RESUMEN
Sulfide- and halide-based ceramic ionic conductors exhibit comparable ionic conductivity with liquid electrolytes and are candidates for high-energy- and high-power-density all-solid-state batteries. These materials, however, are inherently brittle, making them unfavorable for applications. Here, we report a mechanically enhanced composite Na+ conductor that contains 92.5 wt % of sodium thioantimonate (Na3SbS4, NSS) and 7.5 wt % of sodium carboxymethyl cellulose (CMC); the latter serves as the binder and an electrochemically inert encapsulation layer. The ceramic and binder constituents were integrated at the particle level, providing ceramic NSS-level Na+ conductivity in the NSS-CMC composite. The more than 5-fold decrease of electrolyte thickness obtained in NSS-CMC composite provided a 5-fold increase in Na+ conductance compared to NSS ceramic pellets. As a result of the CMC encapsulation, this NSS-CMC composite shows increased moisture resistivity and electrochemical stability, which significantly promotes the cycling performance of NSS-based solid-state batteries. This work demonstrates a well-controlled, orthogonal process of ceramic-rich, composite electrolyte processing: independent streams for ceramic particle formation along with binder encapsulation in a solvent-assisted environment. This work also provides insights into the interplay among the solvent, the polymeric binder, and the ceramic particles in composite electrolyte synthesis and implies the critical importance of identifying the appropriate solvent/binder system for precise control of this complicated process.
RESUMEN
ß-Lithium thiophosphate (LPS) exhibits high Li+ conductivity and has been identified as a promising ceramic electrolyte for safe and high-energy-density all-solid-state batteries. Integrating LPS into solid-state lithium (Li) batteries would enable the use of a Li electrode with the highest deliverable capacity. However, LPS-based batteries operate at a limited current density before short-circuiting, posing a major challenge for the development of application-relevant batteries. In this work, we designed a dual-component interfacial protective layer called LiSn-LiN that forms in situ between the Li electrode and LPS electrolyte. The LiSn component, Li22Sn5, exhibits enhanced Li diffusivity compared with the metallic lithium and facilitates a more uniform lithium deposition across the electrode surface, thus eliminating Li dendrite formation. Meanwhile, the LiN component, Li3N, shows enhanced mechanical stiffness compared with LPS and functions to suppress dendrite penetration. This chemically robust LiSn-LiN interlayer provides a more than doubled deliverable critical current density compared to systems without interfacial protection. Through combined XPS and XAFS analyses, we determined the local structure and the formation kinetics of the key functional Li22Sn5 phase formed via the electrochemical reduction of a Sn3N4 precursor. This work demonstrates an example of the structural-specific design of a protective interlayer with a desired function - dendrite suppression. The structure of a functional protective layer for a given solid-state battery should be tailored based on the given battery configuration and its unique interfacial chemistry.
RESUMEN
Sodium thioantimonate (Na3SbS4) and its W-substituted analogue Na2.88Sb0.88W0.12S4 have been identified as potential electrolyte materials for all-solid-state sodium batteries due to their high Na+ conductivity. Ball milling mechanochemistry is a frequently employed synthetic approach to produce such Na+-conductive solid solutions; however, changes in the structure and morphology introduced in these systems via the mechanochemistry process are poorly understood. Herein, we combined X-ray absorption fine structure spectroscopy, Raman spectroscopy, solid-state nuclear magnetic resonance spectroscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy characterization techniques to provide an in-depth analysis of these solid electrolytes. We report unique changes seen in the structure and morphology of Na3SbS4 and Na2.88Sb0.88W0.12S4 resulting from ball milling, inducing changes in the electrochemical performance of the solid-state batteries. Specifically, we observed a tetragonal-to-cubic crystal phase transition within Na3SbS4 following the ball mill, resulting in an increase in Na+ conductivity. In contrast, the Na+ conductivity was reduced in mechanochemically treated Na2.88Sb0.88W0.12S4 due to the formation and accumulation of a WS2 phase. In addition, mechanochemical treatment alters the surface morphology of densified Na2.88Sb0.88W0.12S4 pellets, providing intimate contact at the solid electrolyte/Na interface. This phenomenon was not observed in Na3SbS4. This work reveals the structural and morphological origin of the changes seen in these materials' electrochemical performance and how mechanochemical synthesis can introduce them.
RESUMEN
All-solid-state sodium batteries utilize earth-abundant elements and are sustainable systems for large-scale energy storage and electric transportation. Replacing flammable carbonate-based electrolytes with solid-state ionic conductors promotes battery safety. Using solid-state electrolytes (SEs) also eliminates the need for packing when fabricating tandem cells, potentially enabling further enhanced energy density. Na3SbS4, a Na+ conductor, remains stable in dry air and shows high Na+ conductivity (σ ≈ 1.0 × 10-3 S/cm) and is thus a promising SE for applications in sodium batteries. However, upon repeated electrochemical cycling, Na3SbS4-containing Na batteries exhibit decaying capacity and limited cycle life, which is likely associated with the decomposition of Na3SbS4 at the electrode/electrolyte interface. This work presents an in-depth analysis of the decomposition chemistry occurring at the Na3SbS4/anode interface using combined in situ Raman and post-mortem characterization. The results indicate that the SbS43- counterion is electrochemically reduced when experiencing Na+ reduction potentials, and this reduction chemistry likely follows multiple pathways. The observed reduction products include SbS33-, the Sb2S74- dimer, the NaSb binary phase, and Na2S. We also observed the irreversibility of the decomposition and, as a consequence, the accumulation of the degradation products over cycles. Also notable is the heterogeneity of this degradation chemistry across the interface. Through the spectroelectrochemical characterizations, we reveal the possible mechanisms of the Na3SbS4 decomposition at the solid electrolyte/anode interface in an operating device.
RESUMEN
Iron-sulfur clusters are thought to be ancient cofactors that could have played a role in early protometabolic systems. Thus far, redox active, prebiotically plausible iron-sulfur clusters have always contained cysteine ligands to the cluster. However, extant iron-sulfur proteins can be found to exploit other modes of binding, including ligation by histidine residues, as seen with [2Fe-2S] Rieske and MitoNEET proteins. Here, we investigated the ability of cysteine- and histidine-containing peptides to coordinate a mononuclear Fe2+ center and a [2Fe-2S] cluster and compare their properties with purified iron-sulfur proteins. The iron-sulfur peptides were characterized by UV-vis, circular dichroism, and paramagnetic NMR spectroscopies and cyclic voltammetry. Small (≤6 amino acids) peptides can coordinate [2Fe-2S] clusters through a combination of cysteine and histidine residues with similar reduction potentials as their corresponding proteins. Such complexes may have been important for early cell-like systems.
Asunto(s)
Histidina , Proteínas Hierro-Azufre , Cisteína/metabolismo , Histidina/química , Hierro/metabolismo , Proteínas Hierro-Azufre/química , Péptidos/metabolismo , Azufre/metabolismoRESUMEN
Polytellurophenes represent an emerging class of π-conjugated polymers that possess important characteristics for flexible electronics, such as narrow HOMO-LUMO gaps (Eg) and charge mobilities that can be orders of magnitude larger than their ubiquitous polythiophene counterparts. Herein we use the reactivity of pinacolboronate (BPin) groups attached to tellurophene scaffolds to directly prepare new 2,5-diiodinated monomers, which are then polymerized to afford new low Eg oligomers and polymers. Specifically, mixtures of (cycloalkyl)tellurophene oligomers (of 5 to 12 repeat units) with ring-fused 5- and 6-membered cyclic side chains were prepared via Yamamoto coupling, with a dramatic narrowing of band gap noted when less bulky 5-membered cycloalkyl side groups were present, due to enhanced tellurophene ring coplanarity. Grignard metathesis (GRIM) was also used to gain access to the first poly(3-aryltellurophene) with 94% regioregularity, along with a low Eg of 1.3 eV and an onset of light absorption at ca. 1000 nm.
RESUMEN
Self-assembled monolayers (SAMs) of phosphonic acids (PAs) on transparent conductive oxide (TCO) surfaces can facilitate improvement in TCO/organic semiconductor interface properties. When ordered PA SAMs are formed on oxide substrates, interface dipole and electronic structure are affected by the functional group properties, orientation, and binding modes of the modifiers. Choosing octylphosphonic acid (OPA), F13-octylphosphonic acid (F13OPA), pentafluorophenyl phosphonic acid (F5PPA), benzyl phosphonic acid (BnPA), and pentafluorobenzyl phosphonic acid (F5BnPA) as a representative group of modifiers, we report polarization modulation-infrared reflection-absorption spectroscopy (PM-IRRAS) of binding and molecular orientation on indium-doped zinc oxide (IZO) substrates. Considerable variability in molecular orientation and binding type is observed with changes in PA functional group. OPA exhibits partially disordered alkyl chains but on average the chain axis is tilted â¼57° from the surface normal. F13OPA tilts 26° with mostly tridentate binding. The F5PPA ring is tilted 23° from the surface normal with a mixture of bidentate and tridentate binding; the BnPA ring tilts 31° from normal with a mixture of bidentate and tridentate binding, and the F5BnPA ring tilts 58° from normal with a majority of bidentate with some tridenate binding. These trends are consistent with what has been observed previously for the effects of fluorination on orientation of phosphonic acid modifiers. These results from PM-IRRAS are correlated with recent results on similar systems from near-edge X-ray absorption fine structure (NEXAFS) and density functional theory (DFT) calculations. Overall, these results indicate that both surface binding geometry and intermolecular interactions play important roles in dictating the orientation of PA modifiers on TCO surfaces. This work also establishes PM-IRRAS as a routine method for SAM orientation determination on complex oxide substrates.
RESUMEN
Self-assembled monolayers (SAMs) of dipolar phosphonic acids can tailor the interface between organic semiconductors and transparent conductive oxides. When used in optoelectronic devices such as organic light emitting diodes and solar cells, these SAMs can increase current density and photovoltaic performance. The molecular ordering and conformation adopted by the SAMs determine properties such as work function and wettability at these critical interfaces. We combine angle-dependent near-edge X-ray absorption fine structure (NEXAFS) spectroscopy and polarization modulation infrared reflection absorption spectroscopy (PM-IRRAS) to determine the molecular orientations of a model phenylphosphonic acid on indium zinc oxide, and correlate the resulting values with density functional theory (DFT). We find that the SAMs are surprisingly well-oriented, with the phenyl ring adopting a well-defined tilt angle of 12-16° from the surface normal. We find quantitative agreement between the two experimental techniques and density functional theory calculations. These results not only provide a detailed picture of the molecular structure of a technologically important class of SAMs, but also resolve a long-standing ambiguity regarding the vibrational-mode assignments for phosphonic acids on oxide surfaces, thus improving the utility of PM-IRRAS for future studies.
RESUMEN
Biodegradation of dissolved fluorene (Flu), phenanthrene (Ph) and pyrene (Py), three polycyclic aromatic hydrocarbons (PAHs), singly or as a mixture of the three, by two bacterial strains, MEBIC 5140 (Mycobacterium flavescens) and MEBIC 5141 (Mycobacterium scrofulaceum), as well as the effects of low molecular weight organic acids (LMWOAs), e.g. malic acid, citric acid and butyric acid on biodegradation of the three PAHs in mineral salts medium aqueous solution were investigated using a newly established dual-wavelength fluorimetric method. The results showed that biodegradation processes can be monitored simultaneously, quickly and simply by dual-wavelength fluorimetry. Both co-metabolism and inhibitory effects were found during the biodegradation of the three PAHs by MEBIC 5140 and MEBIC 5141. Positive effects of butyric acid and negative effects of citric acid on biodegradation of the three PAHs in a mixture were observed.