Soluble Fluorinated Cardo Copolyimide as an Effective Additive to Photopolymerizable Compositions Based on Di(meth)acrylates: Application for Highly Thermostable Primary Protective Coating of Silica Optical Fiber.

The development of photocurable compositions is in high demand for the manufacture of functional materials for electronics, optics, medicine, energy, etc. The properties of the final photo-cured material are primarily determined by the initial mixture, which needs to be tuned for each application. In this study we propose to use simple systems based on di(meth)acrylate, polyimide and photoinitiator for the preparation of new photo-curable compositions. It was established that a fluorinated cardo copolyimide (FCPI) based on 2,2-bis-(3,4-dicarboxydiphenyl)hexafluoropropane dianhydride, 9,9-bis-(4-aminophenyl)fluorene and 2,2-bis-(4-aminophenyl)hexafluoropropane (1.00:0.75:0.25 mol) has excellent solubility in di(met)acrylates. This made it possible to prepare solutions of FCPI in such monomers, to study the effect of FCPI on the kinetics of their photopolymerization in situ and the properties of the resulting polymers. According to the obtained data, the solutions of FCPI (23 wt.%) in 1,4-butanediol diacrylate (BDDA) and FCPI (15 wt.%) in tetraethylene glycol diacrylate were tested for the formation of the primary protective coatings of the silica optical fibers. It was found that the new coating of poly(BDDA-FCPI23%) can withstand prolonged annealing at 200 °C (72 h), which is comparable or superior to the known most thermally stable photo-curable coatings. The proposed approach can be applied to obtain other functional materials.

Spectrum collapse in a 7-core Yb-doped fiber laser with an array of fs-inscribed fiber Bragg gratings.

Femtosecond inscription of fiber Bragg gratings (FBGs) in each core of a cladding-pumped seven-core Yb-doped fiber enables efficient (≈70%) 1064-nm lasing in a robust all-fiber scheme with ≈33 W power, nearly the same for uncoupled and coupled cores. However, the output spectrum is quite different: without coupling, seven individual lines corresponding to the in-core FBG reflection spectra sum up into a broad (0.22 nm) total spectrum, whereas the multiline spectrum collapses into a single narrow line at strong coupling. The developed model shows that the coupled-core laser generates coherent superposition of supermodes at the wavelength corresponding to the geometric mean of the individual FBG spectra, whereas the generated laser line broadens, with a power (0.04-0.12 nm) like the single-core mode of a seven-times larger effective area.

Advanced distributed feedback lasers based on composite fiber heavily doped with erbium ions.

Specially designed composite heavily Er3+-doped fiber in combination with unique point-by-point inscription technology by femtosecond pulses at 1,026 nm enables formation of distributed-feedback (DFB) laser with ultra-short cavity length of 5.3 mm whose parameters are comparable and even better than those for conventional Er3+-doped fiber DFB lasers having much longer cavity. The composite fiber was fabricated by melting rare-earth doped phosphate glass in silica tube. The ultra-short DFB laser generates single-polarization single-frequency radiation at 1,550 nm with narrow linewidth (3.5 kHz) and 0.5 mW output power at 600 mW 980-nm pumping. The same fiber with conventional CW UV (244 nm) inscription technology using phase mask enables fabrication of 40-mm long DFB laser with > 18 mW output power at 3.3% pump conversion, which is a record efficiency for Er3+-doped fiber DFB lasers. The developed technologies form an advanced platform for Er3+-doped fiber DFB lasers operating around 1.55 µm with excellent output characteristics and unique practical features, in particular, the ultra-short DFB lasers are attractive for sensing applications.

Fabrication of Bragg gratings in microstructured and step index Bi-SiO2 optical fibers using an ArF laser.

An ArF excimer laser was used to fabricate Bragg gratings in fibers with Bi-SiO(2) core and microstructured or F-doped claddings without fiber presensitization. Average and modulated refractive index changes of 2.7 × 10(-4) and 1.0 × 10(-4) were induced in pristine microstructured fiber while 1.0 × 10(-4) and 0.7 × 10(-4) were observed in the F-doped-cladding fiber. Fiber luminescence was also measured under 1064 nm pumping for both fibers. Photosensitivity and luminescence were compared to a Bi-Al(2)O(3)-SiO(2) core optical fiber.

Mechanisms of optical losses in Bi:SiO2 glass fibers.

The mechanisms of optical losses in bismuth-doped silica glass (Bi:SiO(2)) and fibers were studied. It was found that in the fibers of this composition the up-conversion processes occur even at bismuth concentrations lower than 0.02 at.%. Bi:SiO(2) core holey fiber drawn under oxidizing conditions was investigated. The absorption spectrum of this fiber has no bands of the bismuth infrared active center. Annealing of this fiber under reducing conditions leads to the formation of the IR absorption bands of the bismuth active center (BAC) and to the simultaneous growth of background losses. Under the realized annealing conditions (argon atmosphere, T(max) = 1100°C, duration 30 min) the BAC concentration reaches its maximum and begins to decrease in the process of excessive Bi reduction, while the background losses only increase. It was shown that the cause of these background losses is the absorption of light by nanoparticles of metallic bismuth formed in bismuth-doped glasses as a result of reduction of a part of the bismuth ions to Bi(0) and their following aggregation. The growth of background losses occurs owing to the increase of the concentration and the size of the metallic bismuth nanoparticles.

Broadband wavelength conversion in a germanosilicate-core photonic crystal fiber.

A photonic crystal fiber with a germanosilicate core having a nonlinear coefficient of 40 (W km)(-1) near the single dispersion zero at 1.09 microm is fabricated and studied. Broadband parametric wavelength conversion of the Ti:sapphire laser output tunable at 0.8 microm to the 1.55 microm band is obtained at 1.064 microm cw pump. The tuning of the converted signal in the 300 nm range was first realized without variation of the pump wavelength.