A Short Review on Current Status and Obstacles in the Sustainable Production of Biohydrogen from Microalgal Species.

Biohydrogen is an economical fuel which has enormous promise as an alternative energy source. The synthesis of biohydrogen can be done more affordably and sustainably using microalgae. For the generation of biohydrogen and the treatment of wastewater, microalgae derived from effluent have been showing very impressive outcomes. In comparison to traditional fuel sources, microalgae have benefits. Microalgae are capable of fixing ambient Carbon dioxide and converting it to carbohydrates, which are subsequently processed biochemically to provide fuel. When compared to terrestrial crops, they require less water and minerals for production. But besides these benefits, there are certain technological restrictions on the scale-up implementations of microalgae bioenergy. In this work, we explored the production of biohydrogen from several types of microalgae. The process of producing biohydrogen is affected by a number of variables, including pH, substrate concentration, the kinds of microalgal species, and others. The most recent studies and difficulties related to each stage of the biohydrogen manufacturing process are outlined. The synthesis of microalgal biohydrogen is improved using promising approaches that are discussed. Also, the specific future direction are covered. The possibility for microalgae-based production of biohydrogen to serve as an environmentally friendly and carbon-free biofuel solution that might handle the impending fuel scarcity was demonstrated. However, additional study is required on both the upstream and downstream processes of the synthesis of biohydrogen.

A review on recent advances in electrodeionization for various environmental applications.

The growing contamination of ecosystems necessitates the development of long-term pollution-removal technologies. Electrodeionization, in notably, has newly proven as an efficient method for removing ionic chemicals from polluted waterways. The fact that continuous electrodeionization is a greener technique is most probably the biggest cause for its success. It replaces the toxic chemicals typically required to replenish resins with electric power, therefore eliminating the wastewater involved with resin renewal. In water treatment, electrodeionization solves some of the drawbacks of ion exchange resin beds, particularly ion dumping as beds expire. This comprehensive review explores the theory, principles, and mechanisms of ion movement and separation in an electrodeionization unit. Also, it investigated the construction and usage, notably in removing heavy metal and its current developments in electrodeionization unit. Recent advances in Electrodeionization like polarity reversal, Resin wafer Electrodeionization, membrane free Electrodeionization, and electrostatic shielding with novel materials and hybrid process along with Electrodeionization were addressed. Further advancements are expected in electrodeionization systems that exhibit better efficacy while running at lower costs due to decreased energy usage, rendering them appealing for industrial scale up across a wide range of applications across the world.

Continuous electrodeionization on the removal of toxic pollutant from aqueous solution.

Arsenic is among the most harmful pollutants and can create severe public health effects from such a small volume of water. Electrodeionization was used to eradicate arsenic ions from groundwater in this research. Electrodeionization system incorporates hybrid electro dialysis/ion exchange to remove and concentrate Arsenic ions from water, then reuses the processed water. The findings indicate that Electrodeionization will remove arsenic from liquids at intensities varies from 5 to 25 ppm in batch recirculation mode and 5-15 ppm in continuous column analysis. Although the device demonstrated the maximum ion percentage removal, of about 100 percent, when operated at a low voltage range from 5 to 20 V. A number of column studies were conducted to establish the breakthrough curves with concentrations ranging from 5 to 15 ppm, applied voltages ranging from 5 to 20 V, and flow rates ranging from 5 to 20 mL/min. For the present work, Arsenic was eliminated up to 98.8 percent in the trials reported here, with energy usage in the Electrodeionization unit varying around 3.88 and 60.7 kW h per kilogram of removed arsenic. This demonstrates the application's ability and productivity in removing Arsenic from aqueous solutions.

Feasibility of magnetic nano adsorbent impregnated with activated carbon from animal bone waste: Application for the chromium (VI) removal.

Chromium is the heavy metal which existing in the effluents cause extensive discomfort to the environmental components. Bone waste is widely generated in food processing industries and restaurants. It is now used by switching into activated carbon. By co-precipitation procedure, the activated carbon is coated with a nano adsorbent. The Fe3O4-BAC adsorbent potential was established in this study via several batch tests. The adsorbing adverts had super magnetic behavior, and the magnetization value was 22 emu/g. The SEM imaging of the Fe3O4-BAC shows an improved morphology of 100-446 nm, and the nanoparticles were monodispersed. The present investigation also delves into the study of system parameters on the removal of metal ions. Optimal adsorption has been found at the acidic pH at the contact time of 60min for the adsorbent amount of 5 g/L. Maximum capacity of adsorption by nano adsorbent was 27.86 mg/g. Thermodynamic and isotherm tests have established the process viability. In addition, the kinetic studies establish the inclination of the studied Fe3O4-BAC towards pseudo-first order models. Hence, Fe3O4-BAC could be potential adsorbent to remove chromium from an aqueous solution.

Critical review on hazardous pollutants in water environment: Occurrence, monitoring, fate, removal technologies and risk assessment.

Water is required for the existence of all living things. Water pollution has grown significantly, over the decades and now it has developed as a serious worldwide problem. The presence and persistence of Hazardous pollutants such as dyes, pharmaceuticals and personal care products, heavy metals, fertilizer and pesticides and their transformed products are the matter of serious environmental and health concerns. A variety of approaches have been tried to clean up water and maintain water quality. The type of pollutants present in the water determines the bulk of technological solutions. The main objective of this article was to review the occurrences and fate of hazardous contaminants (dyes, pharmaceuticals and personal care products, heavy metals, and pesticides) found in wastewater effluents. These effluents mingle with other streams of water and that are utilized for a variety of reasons such as irrigation and other domestic activities that is further complicating the issue. It also discussed traditional treatment approaches as well as current advances in hazardous pollutants removal employing graphite oxides, carbon nanotubes, metal organic structures, magnetic nano composites, and other innovative forms of useable materials. It also discussed the identification and quantification of harmful pollutants using various approaches, as well as current advancements. Finally, a risk assessment of hazardous pollutants in water is provided in terms of the human health and the environment. This data is anticipated to serve as a foundation for future improvements in hazardous pollutant risk assessment. Furthermore, future studies on hazardous pollutants must not only emphasize on the parent chemicals, as well as on their possible breakdown products in various media.

A review on adsorptive separation of toxic metals from aquatic system using biochar produced from agro-waste.

Water is a basic and significant asset for living beings. Water assets are progressively diminishing due to huge populace development, industrial activities, urbanization and rural exercises. Few heavy metals include zinc, copper, lead, nickel, cadmium and so forth can easily transfer into the water system either direct or indirect activities of electroplating, mining, tannery, painting, fertilizer industries and so forth. The different treatment techniques have been utilized to eliminate the heavy metals from aquatic system, which includes coagulation/flocculation, precipitation, membrane filtration, oxidation, flotation, ion exchange, photo catalysis and adsorption. The adsorption technique is a better option than other techniques because it can eliminate heavy metals even at lower metal ions concentration, simplicity and better regeneration behavior. Agricultural wastes are low-cost biosorbent and typically containing cellulose have the ability to absorb a variety of contaminants. It is important to note that almost all agro wastes are no longer used in their original form but are instead processed in a variety of techniques to improve the adsorption capacity of the substance. The wide range of adsorption capacities for agro waste materials were observed and almost more than 99% removal of toxic pollutants from aquatic systems were achieved using modified agro-waste materials. The present review aims at the water pollution due to heavy metals, as well as various heavy metal removal treatment procedures. The primary objectives of this research is to include an overview of adsorption and various agriculture based adsorbents and its comparison in heavy metal removal.

A review on sources, identification and treatment strategies for the removal of toxic Arsenic from water system.

Arsenic liberation and accumulation in the groundwater environment are both affected by the presence of primary ions and soluble organic matter. The most important influencing role in the co-occurrence is caused by human activity, which includes logging, agricultural runoff stream, food, tobacco, and fertilizers. Furthermore, it covers a wide range of developed and emerging technologies for removing arsenic impurities from the ecosystem, including adsorption, ion exchangers, bio sorption, coagulation and flocculation, membrane technology and electrochemical methods. This review thoroughly explores various arsenic toxicity to the atmosphere and the removal methods involved with them. To begin, the analysis focuses on the general context of arsenic outbreaks in the area, health risks associated with arsenic, and measuring techniques. The utilization of innovative functional substances such as graphite oxides, metal organic structures, carbon nanotubes, and other emerging types of composite materials, as well as the ease, reduced price, and simple operating method of the adsorbent material, are better potential alternatives for arsenic removal. The aim of this article is to examine the origins of arsenic, as well as identification and treatment methods. It also addressed recent advancements in Arsenic removal using graphite oxides, carbon nanotubes, metal organic structures, magnetic nano composites, and other novel types of usable materials. Under ideal conditions for the above methods, the arsenic removal will achieve nearly 99% in lab scale.

Application of adsorption process for effective removal of emerging contaminants from water and wastewater.

Emerging pollutants in the marine ecosystem, as well as their possible impact on live species, have become a rising cause of worry. A traditional wastewater treatment plants alone are not successful in eliminating such massive contaminant groups and therefore additional water treatment is required which is to be cost effective. Since standard primary and secondary treatment plants are unsuccessful at eliminating or degrading these harmful chemicals, a cost-effective tertiary treatment approach is proposed. Adsorption is a successful approach for Contaminants removal globally, because it is low installation expense, high performance and has easy operational design. Emerging pollutants have been removed from wastewaters using various adsorbents like activated carbons, improved bio chars, Nano adsorbents, hybrid adsorbents, and others. The purpose of this paper is to review the source of contaminants and the concept of adsorption when separating emerging contaminants. The present study aims to examine the adsorption mechanism as an effective approach for treating emerging contaminants. Then, the analysis of natural and man-made adsorbents for the separation of contaminants is examined along with its comparison. Also, future view on emerging contaminants and adsorbents in modern generation has been discussed.

An effective separation of toxic arsenic from aquatic environment using electrochemical ion exchange process.

The existence of arsenic in drinking water available for human consumption in multiple nations is among the major health issues globally. Intensified research efforts has made to eradicate arsenic contaminants from water in order to supply people who are living in multiple regions with safe drinking water. A novel process for the deletion of arsenic from aqueous solutions by the electrochemical ion exchange hybrid method were explored in this work. The paper aims to extract arsenic from aqueous solution and recycle it using an electrochemical ion exchange system for industrial purposes. A 3-compartment system was used to demonstrate this process: the center cell is separated from the anodized and cathodic chambers by means of double anionic exchange membrane, a middle cell packed with a strong anion exchange resin, and two rinse compartments, one at each electrode. Efforts are being made to illustrate the optimization of the operating parameters, including concentration, resin dose, pH, contact time, temperature for optimal arsenic removal in batch mode operation. The maximum removal of arsenic obtained is almost 100% and a minimum of 91% extraction at an initial intensity of 5-15 mg /L of arsenic with supply voltage in the 5-20 V range.

A review on effective removal of emerging contaminants from aquatic systems: Current trends and scope for further research.

Wastewater is water that has already been contaminated by domestic, industrial and commercial activity that needs to be treated before it could be discharged into some other water bodies to avoid even more groundwater contamination supplies. It consists of various contaminants like heavy metals, organic pollutants, inorganic pollutants and Emerging contaminants. Research has been doing on all types of contaminates more than a decade, but this emerging contaminants is the contaminants which arises mostly from pharmaceuticals, personal care products, hormones and fertilizer industries. The majority of emerging contaminants did not have standardized guidelines, but may have adverse effects on human and marine organisms, even at smaller concentrations. Typically, extremely low doses of emerging contaminants are found in the marine environment and cause a potential risk to the aquatic animals living there. When contaminants emerge in the marine world, they are potentially toxic and pose many risks to the health of both man and livestock. The aim of this article is to review the Emerging contaminate sources, detection methods and treatment methods. The purpose of this study is to consider the adsorption as a beneficial treatment of emerging contaminants also advanced and cost effective emerging contaminates treatment methods.