1.
Chem Commun (Camb)
; 54(24): 2982-2985, 2018 Mar 25.
Artículo
en Inglés
| MEDLINE
| ID: mdl-29504615
RESUMEN
A Pd-catalyzed synthesis of 3,4,5-trisubstituted cyclopentenes from diazabicyclic olefins and o-iodobenzoates has been developed. The hitherto unknown cascade process involves three stages: carbopalladation, oxypalladation and a Tsuji-Trost reaction. We have also developed a facile route involving a novel benzylic C-H activation towards cyclopentenoindane moieties.