Recent and sustainable advances in phytoremediation of heavy metals from wastewater using aquatic plant species: Green approach.

A key component in a nation's economic progress is industrialization, however, hazardous heavy metals that are detrimental to living things are typically present in the wastewater produced from various industries. Therefore, before wastewater is released into the environment, it must be treated to reduce the concentrations of the various heavy metals to maximum acceptable levels. Even though several biological, physical, and chemical remediation techniques are found to be efficient for the removal of heavy metals from wastewater, these techniques are costly and create more toxic secondary pollutants. However, phytoremediation is inexpensive, environmentally friendly, and simple to be applied as a green technology for heavy metal detoxification in wastewater. The present study provides a thorough comprehensive review of the mechanisms of phytoremediation, with an emphasis on the possible utilization of plant species for the treatment of wastewater containing heavy metals. We have discussed the concept, its applications, advantages, challenges, and independent variables that determine how successful and efficient phytoremediation could be in the decontamination of heavy metals from wastewater. Additionally, we argue that the standards for choosing aquatic plant species for target heavy metal removal ought to be taken into account, as they influence various aspects of phytoremediation efficiency. Following the comprehensive and critical analysis of relevant literature, aquatic plant species are promising for sustainable remediation of heavy metals. However, several knowledge gaps identified from the review need to be taken into consideration and possibly addressed. Therefore, the review provides perspectives that indicate research needs and future directions on the application of plant species in heavy metal remediation.

Optimization of desorption parameters using response surface methodology for enhanced recovery of arsenic from spent reclaimable activated carbon: Eco-friendly and sorbent sustainability approach.

Desorption and adsorbent regeneration are imperative factors that are required to be taken into account when designing the adsorption system. From the environmental, economic, and practical points of view, regeneration is necessary for evaluating the efficiency and sustainability of synthesized adsorbents. However, no study has investigated the optimization of arsenic species desorption from spent adsorbents and their regeneration ability for reuse as well as safe disposal. This study aims to investigate the desorption ability of arsenic ions adsorbed on hybrid granular activated carbon and the optimization of the independent factors influencing the efficient recovery of arsenic species from the spent activated carbon using central composite design of the response surface methodology. The activated carbon before the sorption process and after the adsorption-desorption of arsenic ions have been characterized using SEM-EDX, FTIR, and TEM. The study found that all the investigated independent desorption variables greatly influence the retrievability of arsenic ions from the spent activated carbon. Using the desirability function for the optimization of the independent factors as a function of desorption efficiency, the optimum experimental conditions were solution pH of 2.00, eluent concentration of 0.10 M, and temperature of 26.63 ℃, which gave maximum arsenic ions recovery efficiency of 91 %. The validation of the quadratic model using laboratory confirmatory experiments gave an optimum arsenic ions desorption efficiency of 97 %. Therefore, the study reveals that the application of the central composite design of the response surface methodology led to the development of an accurate and valid quadratic model, which was utilized in the enhanced optimization of arsenic ions recovery from the spent reclaimable activated carbon. More so, the desorption isotherm and kinetic data of arsenic were well correlated with the Langmuir and the pseudo-second-order models, while the thermodynamics studies indicated that arsenic ions desorption process was feasible, endothermic, and spontaneous.

Adsorption and desorption processes of toxic heavy metals, regeneration and reusability of spent adsorbents: Economic and environmental sustainability approach.

A growing number of variables, including rising population, water scarcity, growth in the economy, and the existence of harmful heavy metals in the water supply, are contributing to the increased demand for wastewater treatment on a global scale. One of the innovative water treatment technologies is the adsorptive removal of heavy metals through the application of natural and engineered adsorbents. However, adsorption currently has setbacks that prevent its wider application for heavy metals sequestration from aquatic environments using various adsorbents, including difficulty in selecting suitable desorption eluent to recover adsorbed heavy metals and regeneration techniques to recycle the spent adsorbents for further use and safe disposal. Therefore, the recovery of adsorbed heavy metal ions and the ability to reuse the spent adsorbents is one of the economic and environmental sustainability approaches. This study presents a state-of-the-art critical review of different desorption agents that could be used to retrieve heavy metals and regenerate the spent adsorbents for further adsorption-desorption processes. Additionally, an attempt was made to discuss and summarize some of the independent factors influencing heavy metals desorption, recovery, and adsorbent regeneration. Furthermore, isotherm and kinetic modeling have been summarized to provide insights into the adsorption-desorption mechanisms of heavy metals. Finally, the review provided future perspectives to provide room for researchers and industry players who are interested in heavy metals desorption, recovery, and spent adsorbents recycling to reduce the high cost of adsorbents reproduction, minimize secondary waste generation, and thereby provide substantial economic and environmental benefits.

Efficacy of waste stabilization ponds and constructed wetlands adopted for treating faecal sludge in Africa: a review.

The generation of faecal sludge (FS) in capitals and urban settings of African countries outpaces the available storage, emptying, transportation and treatment technologies. The low technology-based treatment systems for handling FS are preferable and widely adopted in the African context due to their less associated investment and operation costs. The waste stabilization ponds and constructed wetlands were principally developed as wastewater treatment systems however they are widely adopted for treating FS in urban settings of Africa. Less information is known about the efficiency of these systems in lowering FS pollutant concentrations to meet the design specifications and the allowable discharge limits. This paper reviewed the technical efficacy of waste stabilization ponds and the constructed wetlands in treating FS by evaluating the actual treatment efficiency data against the design efficiencies and the maximum allowable discharge limits. The review results revealed that these technologies are user-friendly although they fail to lower the solids concentrations to meet the design and maximum allowable discharge limits. This failure imposes extra costs on operation and maintenance due to the fast filling of solids in the systems hence leading to short-circuiting issues. So, studies on the adequate dewatering technologies of FS before entering the systems are needed.

Evaluating the performance of faecal sludge dewatering technologies in urban settings of developing African countries: a review.

Inadequate dewatering technologies are reported as the dominant challenge in handling faecal sludge (FS) within urban settings of most African countries. Studies have been carried out to evaluate the efficiencies of unplanted sand drying beds (USDBs), decentralized wastewater treatment systems (DEWATS), and geo-tubes. However, limited information is available on comparative capabilities in dewatering the FS. This work reviewed treatment efficiencies by assessing the reported actual waste removal capacities and ascertaining if they align with the design removal provisions. Peer-reviewed papers, books, and technical reports from trusted sources were examined. The results show that all the technologies perform best in dewatering the FS; however, USDBs are widely adopted for city-wide treatment, and the other two are suited for decentralized communities. The USDB is challenged by frequent clogging and poor quality of dewatered sludge when reused or recycled in the production of solid fuel and compost due to sticking sand after sludge harvesting. The DEWATS and geo-tubes increase operational costs when used to treat the FS at a large scale. More studies should be conducted to explore locally made, cost-effective filter media and technologies to enhance the dewatering quality and quantity of the FS and increase the quality of recycled by-products.

This paper reviewed the capabilities of sand drying beds, decentralized wastewater treatment systems (DEWATS) and geo-tubes in dewatering the faecal sludge (FS).All reviewed dewatering technologies significantly reduce the solid concentration of faecal sludge, so they perform best in dewatering the FS.Sand drying beds are considered a suitable technology for city-wide sanitation management, the other two are best suited for decentralized communities.Although sand drying beds are viewed as the most promoted and adopted city-wide dewatering technology, they face clogging and poor quality of harvested dry solids for reuse and recycling purposes.More studies on alternative filter media and/or technologies are urgently needed. If the filter media is in contact and or is removed together with dry sludge during harvesting, then the media should be organic so that it enhances the quality of reused or recycled byproducts.

Facile biosynthesis of Ag-ZnO nanocomposites using Launaea cornuta leaf extract and their antimicrobial activity.

The quest to synthesize safe, non-hazardous Ag-ZnO nanoomposites (NCs) with improved physical and chemical properties has necessitated green synthesis approaches. In this research, Launaea cornuta leaf extract was proposed for the green synthesis of Ag-ZnO NCs, wherein the leaf extract was used as a reducing and capping agent. The antibacterial activity of the prepared nanoomposites was investigated against Escherichia coli and Staphylococcus aureus through the disc diffusion method. The influence of the synthesis temperature, pH, and precursor concentration on the synthesis of the Ag-ZnO NCs and antimicrobial efficacy were investigated. The nanoparticles were characterized by ATR-FTIR, XRD, UV-Vis, FESEM, and TEM. The FTIR results indicated the presence of secondary metabolites in Launaea cornuta which assisted the green synthesis of the nanoparticles. The XRD results confirmed the successful synthesis of crystalline Ag-ZnO NCs with an average particle size of 21.51 nm. The SEM and TEM images indicated the synthesized nanoparticles to be spherical in shape. The optimum synthesis conditions for Ag-ZnO NCs were at 70 °C, pH of 7, and 8% silver. Antibacterial activity results show Ag-ZnO NCs to have higher microbial inhibition on E. coli than on S. aureus with the zones of inhibition of 21 ± 1.08 and 19.67 ± 0.47 mm, respectively. Therefore, the results suggest that Launaea cornuta leaf extract can be used for the synthesis of Ag-ZnO NCs.

Adsorption and desorption ability of divalent mercury from an interactive bicomponent sorption system using hybrid granular activated carbon.

The sequestration of heavy metals from multicomponent sorption media has become critical due to the noxious effects of heavy metals on the natural environment and subsequently on human health as well as all life forms. The abatement of heavy metals using bio-adsorbents is one of the efficient and affordable approaches for treating water and wastewater. Therefore, the interactive effect of arsenic [As(III)] ions on the sorption and desorption ability of mercury [Hg(II)] from a binary sorption system was conducted. More so, the impact of reaction time, solution pH, bio-adsorbent particle size, bio-adsorbent dose, initial mono-metal, and binary-metal concentration as well as reaction temperature on the individual and competitive sorption of Hg(II) was explored. The study showed that Hg(II) could be removed effectively from the single-component system and competitively from the aqueous phases by the bio-adsorbent in the coexistence of As(III) species in the bicomponent medium. The adsorptive detoxification of Hg(II) from the monocomponent and bicomponent sorption media showed dependence on all the studied adsorption parameters. The occurrence of As(III) species in the bicomponent sorption medium affected the decontamination of Hg(II) by the bio-adsorbent and the major interactive mechanism was found to be antagonism. The spent bio-adsorbent was effectively recycled using 0.10 M nitric (HNO3) and hydrochloric (HCl) acids solutions and the multi-regeneration cycles showed a high removal efficiency in each cycle. The first regeneration cycle was found to have the highest Hg(II) ions removal efficiencies of 92.31 and 86.88% for the monocomponent and bicomponent systems, respectively. Thus, the bio-adsorbent was found to be mechanically stable and reusable up to the 6.00 regeneration cycle. Therefore, this study concludes that the bio-adsorbent not only has a higher adsorption capacity but also a good recycling performance pointing to good industrial applications and economic prospects.

Removal of heavy metals from binary and multicomponent adsorption systems using various adsorbents - a systematic review.

The ecosystem and human health are both significantly affected by the occurrence of potentially harmful heavy metals in the aquatic environment. In general, wastewater comprises an array of heavy metals, and the existence of other competing heavy metal ions might affect the adsorptive elimination of one heavy metal ion. Therefore, to fully comprehend the adsorbent's efficiency and practical applications, the abatement of heavy metals in multicomponent systems is important. In the current study, the multicomponent adsorption of heavy metals from different complex mixtures, such as binary, ternary, quaternary, and quinary solutions, utilizing various adsorbents are reviewed in detail. According to the systematic review, the adsorbents made from locally and naturally occurring materials, such as biomass, feedstocks, and industrial and agricultural waste, are effective and promising in removing heavy metals from complex water systems. The systematic study further discovered that numerous studies evaluate the adsorption characteristics of an adsorbent in a multicomponent system using various important independent adsorption parameters. These independent adsorption parameters include reaction time, solution pH, agitation speed, adsorbent dosage, initial metal ion concentration, ionic strength as well as reaction temperature, which were found to significantly affect the multicomponent sorption of heavy metals. Furthermore, through the application of the multicomponent adsorption isotherms, the competitive heavy metals sorption mechanisms were identified and characterized by three primary kinds of interactive effects including synergism, antagonism, and non-interaction. Despite the enormous amount of research and extensive data on the capability of different adsorbents, several significant drawbacks hinder adsorbents from being used practically and economically to remove heavy metal ions from multicomponent systems. As a result, the current systematic review provides insights and perspectives for further studies through the thorough and reliable analysis of the relevant literature on heavy metals removal from multicomponent systems.

Artisanal and small-scale mining in Tanzania and health implications: A policy perspective.

The mineral sector, especially its small-scale subsector, has become significant in the emerging economies of the Global South. Tanzania is the focus of this policy exposition paper because, aside from Ghana and South Africa, Tanzania is ranked 4th in Africa in terms of its mineral deposits and small-scale mining activities. The focus is also on artisanal and small-scale mining (ASM) because ASM operations have significantly increased in recent times across this mineral-rich country of East Africa. This is done against a negative backdrop-labelling of ASM as unsustainable, environmentally unfriendly, inefficient, and illegal. Tanzania has made some progress to respond to some of the challenges in the mining sector to improve the micro and macroeconomics of the country. Some areas remain challenging including the lack of proper environmental health education for the ASM miners; the lack of clear national-level policies to guide health-related matters in the ASM subsector, and the small capital investment of the ASM subsector to support healthy mining practices. The details related to the persistence of these challenges are not well known, particularly those that pertain to policymaking. This article attempts to evaluate the policy environment of the ASM subsector in Tanzania and propose appropriate actions for the future of mineral resource policymaking in Tanzania.

Data from the batch adsorption of ciprofloxacin and lamivudine from synthetic solution using jamun seed (Syzygium cumini) biochar: Response surface methodology (RSM) optimization.

This dataset expresses the experimental data on the batch adsorption of ciprofloxacin and lamivudine from synthetic solution using jamun seed (JS) (Syzygium cumini) biochar. Independent variables including concentration of pollutants (10-500 ppm), contact time (30-300 min), adsorbent dosage (1-1000 mg), pH (1-14) and adsorbent calcination temperature (250,300, 600 and 750 °C) were studied and optimized using Response Surface Methodology (RSM). Empirical models were developed to predict the maximum removal efficiency of ciprofloxacin and lamivudine, and the results were compared with the experimental data. The removal of polutants was more influenced by concentration, followed by adsorbent dosagage, pH, and contact time and the maximum removal reached 90%.

Contribution of Illicit Drug Use to Pharmaceutical Load in the Environment: A Focus on Sub-Saharan Africa.

Illicit drug abuse and addiction are universal issues requiring international cooperation and interdisciplinary and multisectoral solutions. These addictive substances are utilized for recreational purposes worldwide, including in sub-Saharan Africa. On the other hand, conventional wastewater treatment facilities such as waste stabilization ponds lack the design to remove the most recent classes of pollutants such as illicit drug abuse. As a result, effluents from these treatment schemes contaminate the entire ecosystem. Public health officials are concerned about detecting these pollutants at alarming levels in some countries, with potential undesirable effects on aquatic species and increased health hazards through exposure to contaminated waters or recycling treated or untreated effluents in agriculture. Contaminants including illicit substances enter the environment by human excreta following illegal intake, spills, or through direct dumping, such as from clandestine laboratories, when their manufacturer does not follow accepted production processes. These substances, like other pharmaceuticals, have biological activity and range from pseudopersistent to highly persistent compounds; hence, they persist in the environment while causing harm to the ecosystem. The presence of powerful pharmacological agents such as cocaine, morphine, and amphetamine in water as complex combinations can impair aquatic organisms and human health. These compounds can harm human beings and ecosystem health apart from their low environmental levels. Therefore, this article examines the presence and levels of illicit substances in ecological compartments such as wastewater, surface and ground waters in sub-Saharan Africa, and their latent impact on the ecosystem. The information on the occurrences of illicit drugs and their metabolic products in the sub-Saharan Africa environment and their contribution to pharmaceutical load is missing. In this case, it is important to research further the presence, levels, distribution, and environmental risks of exposure to human beings and the entire ecosystem.

Response surface optimization and modeling in heavy metal removal from wastewater-a critical review.

The existence of hazardous heavy metals in aquatic settings causes health risks to humans, prompting researchers to devise effective methods for removing these pollutants from drinking water and wastewater. To obtain optimum removal efficiencies and sorption capacities of the contaminants on the sorbent materials, it is normally necessary to optimize the purification technology to attain the optimum value of the independent process variables. This review discusses the most current advancements in using various adsorbents for heavy metal remediation, as well as the modeling and optimization of the adsorption process independent factors by response surface methodology. The remarkable efficiency of the response surface methodology for the extraction of the various heavy metal ions from aqueous systems by various types of adsorbents is confirmed in this critical review. For the first time, this review also identifies several gaps in the optimization of adsorption process factors that need to be addressed. The comprehensive analysis and conclusions in this review should also be useful to industry players, engineers, environmentalists, scientists, and other motivated researchers interested in the use of the various adsorbents and optimization methods or tools in environmental pollution cleanup.

A comprehensive review on the decontamination of lead(ii) from water and wastewater by low-cost biosorbents.

The disadvantages of conventional methods in water and wastewater management including the demand for high energy consumption, the creation of secondary toxic sludge, and operation cost are much too high for developing countries. However, adsorption using low-cost biosorbents is the most efficient non-conventional technique for heavy metals removal. The high adsorption capacities, cost-effectiveness, and the abundance of agricultural waste materials in nature are the important parameters that explain why these biosorbents are economical for heavy metals removal. The present investigation sought to review the biosorption of lead [Pb(ii)] onto low-cost biosorbents to understand their adsorption mechanism. The review shows that biosorption using low-cost biosorbents is eco-friendly, cost-effective, and is a simple technique for water and wastewater treatment containing lead(ii) ions. The batch biosorption tests carried out in most studies show that Pb(ii) biosorption by the low-cost biosorbents is dependent on biosorption variables such as pH of the aqueous solution, contact time, biosorbent dose, Pb(ii) initial concentration, and temperature. Furthermore, batch equilibrium data have been explored in many studies by evaluating the kinetics, isothermal and thermodynamic variables. Most of the studies on the adsorptive removal of Pb(ii) were found to follow the pseudo-second kinetic and Langmuir isotherm models with the thermodynamics variables suggesting the feasibility and spontaneous nature of Pb(ii) sequestration. However, gaps exist to increase biosorption ability, economic feasibility, optimization of the biosorption system, and desorption and regeneration of the used agricultural biosorbents.

Health Risk Assessment of Trace Elements in Soil for People Living and Working in a Mining Area.

The present study used soils collected from a small-scale gold mine area to determine the health risks due to trace elements to the at-risk population in the study area. The work involved 74 soil samples from four sampling categories: 29 samples were from the mining pits (MD), 18 samples from the first washing area (WA), 17 samples from the second washing area (WB), and 10 samples from the control area (C). All samples were analyzed for Cr, Cu, As, Pb, Cd, Co, Ni, Zn, and Hg using the Energy Dispersive X-Ray Florescence (ED-XRF) method. Trace element levels were found to vary across the four sampling categories. The concentrations of trace elements recorded from different sampling categories varied in an increasing order of MD > WA > WB > C. Mercury was detected in the highest levels (max. 3.72 ± 0.15) at WB while it was not detected in the samples from C. Samples from MD indicated that Cu (max. 737.66 ± 1.3 mg/kg) was found in the highest levels whereas Hg (mean = 0.007 mg/kg) was the lowest. At WA, Cu (max. = 178.97 ± 2.46 mg/kg) registered the highest average concentration while Hg (mean = 0.05 mg/kg) had the lowest concentration. For WB, Cu (max. = 230.66 ± 3.99 mg/kg) was found in the highest concentration. The hazard index value for all exposure routes was found to be 1.77, making noncarcinogenic effects significant to the adult population. For children, the hazard index value was 9.11, showing a severe noncarcinogenic effect on children living in the study area. For the noncancer effects through the inhalation pathway, the risk posed by Ni, Cu, Zn, and Pb was negligible for both adults and children, while Co posed the highest noncancer risk for children. Cobalt also indicated the highest noncancer risk for children through the dermal pathway, while As indicated the highest noncancer risk to children through ingestion. For the cancer risk, the adults were more at risk compared to children, except for As and Co through the dermal pathway posing the highest threat. Trace element concentrations, hazard quotient, and hazard index values indicated that the area was polluted and that noncarcinogenic and carcinogenic effects on residents and miners were significant. Therefore, there is a need to put in place mining regulations aimed at protecting the at-risk human population in the study area.

Quantitative assessment of metal contamination and associated pollution risk in sediments from the Mara River in Tanzania.

For most rivers in sub-Saharan Africa, information about pollution indices related to sediments is sparse. Sedimentological research of rivers that empty into Lake Victoria is highly patchy and wide apart. The present study determined the levels and associated risk of As, Cd, Cr, Hg, and Pb in sediments collected from four different sites along the Mara River that empties into Lake Victoria in Tanzania. Samples were collected in the dry and rainy months in 2019. Pollution indices, namely geo-accumulation index (Igeo), enrichment factor (EF), contamination factor (CF), modified contamination degree (mCd), pollution load index (PLI), potential ecological risk factor (Eri), and potential ecological risk index (RI) were used to evaluate the influence of heavy metal contamination in sediments. Dry month mean concentrations, in milligram per kilogram, of heavy metals were as follows: As (11.04 ± 0.13), Cr (1.02 ± 0.29), Cd (0.43 ± 0.05), and Hg (0.01) in the dry month. Respective sediment heavy metal concentrations for the rainy month were 22.22 ± 0.05 mg As/kg, 3.84 ± 0.34 mg Pb/kg, 1.53 ± 0.15 mg Cd/kg, 1.43 mg Cr/kg, and 0.03 mg Hg/kg. Generally, the risk indices showed high values in the rainy month and low values in the dry month, especially for As and Cd-an indication of anthropogenic influence. Correlation coefficient analysis for Pb and Cd showed a strong positive correlation (r = 0.99, p < 0.01)-this may suggest a similar source or similar transport behavior. Special attention needs to be paid with regard to rainy season As and Cd enrichment in the study area.

Levels and distribution of progesterone in receiving waters and wastewaters of a growing urban area.

This study aimed at investigating the levels and distribution of progesterone in receiving waters and wastewaters in Arusha, a fast-growing urban area and the third largest city in Tanzania. Specifically, the study was conducted along the Themi River and the adjacent waste stabilization ponds (WSPs). Progesterone was detected and quantified by using an enzyme-linked immunosorbent assay (ELISA) kit. For Themi River samples, the level of progesterone obtained ranged from 'no detection' to 439 ng/L with a mean value of 120.3 ng/L. The levels detected were significantly higher in the midstream than the upstream and downstream sections of the river (P<0.05). The higher values at the midstream were attributable to livestock, WSPs and household effluents; agricultural activities; and sewage infiltration. Progesterone levels in the present study, although not extremely high, correspond to those associated with harmful effects in other studies. Results for samples collected from the WSPs indicated a release of 215 ng progesterone per L of the receiving waters. Although progesterone removal efficiency by the WSPs was 75%, the amount released was still high enough to cause harm to aquatic organisms. Thus, more efficient techniques are required to adequately remove progesterone to the recommended levels.

Comparative sorption isotherms and removal studies for Pb(II) by physical and thermochemical modification of low-cost agro-wastes from Tanzania.

Corn and rice husks, agro-wastes available in large quantities in Tanzania, were used to remove Pb2+ from aqueous solution. Husks were used in raw form, pyrolyzed form, and chemically modified form. Material characterization was carried out using the BET method, FTIR spectroscopy, SEM, pHPZC, and cation exchange capacity analysis. Langmuir, Freundlich, Dubinin-Radushkevich (D-R), and Temkin isotherms were used to elucidate Pb2+ sorption mechanisms. The surface area and cation exchange capacity (CEC) of untreated and chemically treated biochars were significantly higher than that of raw husks. Sorption data for Pb2+ for all biosorbents fit the Freundlich and D-R models well with high R2 values. Most of the synthesized biosorbents in this study indicated >90% for Pb2+ removal, with the ZnCl2-treated corn husk biochar sorption capacities ranking highest in all modeling results. Surface morphological features (e.g., micropores and fissures) and acidic and unsaturated functional groups may have significantly contributed to the observed Pb2+ removal efficiencies.