3O4 nanoparticles were synthesized by using co-precipitation of ferrous (Fe2+) and ferric (Fe3+) ions following a surface modification step with oleic acid as stabilizers. Thereafter, a ligand exchange technique was employed to displace oleic acid with hydrophilic dopamine (DOPA) molecules which have a catechol group for anchoring to the iron oxide surface to prepare water dispersible nanoparticles. The surface of the resulting Fe3O4/DOPA nanoparticles contains amino (-NH2) groups that are conjugated with vancomycin via a coupling reaction between the -NH2 group of dopamine and the -COOH group of vancomycin. The prepared vancomycin conjugated Fe3O4/DOPA nanoparticles were named Fe3O4/DOPA/Van and exhibited a magnetic response to an external magnetic field due to the presence of magnetite Fe3O4 in the core. The Fe3O4/DOPA/Van nanoparticles showed bactericidal activity against both Gram positive Bacillus subtilis (B. subtilis) and Streptococcus and Gram-negative bacteria Escherichia coli (E. coli). Maximum inhibition zones of 22 mm, 19 mm and 18 mm were found against B. subtilis, Streptococcus and E. coli respectively. Most importantly, the vancomycin conjugated nanoparticles were effectively bound to the cell wall of the bacteria, promoting bacterial separation and growth inhibition. Therefore, the prepared Fe3O4/DOPA/Van nanoparticles can be promising for effective bacterial separation and killing in the dispersion media.

Synthesis of Self-Assembled Randomly Oriented VO2 Nanowires on a Glass Substrate by a Spin Coating Method.

Randomly oriented vanadium dioxide (VO2) nanowires were produced on a glass substrate by spin coating from a cosolvent. SEM studies reveal that highly dense VO2 nanowires were grown at an annealing temperature of 400 °C. X-ray diffraction (XRD) provides evidence of the high crystallinity of the VO2 nanowires-embedded VO2 thin films on the glass substrate at 400 °C. Characterization by high-resolution transmission electron microscopy (HR-TEM) confirmed the formation of VO2 nanowires. The optical band gap of the nanowires-embedded VO2 thin films was also calculated from the transmittance data to be 2.65-2.70 eV. The growth mechanism of the solution-processed semiconducting VO2 nanowires was proposed based on both solvent selection and annealing temperature. Finally, the solar water splitting ability of the VO2 nanowires-embedded VO2 thin films was demonstrated in a photoelectrochemical cell (PEC).

Oil-in-water emulsion impregnated electrospun poly(ethylene terephthalate) fiber mat as a novel tool for optical fiber cleaning.

HYPOTHESIS: The complete removal of remaining polymer debris after stripping of optical fiber cables is essential for high precision connection between two fibers. It can be anticipated that electrospun porous membranes as cleaning wipes are able to trap and retain polymer debris within their pores. Impregnation of an oil-in-water emulsion as cleaning agent lowers the interfacial tension between debris and the optical fiber thereby enabling the straightforward removal of polymer debris from the optical fiber. EXPERIMENTS: Electrospun membranes of poly(ethylene terephthalate) (PET) and cellulose acetate (CA) were obtained with fiber diameters of 0.430 µm and 2 µm respectively. The oil-in-water emulsion was formulated with 10 wt% medium chain triglyceride (MCT) and 10 wt% Tween 80 surfactant in an aqueous phosphate buffer solution. FINDINGS: In a scoring range from 0 to 5 for which the score 0 indicated superior cleaning and the score 5 referred to the least efficient cleaning, the electrospun fiber mats (without emulsion) scored within the range of 2-4 while emulsion impregnated electrospun fiber mats revealed the best score of 0. A drastic improvement was thus clearly evident from the obtained results when the cleaning emulsion was applied. The materials developed herein thus represent a new class of soft cleaning agents for optical fibers.

Nucleic acid sample preparation for in vitro molecular diagnosis: from conventional techniques to biotechnology.

Nucleic acid (DNA and RNA)-based molecular diagnosis is a promising laboratory technique because of its ability to identify disease accurately. However, one of its disadvantages is the inevitable purification and detection of nucleic acids from other contaminated entities. Different nano- and microparticles have been developed for use in an advanced, efficient high-throughput autosystem for the purification and detection of nucleic acid samples for use in molecular diagnoses. In this review, we discuss recent advances in the development of particle-based nucleic acid purification and detection.

Highly temperature responsive core-shell magnetic particles: synthesis, characterization and colloidal properties.

Temperature responsive magnetic polymer submicron particles were prepared by two step seed emulsion polymerization process. First, magnetic seed polymer particles were obtained by emulsion polymerization of styrene using potassium persulfate (KPS) as an initiator and divinylbenzne (DVB) as a cross-linker in the presence of oil-in-water magnetic emulsion (organic ferrofluid droplets). Thereafter, DVB cross-linked magnetic polymer particles were used as seed in the precipitation polymerization of N-isopropylacrylamide (NIPAM) to induce thermosensitive PNIPAM shell onto the hydrophobic polymer surface of the cross-linked magnetic polymer particles. To impart cationic functional groups in the thermosensitive PNIPAM backbone, the functional monomer aminoethylmethacrylate hydrochloride (AEMH) was used to polymerize with NIPAM while N,N'-methylenebisacrylamide (MBA) and 2, 2'-azobis (2-methylpropionamidine) dihydrochloride (V-50) were used as a cross-linker and as an initiator respectively. The effect of seed to monomer (w/w) ratio along with seed nature on the final particle morphology was investigated. Dynamic light scattering (DLS) results demonstrated particles swelling at below volume phase transition temperature (VPTT) and deswelling above the VPTT. The perfect core (magnetic) shell (polymer) structure of the particles prepared was confirmed by Transmission Electron Microscopy (TEM). The chemical composition of the particles were determined by thermogravimetric analysis (TGA). The effect of temperature, pH, ionic strength on the colloidal properties such as size and zeta potential of the micron sized thermo-sensitive magnetic particles were also studied. In addition, a short mechanistic discussion on the formation of core-shell morphology of magnetic polymer particles has also been discussed.