Emulsions in external electric fields.

Water is co-produced with crude oils, generally in the form of water-in-crude oil emulsions. The oil and water phases need to be separated before export. Separation is performed in gravity separators with the addition of chemical demulsifiers and, sometimes, with the application of an electric field by using an electrocoalescer. The present article reviews several aspects of electrocoalescence by considering the effect of the electric field from the molecular to a macroscopic scale: the oil-water interface, single drop effects, two drop interactions, and finally emulsions at laboratory scales. Experimental results together with Dissipative Particle Dynamics (DPD) simulation results are presented. The review begins with water-oil interface under an electric field and followed by single drop electrohydrodynamics. The electric field is shown to influence the adsorption of crude oil indigenous surface-active components (asphaltenes) due to the electrohydrodynamic (EHD) flows. The interactions between two droplets in the presence of electric field and the factors governing the drop-drop coalescence are discussed in detail. DPD simulations help to elucidate thin film breakup during (electro)-coalescence of two water droplets, where the oil film has drained out to nanometer thickness. The film is comprised of surfactant and demulsifier molecules, and the simulations capture the pores formation in the film when a DC field is applied. The results demonstrate influence of the molecular structure of the surfactant and demulsifier, and their interactions. The subsequent section describes experimental techniques to assess the resolution of crude oil emulsions at the laboratory scale. The focus is on low-field Nuclear Magnetic Resonance (LF-NMR) which allows a determination of various emulsion features such as the droplet size distribution (DSD) and the brine profile (variation of the concentration of water with the height of the emulsion sample) and their evolution with time. Application of the technique in emulsion treatment involving chemical demulsifiers and electric field is presented. The review concludes with description of commercial industrial electrocoalecers such as the Vessel Internal Electrostatic Coalescer (VIEC) and the Compact Electrostatic Coalescer (CEC).

Microdosimetry modeling with auger emitters in generalized cell geometry.

A microdosimetry model was developed for the prediction of cell viability for irregular non-spherical cells that were irradiated by low energy, short range auger electrons. Measured cell survival rates for LNCaP prostate cancer were compared to the computational results for the radioisotopes177Lu and161Tb (conjugated to PSMA). The cell geometries used for the computations were derived directly from the cell culture images. A general computational approach was developed to handle arbitrary cell geometries, based on distance probability distribution functions (PDFs) derived from basic image processing. The radiation calculations were done per coarse grained PDF bin to reduce computation time, rather than on a pixel/voxel basis. The radiation dose point kernels over the full electron spectrum were derived using Monte Carlo simulations for energies below 50 eV to account for the propagation of auger electrons over length scales at and below a cellular radius. The relative importance of short range auger electrons were evaluated between the two nuclide types. The microdosimetry results were consistent with the cell viability measurements, and it was found that161Tb was more efficient than177Lu primarily due to the short range auger electrons. We foresee that imaging based microdosimetry can be used to evaluate the relative therapeutic effect between various nuclide candidates.

Electrocoalescence of water in oil emulsions: a DPD simulation study and a novel application of electroporation theory.

Pore formation in a surfactant laden oil film between two aqueous electrolyte layers in a DC field was studied using DPD (Dissipative Particle Dynamics molecular simulation). This setting represents the final stage of an electro-coalescence process between water droplets in oil, where the oil film has drained out to nanometer thickness. We introduce a novel model for the coalescence probability based on electroporation theory for lipid bilayers, and an equation for a threshold electric potential above which coalescence is highly probable. Excess electric forcing (pinching) of the oil film occurred locally due to charge density fluctuations in the electrolyte, and this could lead to the formation of unstable, expanding pores and coalescence between the aqueous domains. Such unstable pores can form at lower electric potentials when the cohesive energy in the surfactant layer (primarily line tension) is lowered by adding demulsifier, or when demulsifier causes a morphology change in the surfactant layers with local areas that have lower surfactant density. In conclusion, higher ion concentrations in the electrolyte, higher electric field strength, and lower cohesive energy in the surfactant layer increased the coalescence probability.

Derivation and thermodynamics of a lattice Boltzmann model with soluble amphiphilic surfactant.

We derive a lattice Boltzmann model of a ternary fluid mixture, one component of which consists of amphiphilic molecules with a rotational degree of freedom. The model was first introduced elsewhere where it was constructed on the basis of the earlier Shan-Chen type lattice Boltzmann model for binary fluids. We provide a rigorous derivation of the model from an underlying continuum kinetic theory. In particular, we show how the model can be interpreted as a discretization of a Vlasov-Boltzmann type kinetic theory for a fluid composed of two species of oppositely charged monopoles and a composite, dipolar molecule. We also derive a free-energy functional for the model, including the contribution from the amphiphiles, and confirm that the free energy is lowered during phase separation and during the formation of a stable emulsion.