RESUMEN
The reaction of lithium hexa-methyl-disilyl-amide, [Li{N(Si(CH3)3)2}] (LiHMDS), with 4,4-dimethyl-2-phenyl-2-oxazoline (Phox, C11H13NO) in hexane produced colourless crystals of bis-(4,4-dimethyl-2-phenyl-2-oxazoline-κN)(hexa-methyl-disilyl-amido-κN)lithium, [Li(C6H18NSi2)(C11H13NO)2] or [Li{N(Si(CH3)3)2}(Phox)2] in high yield (89%). Despite the 1:1 proportion of the starting materials in the reaction mixture, the product formed with a 1:2 amide:oxazoline ratio. In the unit cell of the C2/c space group, the neutral mol-ecules lie on twofold rotation axes coinciding with the Li-N(amide) bonds. The lithium(I) centre adopts a trigonal-planar coordination geometry with three nitro-gen donor atoms, one from the HMDS anion and two from the oxazolines. All ligands are monodentate. In the phenyl-oxazoline units, the dihedral angle defined by the five-membered heterocyclic rings is 35.81â (5)°, while the phenyl substituents are approximately face-to-face, separated by 3.908â (5)â Å. In the amide, the methyl groups assume a nearly eclipsed arrangement to minimize steric repulsion with the analogous substituents on the oxazoline rings. The non-covalent inter-actions in the solid-state structure of [Li{N(Si(CH3)3)2}(Phox)2] were assessed by Hirshfeld surface analysis and fingerprint plots. This new compound is attractive for catalysis due to its unique structural features.
RESUMEN
Organometallic sandwich complexes are versatile molecular systems that have been recently employed for single-molecule manipulation and spin sensing experiments. Among related organometallic compounds, the mixed-sandwich S = 1/2 complex (η8-cyclooctatetraene)(η5-cyclopentadienyl)titanium, here [CpTi(cot)], has attracted interest as a spin qubit because of the long coherence time. Here the structural and chemical properties of [CpTi(cot)] on Au(111) are investigated at the monolayer level by experimental and computational methods. Scanning tunneling microscopy suggests that adsorption occurs in two molecular orientations, lying and standing, with a 3:1 ratio. XPS data evidence that a fraction of the molecules undergo partial electron transfer to gold, while our computational analysis suggests that only the standing molecules experience charge delocalization toward the surface. Such a phenomenon depends on intermolecular interactions that stabilize the molecular packing in the monolayer. This orientation-dependent molecule-surface hybridization opens exciting perspectives for selective control of the molecule-substrate spin delocalization in hybrid interfaces.
Asunto(s)
Electrones , Titanio , Propiedades de Superficie , Microscopía de Túnel de Rastreo/métodos , AdsorciónRESUMEN
The reaction between mononuclear [Ln(bbpen)Cl] [Ln = Gd or Dy; H2bbpen = N,N'-bis-(2-hy-droxy-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine, C28H30N4O2] and potassium oxalate monohydrate in water/methanol produced the solvated centrosymmetric isostructural binuclear (µ-oxalato)bis-{[N,N'-bis-(2-oxidobenzyl-κO)-N,N'-bis-(pyridin-2-ylmethyl-κN)ethyl-enedi-amine-κ2 N,N']dilanthanide(III)}-methanol-water (1/4/4) complexes, [Ln 2(C28H28N4O2)2(C2O4)]·4CH3OH·4H2O, with lanthanide(III) = gadolinium(III) (Ln = Gd) and dysprosium(III) (Ln = Dy), in high yields (ca 70%) directly from the reaction mixtures. In both complexes, the lanthanide ion is eight-coordinate and adopts a distorted square-anti-prismatic coordination environment. The triclinic (P ) unit cell contains one dimeric unit together with four water and four methanol mol-ecules; in the final structural model, two of each type of solvating mol-ecule refine well. In each lanthanide(III) dimeric mol-ecule, the medium-strength Oâ¯H-O hydrogen-bonding pattern involves four oxygen atoms, two of them from the phenolate groups that are 'bridged' by one water and one methanol mol-ecule. These inter-actions seem to contribute to the stabilization of the relatively compact shape of the dimer. Electron densities associated with an additional water and methanol mol-ecule were removed with the SQUEEZE procedure in PLATON [Spek (2015 â¸). Acta Cryst. C71, 9-18]. These two new compounds are of inter-est with respect to magnetic properties.