RESUMEN
A condensation polymer (urea-formaldehyde resin) passivated ZnO nanoparticles were used as an efficient photocatalyst for methyl blue degradation in the presence of H2O2 involving a Fenton-like reaction. The formation of OHË radicals were attributed to the pivotal factor for the degradation process. The method was easy and recyclable. The dose of photocatalyst, initial dye concentration, pH variation, variations of the composition of the photocatalyst, and the effect of scavengers were gauged. The degraded product was highly fluorescent and fluorometric detection of H2O2 was achieved along with a colorimetric recognition pathway. No other dye could be degraded under similar experimental conditions, implying the novel utility of methyl blue for environmental remediation.
RESUMEN
A difficult issue in chemistry and materials science is to create metal compounds with well-defined components. Metal nanoclusters, particularly those of coinage groups (Cu, Ag, and Au), have received considerable research interest in recent years owing to the availability of atomic-level precision via joint experimental and theoretical methods, thus revealing the mechanisms in diverse nano-catalysts and functional materials. The textile sector significantly contributes to wastewater containing pollutants such as dyes and chemical substances. Textile and fabric manufacturing account for about 7 × 105 tons of wastewater annually. Approximately one thousand tons of dyes used in textile processing and finishing has been recorded as being discharged into natural streams and water bodies. Owing to the widespread environmental concerns, research has been conducted to develop absorbents that are capable of removing contaminants and heavy metals from water bodies using low-cost technology. Considering this idea, we reviewed coinage metal nanoclusters for azo and cationic dye degradation. Fluorometric and colorimetric techniques are used for dye degradation using coinage metal nanoclusters. Few reports are available on dye degradation using silver nanoclusters; and some of them are discussed in detailed herein to demonstrate the synergistic effect of gold and silver in dye degradation. Mostly, the Rhodamine B dye is degraded using coinage metals. Silver nanoclusters take less time for degradation than gold and copper nanoclusters. Mostly, H2O2 is used for degradation in gold nanoclusters. Still, all coinage metal nanoclusters have been used for the degradation due to suitable HOMO-LUMO gap, and the adsorption of a dye onto the surface of the catalyst results in the exchange of electrons and holes, which leads to the oxidation and reduction of the adsorbed dye molecule. Compared to other coinage metal nanoclusters, Ag/g-C3N4 nanoclusters displayed an excellent degradation rate constant with the dye Rhodamine B (0.0332 min-1). The behavior of doping transition metals in coinage metal nanoclusters is also reviewed herein. In addition, we discuss the mechanistic grounds for degradation, the fate of metal nanoclusters, anti-bacterial activity of nanoclusters, toxicity of dyes, and sensing of dyes.
RESUMEN
A metal-enhanced fluorescence was achieved from in situ-generated Ag0 nanoparticles in the proximity of 2-hydroxy benzaldehyde (2HB). Such nanoparticles eliminated methyl blue (MB) dye from water exclusively in the presence of Zn2+ and were proven to be an efficient adsorbent for environmental remediation (maximum uptake capacity 1065 mg·g-1). Ag was zero valent in the absorbent, while Zn2+ was in Zn(OH)2 form. Fe3+ brought back MB in the aqueous medium due to the strong interaction of MB with Fe3+ and the regeneration of blue color helped to design a selective and sensitive Fe3+ sensing platform colorimetrically (linear detection range 10-4-10-6 M; linear detection limit 10-6 M). The silver nanoparticle-induced metal-enhanced fluorescence was quenched efficiently with MB. Pb2+ restored the quenched fluorescence by removing MB from the proximity of the metalized surface of silver, and Pb2+ sensing was performed fluorometrically (linear detection range; 10-5-5 × 10-8 M limit of detection 5 × 10-8 M). Iron and lead were also estimated in a variety of natural water sources, including rainfall, drinking water from taps, and water from the Ganga River via spiking method.