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1.
Langmuir ; 2024 Sep 13.
Artículo en Inglés | MEDLINE | ID: mdl-39268767

RESUMEN

In the current research work, an advanced oxidation process was applied to the degradation of Remazol brilliant blue dye (RBBD) using a sulfate radical. Fe3O4@PDA nanoparticles were synthesized using coprecipitation and self-polymerization techniques. Nanoparticle formation was confirmed by XRD, FTIR, FESEM-EDX, VSM, and XPS analyses. The crystalline nature of the material showed that it possessed a spherical shape with an Ms value of 58 emu/g. The elemental composition and binding energy from EDX and XPS analyses showed successful doping. Batch studies were conducted, and experimental studies showed that the optimum condition for degradation of 90 ppm of RBBD was 0.3 g/L of nanomaterial, 20 mM PS at pH 3, achieving 91.35% degradation. The kinetic model suitable for this study was a pseudo-second-order kinetic model with R2 value >0.9. From the radical identification tests, sulfate radicals played a dominant role in degradation, and to confirm it, EPR analysis was conducted using DMPO. A stability test was performed for 5 cycles in which the degradation efficiency was reduced appreciably. From XPS, XRD, and EDX analyses, the elemental composition and oxidation state of the recycled material used in the fifth cycle showed variation in a negligible manner when compared to the fresh catalyst used in the first cycle of the degradation experiment. Intermediate identification was done by GCMS analysis, and it disclosed the formation of aliphatic products from the degradation of RBBD with less toxicity. Phytotoxicity analysis was conducted using green grams for 10 days, and it proved that intermediates formed in the solution were nontoxic to the plants. Additionally, TOC and COD removal % were attained to be 80.021 and 80.903%, respectively, which confirm the mineralization efficacy. Hence, this research work proved the efficient performance of the catalyst for RBBD degradation with less formation of intermediates, and therefore, this technique is most suitable for the reduction of water pollution.

2.
Langmuir ; 40(33): 17753-17766, 2024 Aug 20.
Artículo en Inglés | MEDLINE | ID: mdl-39106518

RESUMEN

This investigation delved into the field of bifunctional electrocatalyst water splitting, aimed at advancing sustainable energy by addressing the scarcity of efficient nonprecious electrocatalysts capable of facilitating both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). This study focused on nanohybrids consisting of hydrothermally synthesized rGO/MnO2/MoS2 composites and highlighted their efficacy as bifunctional electrocatalysts. The synergistic integration of rGO/MnO2/MoS2 enhanced the surface area, magnified electroactive sites, established a customized conductive arrangement, and provoked the efficiency in splitting of water. The nanohybrid displayed exceptional catalytic performance for the OER and HER, with significantly reduced overpotentials of 208 and 205 mV in 1 M KOH at 10 mA cm-2 current density, respectively. The findings underscore the potential of these cost-effective and environmentally friendly rGO/MnO2/MoS2 nanohybrids in advancing the field of electrocatalysis for renewable energy applications.

3.
Environ Res ; 260: 119768, 2024 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-39134114

RESUMEN

The development of biocompatible adsorbents is vital for environmental remediation to control and reduce pollution and waste accumulation in ecosystems. Biocompatible hydrogels represent an innovative class of materials that are primarily composed of polymer chain units forming their structural framework. They have a high affinity for water molecules. This research thus aims to incorporate iron oxide particles into the gelatin matrix to produce gelatin hydrogel beads to remove hexavalent chromium from an aqueous solution. The synthesized beads, known for their consistent size, low friction, high specific surface area, mechanical stability, and lightweight characteristics, demonstrated their suitability for various industrial applications. The effectiveness of these hydrogels in removing hexavalent chromium ions was confirmed through a thorough analysis using techniques such as FTIR, TGA, SEM, EDX, VSM, and XPS. Batch experiments revealed that the gelatin-based nanocomposite beads exhibited optimal adsorption efficiency under acidic conditions, lower initial concentrations of chromium ions, extended contact time, and elevated temperature (50-60 °C). The composite achieved a maximum removal efficiency of 99% at pH 1, with an adsorbent dose of 0.5 g at 50 °C, and an initial concentration of 50 mg per liter. The use of 0.7 N NaOH in the regeneration process resulted in a commendable 70.5% desorption efficiency, enabling potential reuse and regeneration. Significantly, the desorption efficiency remained consistently high even after four desorption-readsorption cycles, contributing to the economic and environmental sustainability of chromium removal. Additionally, the study determined that the sorption process was feasible, spontaneous, and endothermic. These collective findings suggest that magnetic gelatin hydrogel beads could serve as a cost-effective alternative adsorbent for the efficient removal of chromium ions from aqueous solutions.


Asunto(s)
Cromo , Gelatina , Hidrogeles , Nanopartículas de Magnetita , Contaminantes Químicos del Agua , Purificación del Agua , Hidrogeles/química , Gelatina/química , Contaminantes Químicos del Agua/química , Cromo/química , Cromo/aislamiento & purificación , Adsorción , Nanopartículas de Magnetita/química , Purificación del Agua/métodos , Materiales Biocompatibles/química
4.
Environ Geochem Health ; 46(9): 308, 2024 Jul 13.
Artículo en Inglés | MEDLINE | ID: mdl-39001890

RESUMEN

This study introduces a new biosorbent derived from Delonix regia bark-activated carbon to efficiently remove Chromium Cr(VI) metal ions from aqueous systems. The biosorbent was synthesized from the bark powder of the plant species and chemically activated with phosphoric acid. The biosorbent was characterized using FTIR, SEM, and BET to determine its functional properties and structural morphology. The batch adsorption experiments examined the optimal conditions for Cr(VI) metal ion adsorption, identifying that the highest removal efficiency occurred at pH levels of 2. The ideal adsorbent dosage was determined to be 2.5 g/L, with equilibrium achieved at a contact time of 60 min at the optimal temperature of about 303 K for a Cr(VI) metal ion concentration of 20 mg/L. Various isotherm models were applied to the adsorption equilibrium values, revealing that the adsorbent had a maximum removal capacity of approximately 224.8 mg/g for Cr(VI) metal ions. The adsorption process of Cr(VI) on the DAC biosorbent was best described by the Freundlich isotherm, indicating multilayer adsorption. The kinetic data fit well with the pseudo-second-order model. Thermodynamic parameters suggested that the adsorption process was spontaneous, exothermic, and feasible across different temperatures. Furthermore, the desorption studies showed that the DAC biosorbent can easily be rejuvenated and utilized several cycles with high adsorption capacity. These findings indicate that the developed adsorbent is environmentally friendly and effective for removing Cr(VI) from water systems.


Asunto(s)
Carbón Orgánico , Cromo , Corteza de la Planta , Contaminantes Químicos del Agua , Cromo/química , Adsorción , Corteza de la Planta/química , Contaminantes Químicos del Agua/química , Carbón Orgánico/química , Concentración de Iones de Hidrógeno , Purificación del Agua/métodos , Cinética , Sapotaceae/química , Termodinámica , Espectroscopía Infrarroja por Transformada de Fourier , Temperatura
5.
Environ Res ; 253: 119124, 2024 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-38734294

RESUMEN

Polyaromatic hydrocarbons (PAHs) are the most persistent compounds that get contaminated in the soil and water. Nearly 16 PAHs was considered to be a very toxic according US protection Agency. Though its concentration level is low in the environments but the effects due to it, is enormous. Advanced Oxidation Process (AOP) is an emergent methodology towards treating such pollutants with low and high molecular weight of complex substances. In this study, sulfate radical (SO4‾•) based AOP is emphasized for purging PAH from different sources. This review essentially concentrated on the mechanism of SO4‾• for the remediation of pollutants from different sources and the effects caused due to these pollutants in the environment was reduced by this mechanism is revealed in this review. It also talks about the SO4‾• precursors like Peroxymonosulfate (PMS) and Persulfate (PS) and their active participation in treating the different sources of toxic pollutants. Though PS and PMS is used for removing different contaminants, the degradation of PAH due to SO4‾• was presented particularly. The hydroxyl radical (•OH) mechanism-based methods are also emphasized in this review along with their limitations. In addition to that, different activation methods of PS and PMS were discussed which highlighted the performance of transition metals in activation. Also this review opened up about the degradation efficiency of contaminants, which was mostly higher than 90% where transition metals were used for activation. Especially, on usage of nanoparticles even 100% of degradation could be able to achieve was clearly showed in this literature study. This study mainly proposed the treatment of PAH present in the soil and water using SO4‾• with different activation methodologies. Particularly, it emphasized about the importance of treating the PAH to overcome the risk associated with the environment and humans due to its contamination.


Asunto(s)
Restauración y Remediación Ambiental , Oxidación-Reducción , Hidrocarburos Policíclicos Aromáticos , Sulfatos , Sulfatos/química , Sulfatos/análisis , Hidrocarburos Policíclicos Aromáticos/análisis , Hidrocarburos Policíclicos Aromáticos/química , Restauración y Remediación Ambiental/métodos , Contaminantes Ambientales/química , Contaminantes Ambientales/análisis
6.
Chemosphere ; 360: 142382, 2024 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-38768788

RESUMEN

As an effort to tackle some of the most pressing ecological issues we are currently experiencing, there has been an increasing interest in employing biomass-derived char products in various disciplines. Thermal combustion of biomass results in biochar production, which is a remarkably rich source of carbon. Not only does the biochar obtained by the thermochemical breakdown of biomass lower the quantity of carbon released into the environment, but it also serves as an eco-friendly substitute for activated carbon (AC) and further carbon-containing products. An overview of using biochar to remove toxic pollutants is the main subject of this article. Several techniques for producing biochar have been explored. The most popular processes for producing biochar are hydrothermal carbonization, gasification and pyrolysis. Carbonaceous materials, alkali, acid and steam are all capable of altering biochar. Depending on the environmental domains of applications, several modification techniques are chosen. The current findings on characterization and potential applications of biochar are compiled in this survey. Comprehensive discussion is given on the fundamentals regarding the formation of biochar. Process variables influencing the yield of biochar have been summarized. Several biochars' adsorption capabilities for expulsion pollutants under various operating circumstances are compiled. In the domain of developing biochar, a few suggestions for future study have been given.


Asunto(s)
Carbón Orgánico , Contaminantes Químicos del Agua , Carbón Orgánico/química , Contaminantes Químicos del Agua/química , Contaminantes Químicos del Agua/análisis , Adsorción , Purificación del Agua/métodos , Biomasa
7.
Environ Pollut ; 345: 123418, 2024 Mar 15.
Artículo en Inglés | MEDLINE | ID: mdl-38307243

RESUMEN

Measuring the concentration of organochlorine pesticides (OCPs) in agriculture has engaged significant awareness for healthcare investigation since OCPs are harmful to many physiological processes. Excessive usage of these compounds can result in major contamination of the environment and food supply chains. As a result, more accurate and rapid ways to detect pesticide residues in food are required. In this work, we have portrayed the surface-engineered fluorescent blue emissive-carbon dot (B-CD) with a high quantum yield (49.3 %) via the hydrothermal method for fluorescent sensing of OCPs on real samples. The amine group functionalities of carbon dots have supported the direct coordination with -Cl and -OH groups of HEP, ENS, CDF and 2,4-DPAC for the sensitive detection of OCPs, by switching in the fluorescent intensity of B-CD. The functional group of OCPs exhibits a variety of binding interactions with B-CD to contribute a complex formation, which leads to static quenching via an insubstantial restricted electron transfer process. The synthesized carbon dots exhibit individuality in binding nature towards different OCPs. Fluorescence studies help to distinguish the target OCPs and their low detection limits (LODs) were 0.002, 0.099, 0.16 and 0.082 µM for Heptachlor (HEP - turn "on"), Endosulfan (ENS), Chlordimeform (CDF) and 2,4-dichlorophenoxyacetic acid (2,4-DPAC - turn "off") OCPs respectively. The real water samples and agriculture food samples were effectively investigated and the OCP toxicity was noted. Thus, the design of the fluorescence sensor is established as an easy and proficient sensing method for detecting OCPs.


Asunto(s)
Clorfenamidina , Hidrocarburos Clorados , Plaguicidas , Carbono , Fluorescencia , Monitoreo del Ambiente/métodos , Plaguicidas/análisis , Hidrocarburos Clorados/análisis
8.
Chemosphere ; 350: 141123, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-38185426

RESUMEN

Pollution is a global menace that poses harmful effects on all the living ecosystems and to the Earth. As years pass by, the available and the looming rate of pollutants increases at a faster rate. Although many treatments and processing strategies are waged for treating such pollutants, the by-products and the wastes or drain off generated by these treatments further engages in the emission of hazardous waste. Innovative and long-lasting solutions are required to address the urgent global issue of hazardous pollutant remediation from contaminated environments. Myco-remediation is a top-down green and eco-friendly tool for pollution management. It is a cost-effective and safer practice of converting pernicious substances into non-toxic forms by the use of fungi. But these pollutants can be transformed into useable products along with multiple benefits for the environment such as sequestration of carbon emissions and also to generate high valuable bioactive materials that fits as a sustainable economic model. The current study has examined the possible applications of fungi in biorefineries and their critical role in the transformation and detoxification of pollutants. The paper offers important insights into using fungal bioremediation for both economically and environmentally sound solutions in the domain of biorefinery applications by combining recent research findings.


Asunto(s)
Contaminantes Ambientales , Biodegradación Ambiental , Ecosistema , Residuos Peligrosos
9.
Environ Pollut ; 342: 123035, 2024 Feb 01.
Artículo en Inglés | MEDLINE | ID: mdl-38030112

RESUMEN

Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure. Various oxygenated functional groups in composite beads and activated hydrochar were identified that assist in interaction with PARA pollutant. TGA analysis showed weight loss at three stages 200 °C, 365 °C and 710 °C that leads to complete disintegration of composite beads. BET analysis showed a variation in the surface area between activated hydrochar and beads which could be due to air drying process. Batch adsorption test was conducted for investigating the efficiency of beads in removing PARA from water. Pseudo-second order and Langmuir isotherm fitted the best highlighting chemical mode of adsorption with homogenous interaction on the adsorbent surface. 48.12 mg g-1 was the maximum adsorption capacity estimated from sorption between beads and PARA. For practical applications beads were effectively used in reducing COD levels of PARA spiked sewage water with the defined experimental parameters. Ethanol would be effectively used as regenerating solvent in recycling the beads for the betterment of cost reduction. The activated hydrochar immobilized cellulose beads would be successfully applied as adsorbent in removing target pollutants from water thereby reducing the hurdles faced with respect to fine particles in water treatment.


Asunto(s)
Aguas del Alcantarillado , Contaminantes Químicos del Agua , Acetaminofén , Celulosa , Contaminantes Químicos del Agua/análisis , Concentración de Iones de Hidrógeno , Adsorción , Cinética
10.
Food Res Int ; 173(Pt 2): 113366, 2023 11.
Artículo en Inglés | MEDLINE | ID: mdl-37803705

RESUMEN

The food packaging industries are facing the challenge of food waste generation. This can be addressed through the use of edible coating materials. These coatings aid in extending the shelf life of food products, reducing waste. The key components of these coatings include food-grade binding agents, solvents, and fillers. The integration of polysaccharide, protein, lipids, bioactive and composite-based materials with edible coating matrix aids to combat substantial post-harvest loss of highly perishable commodities and elevates the quality of minimally processed food. The aim of this review is to introduce the concept of edible coatings and discuss the different coating materials used in the food industry, along with their properties. Additionally, this review aims to classify the coating types based on characteristic features and explore their application in various food processing industries. This review provides a comprehensive overview of edible coatings, including the integration of polysaccharides, proteins, lipids, bioactive, and composite-based materials into the coating matrix. This review also addresses the significant post-harvest loss of highly perishable commodities and emphasizes the enhancement of quality in minimally processed food. Furthermore, the antimicrobial, anti-corrosive, and edible characteristics are highlighted, showcasing their potential applications in different food packaging industries. Moreover, it also discusses the challenges, safety and regulatory aspects, current trends, and future perspectives, aiming to shed light on the commercialization and future investigation of edible coatings.


Asunto(s)
Películas Comestibles , Eliminación de Residuos , Embalaje de Alimentos , Conservación de Alimentos , Polisacáridos/química , Frutas , Proteínas/química , Lípidos
11.
Environ Sci Pollut Res Int ; 30(48): 105099-105118, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37740158

RESUMEN

The persistence of organic/inorganic pollutants in the water has become a serious environmental issue. Among the different pollutants, dyes and heavy metal pollution in waterways are viewed as a global ecological problem that can have an impact on humans, plants, and animals. The necessity to develop a sustainable and environmentally acceptable approach to remove these toxic contaminants from the ecosystem has been raised. In the past two decades, rapid industrialization and anthropogenic activities in developed countries have aggravated environmental pollution. Industrial effluents that are discharged directly into the natural environment taint the water, which has a consequence for the water resources. Magnetic nanohybrids are broadly investigated materials used in the adsorption and photocatalytic degradation of poisonous pollutants present across water effluents. In the present review, the toxic health effects of heavy metals and dyes from the water environment have been discussed. This paper reviews the role of magnetic nanohybrids in the removal of pollutants from the water environment, providing an adequate point of view on their new advances regarding their qualities, connection methodologies, execution, and their scale-up difficulties.


Asunto(s)
Contaminantes Ambientales , Metales Pesados , Contaminantes Químicos del Agua , Humanos , Animales , Ecosistema , Contaminación del Agua , Agua , Colorantes , Fenómenos Magnéticos , Metales Pesados/metabolismo
12.
Mol Biotechnol ; 2023 Aug 11.
Artículo en Inglés | MEDLINE | ID: mdl-37566189

RESUMEN

Biohydrogen is an economical fuel which has enormous promise as an alternative energy source. The synthesis of biohydrogen can be done more affordably and sustainably using microalgae. For the generation of biohydrogen and the treatment of wastewater, microalgae derived from effluent have been showing very impressive outcomes. In comparison to traditional fuel sources, microalgae have benefits. Microalgae are capable of fixing ambient Carbon dioxide and converting it to carbohydrates, which are subsequently processed biochemically to provide fuel. When compared to terrestrial crops, they require less water and minerals for production. But besides these benefits, there are certain technological restrictions on the scale-up implementations of microalgae bioenergy. In this work, we explored the production of biohydrogen from several types of microalgae. The process of producing biohydrogen is affected by a number of variables, including pH, substrate concentration, the kinds of microalgal species, and others. The most recent studies and difficulties related to each stage of the biohydrogen manufacturing process are outlined. The synthesis of microalgal biohydrogen is improved using promising approaches that are discussed. Also, the specific future direction are covered. The possibility for microalgae-based production of biohydrogen to serve as an environmentally friendly and carbon-free biofuel solution that might handle the impending fuel scarcity was demonstrated. However, additional study is required on both the upstream and downstream processes of the synthesis of biohydrogen.

13.
Environ Res ; 236(Pt 1): 116723, 2023 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-37487925

RESUMEN

The environment worldwide has been contaminated by toxic pollutants and chemicals through anthropogenic activities, industrial growth, and urbanization. Microbial remediation is seen to be superior compared to conventional remediation due to its low cost, selectivity towards particular metal ions, and high efficiency. One key strategy in enhancing microbial remediation is employing an immobilization technique with biochar as a carrier. This review provides a comprehensive summary of sources and toxic health effects of hazardous water pollutants on human health and the environment. Biochar enhances the growth and proliferation of contaminant-degrading microbes. The combined activity of biochar and microbes in eliminating the contaminants has gained the researcher's interest. Biochar demonstrates its biocompatibility by fostering microbial populations, the release of enzymes, and protecting the microbes from the acute toxicity of surrounding contaminants. The current review complies with the immobilization technique and remediation mechanisms of microbes in pollutant removal. This review also emphasizes the combined utilization, environmental adaptability, and the potential of the combined effect of immobilized microbes and biochar in the remediation of contaminants. Challenges and future outlooks are urged to commercialize the immobilized microbes-biochar interaction mechanism for environmental remediation.

14.
Chemosphere ; 338: 139619, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37487975

RESUMEN

The electrochemical degradation of alizarin red dye was studied using bismuth oxyhalide attached to bismuth vanadate nanocomposite synthesized via a simple solvothermal method. The electrochemical degradation of alizarin red dye was treated at current densities of 3 and 5 mA cm-1 for 30 min under different supporting electrolyte mediums (NaCl and KCl). Also, the electrochemical degradation of BiOBr/BiVO4 electrode shows higher degradation percentages of 97 and 99 for NaCl and KCl electrolyte solutions, which are higher degradation percentages than pure BiVO4 electrode (88 and 91 for NaCl and KCl). Also, the BiOBr/BiVO4 electrode shows 100% COD reduction during the 30th min of alizarin red dye using both NaCl and KCl electrolyte solutions. This may indicate that the prepared BiOBr/BiVO4 electrode shows an efficient electrode material for the degradation of textile dyes.


Asunto(s)
Contaminantes Ambientales , Aguas Residuales , Bismuto , Cloruro de Sodio , Electrodos
15.
J Environ Manage ; 344: 118614, 2023 Oct 15.
Artículo en Inglés | MEDLINE | ID: mdl-37454449

RESUMEN

In recent periods, a broad assortment of continual organic contaminants has been released into our natural water resources. Indeed, it is exceedingly poisonous and perilous to living things; thus, the elimination of these organic pollutants before release into the water bodies is vital. A variety of techniques have been utilized to remove these organic pollutants with advanced oxidation photocatalytic methods with zinc oxide (ZnO) nanoparticles being commonly used as a capable catalyst for contaminated water treatment. Nevertheless, its broad energy gap, which can be only stimulated under an ultraviolet (UV) light source, and high recombination pairs of electrons and holes limit their photocatalytic behaviors. However, numerous methods have been suggested to decrease its energy gap for visible regions. Including, the doping ZnO with metal ions (dopant) can be considered as an effectual route not only the reason for a movement of the absorption edges toward the higher (visible light) region but also to lower the electron-hole pair (e--h+) recombination. This review concentrated on the impact of dissimilar types of metal ions (dopants) on the advancement in the degradation performance of ZnO. So, this work demonstrates a vital review of contemporary attainments in the alteration of ZnO nanoparticles for organic pollutants eliminations. Besides, the effect of doping ions including transition metals, rare earth metals, and metal ions (substitutional and interstitial) concerning numerous types of altered ZnO are summarized. The photodegradation mechanisms for pristine and metal-modified ZnO nanoparticles are also conferred.


Asunto(s)
Contaminantes Ambientales , Nanopartículas del Metal , Óxido de Zinc , Zinc , Metales , Compuestos Orgánicos , Colorantes , Preparaciones Farmacéuticas , Iones , Catálisis
16.
Environ Pollut ; 333: 122114, 2023 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-37379877

RESUMEN

Organochlorine pesticides (OCPs) have been used in agriculture, increasing crop yields and representing a serious and persistent global contaminant that is harmful to the environment and human health. OCPs are typically bioaccumulative and persistent chemicals that can spread over long distances. The challenge is to reduce the impacts caused by OCPs, which can be achieved by treating OCPs in an appropriate soil and water environment. Therefore, this report summarizes the process of bioremediation with commercially available OCPs, considering their types, impacts, and characteristics in soil and water sources. The methods explained in this report were considered to be an effective and environmentally friendly technique because they result in the complete transformation of OCPs into a non-toxic end product. This report suggests that the bioremediation process can overcome the challenges and limitations of physical and chemical treatment for OCP removal. Advanced methods such as biosurfactants and genetically modified strains can be used to promote bioremediation of OCPs.


Asunto(s)
Hidrocarburos Clorados , Plaguicidas , Contaminantes del Suelo , Humanos , Biodegradación Ambiental , Contaminantes del Suelo/análisis , Monitoreo del Ambiente/métodos , Plaguicidas/análisis , Hidrocarburos Clorados/análisis , Suelo/química , China
17.
Chemosphere ; 334: 139014, 2023 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-37224979

RESUMEN

A co-precipitation technique has been used to prepare Bismuth tungstate nanoparticles (Bi2WO6) for electrochemical capacitors and electrochemical sensing of Ascorbic acid (AA). Using a scanning rate of 10 mV s -1, the electrode was performed as the pseudocapacitance behavior and the specific capacitance to be up to 677 Fg -1 at 1 A/g. Bi2WO6 versus Glassy carbon electrode (GCE) was also used to study the behavior of the Bi2WO6 modified electrodes in detecting ascorbic acid. This electrochemical sensor shows excellent electrocatalytic performance when ascorbic acid is present, as determined by differential pulse voltammetry. In solution, ascorbic acid diffuses to an electrode surface and controls its surface properties. Based on the results from the investigation, the sensor showed a detection sensitivity of 0.26 mM/mA, and a limit of detection (LOD) of 77.85 mM. It is clear from these results that Bi2WO6 may find application as an electrode material for supercapacitors and glucose sensors.


Asunto(s)
Nanopartículas del Metal , Tungsteno , Tungsteno/química , Bismuto , Electrodos , Nanopartículas del Metal/química , Ácido Ascórbico/química , Técnicas Electroquímicas/métodos
18.
Chemosphere ; 329: 138670, 2023 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-37054843

RESUMEN

Decarbonization has become a critical issue in recent years due to rising energy demands and diminishing oil resources. Decarbonization systems based on biotechnology have proven to be a cost-effective and environmentally benign technique of lowering carbon emissions. Bioenergy generation is an environmentally friendly technique for mitigating climate change in the energy industry, and it is predicted to play an important role in lowering global carbon emissions. This review essentially provides a new perspective on the unique biotechnological approaches and strategies based decarbonization pathways. Furthermore, the application of genetically engineered microbes in CO2 biomitigation and energy generation is particularly emphasized. The production of biohydrogen and biomethane via anaerobic digestion techniques has been highlighted in the perspective. In this review, role of microorganisms in bioconversion of CO2 into different types of bioproducts such as biochemical, biopolymers, biosolvents and biosurfactant was summarized. The current analysis, which includes an in-depth discussion of a biotechnology-based roadmap for the bioeconomy, provides a clear picture of sustainability, forthcoming challenges, and perspectives.


Asunto(s)
Biocombustibles , Dióxido de Carbono , Dióxido de Carbono/análisis , Biotecnología/métodos
19.
Environ Pollut ; 329: 121635, 2023 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-37085105

RESUMEN

Synthesis and characterization of highly active cross-linked laccase aggregates (CLLAs) were performed and evaluated for removal of pentachlorophenol and phenanthrene from lignocellulosic biorefinery wastewater. Laccase from Tramates versicolor MTCC 138 was insolubilized as CLLAs via precipitation with 70% ammonium sulphate and simultaneous cross-linking with 5 mM glutaraldehyde to obtain activity recovery of 89.1%. Compared to the free laccase, the pH and thermal stability of the prepared CLLAs were significantly higher. At a high temperature of 60 °C, free laccase had a half-life of 0.25 h, while CLLAs had a half-life of 6.2 h. In biorefinery wastewater (pH 7.0), the free and CLLAs were stored for 3 day at a temperature of 30 °C. Free laccase completely lost their initial activity after 60 h; however, the CLLAs retained 39% activity till 72 h. Due to its excellent stability, free laccase and CLLAs were assessed for removing pentachlorophenol and phenanthrene in wastewater. CLLAs could remove 51-58% of pentachlorophenol (PCP) and phenanthrene (PHE) in 24 h. Biosurfactants, including surfactin, sophorolipid, and rhamnolipid, were assessed for their aptitude to improve the removal of organic contaminants in wastewater. Biorefinery wastewater incubated with all surfactants enhanced PCP and PHE removal compared to the no-surfactant controls. Further, 1 µM rhamnolipid significantly amplified pentachlorophenol and phenanthrene removal to 81-93% for free laccase and CLLAs, respectively.


Asunto(s)
Pentaclorofenol , Fenantrenos , Lacasa/química , Aguas Residuales
20.
Environ Pollut ; 327: 121572, 2023 Jun 15.
Artículo en Inglés | MEDLINE | ID: mdl-37028793

RESUMEN

Heavy metals, dyes and pharmaceutical pollutants in water environment are considered as serious threat to the human and animal health globally. Rapid development of industrialization and agricultural activities are the major source for eliminating the toxic pollutants into the aquatic environment. Several conventional treatment methods have been suggested for the removal of emerging contaminants from wastewater. Algal biosorption, among other strategies and techniques, is demonstrating to be a limited technical remedy that is more focused and inherently more efficient and helps remove dangerous contaminants from water sources. The different environmental effects of harmful contaminants, including heavy metals, dyes, and pharmaceutical chemicals, as well as their sources, were briefly compiled in the current review. This paper provides a comprehensive definition of the future possibilities in heavy compound decomposition by using algal technology, from aggregation to numerous biosorption procedures. Functionalized materials produced from algal sources were clearly proposed. This review further highlights the limiting factors of algal biosorption to eliminate the hazardous material. Finally, this study showed how the existence of algae indicates a potential, effective, affordable, and sustainable sorbent biomaterial for minimizing environmental pollution.


Asunto(s)
Contaminantes Ambientales , Metales Pesados , Contaminantes Químicos del Agua , Purificación del Agua , Animales , Humanos , Aguas Residuales , Purificación del Agua/métodos , Plantas , Preparaciones Farmacéuticas
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