Composting of winery waste and characteristics of the final compost according to Brazilian legislation.

The waste generated in the production of wine and grape juice is characterized by a high concentration of organic matter, when properly treated, can serve as sustainable strategies for its use and destination, and among these, the production of biocompost. Thus, the objective of this study was to evaluate the process of composting grape marc, sheep manure, and mango leaves, evaluating in the biocompost its physical-chemical, nutritional and microbiological characteristics for use in agriculture. The composting pile assembly followed the proportion of 30% of sheep manure as nitrogenous material and 70% of carbon-rich material (divided into 50% of grape marc and 20% of hose leaves), the initial C/N ratio was 33:1, and the process lasted 120 days according to legislation. When evaluating the results, the process occurred in an accelerated manner, where at 30 days the biocompost was already stabilized, and at the end of the process (120 days) it presented a C/N ratio of 5.85, as well as acceptable levels for the macronutrients K and P, and without risk of phytotoxicity, and could be used as organic fertilizer or as soil conditioner, reducing environmentally inadequate destination and generating savings with their reinsertion in the production chain.

Phenanthrene and pyrene oxidation in contaminated soils using Fenton's reagent.

Fenton's reagent has shown its applicability to oxidizing these biorefractory organic contaminants. The purpose of this contribution was to investigate the influence of operating parameters on the process efficiency for soil highly contaminated by PAHs. Five variables were selected: pH, reaction time, UV irradiation, hydrogen peroxide concentration and Fe (II) amendment. Their effects on the oxidation of (i) phenanthrene and on (ii) phenanthrene and pyrene present in freshly contaminated soil samples were studied through batch reactor experiments following factorial designs. For phenanthrene oxidation run with a soil contaminated at 700 mg kg(-1), one set of variables enabled us to reach a residual concentration lower than 40 mg kg(-1) (Dutch legislation threshold). The most important factor was the reaction time, followed at a certain distance by UV irradiation, Fe (II), H(2)O(2) concentration and pH, this last variable being the least significant. The possibility of operating without pH adjustment is of importance in the treatment at the field scale. This shows the feasibility of photo-Fenton-like oxidation for the treatment of soil highly contaminated with PAH and the relative importance of the process variables.