Potential use of engineered nanoparticles in ocean fertilization for large-scale atmospheric carbon dioxide removal.

Artificial ocean fertilization (AOF) aims to safely stimulate phytoplankton growth in the ocean and enhance carbon sequestration. AOF carbon sequestration efficiency appears lower than natural ocean fertilization processes due mainly to the low bioavailability of added nutrients, along with low export rates of AOF-produced biomass to the deep ocean. Here we explore the potential application of engineered nanoparticles (ENPs) to overcome these issues. Data from 123 studies show that some ENPs may enhance phytoplankton growth at concentrations below those likely to be toxic in marine ecosystems. ENPs may also increase bloom lifetime, boost phytoplankton aggregation and carbon export, and address secondary limiting factors in AOF. Life-cycle assessment and cost analyses suggest that net CO2 capture is possible for iron, SiO2 and Al2O3 ENPs with costs of 2-5 times that of conventional AOF, whereas boosting AOF efficiency by ENPs should substantially enhance net CO2 capture and reduce these costs. Therefore, ENP-based AOF can be an important component of the mitigation strategy to limit global warming.

Biofuels via Fast Pyrolysis of Perennial Grasses: A Life Cycle Evaluation of Energy Consumption and Greenhouse Gas Emissions.

A well-to-wheel (WTW) life cycle assessment (LCA) model is developed to evaluate the environmental profile of producing liquid transportation fuels via fast pyrolysis of perennial grasses: switchgrass and miscanthus. The framework established in this study consists of (1) an agricultural model used to determine biomass growth rates, agrochemical application rates, and other key parameters in the production of miscanthus and switchgrass biofeedstock; (2) an ASPEN model utilized to simulate thermochemical conversion via fast pyrolysis and catalytic upgrading of bio-oil to renewable transportation fuel. Monte Carlo analysis is performed to determine statistical bounds for key sustainability and performance measures including life cycle greenhouse gas (GHG) emissions and Energy Return on Investment (EROI). The results of this work reveal that the EROI and GHG emissions (gCO2e/MJ-fuel) for fast pyrolysis derived fuels range from 1.52 to 2.56 and 22.5 to 61.0 respectively, over the host of scenarios evaluated. Further analysis reveals that the energetic performance and GHG reduction potential of fast pyrolysis-derived fuels are highly sensitive to the choice of coproduct scenario and LCA allocation scheme, and in select cases can change the life cycle carbon balance from meeting to exceeding the renewable fuel standard emissions reduction threshold for cellulosic biofuels.

Effects of co-products on the life-cycle impacts of microalgal biodiesel.

Microalgal biodiesel production has been investigated for decades, yet it is not commercially available. Part of the problem is that the production process is energy and chemical intensive due, in part, to the high portion of microalgal biomass left as residues. This study investigated cradle-to-gate life-cycle environmental impacts from six different scenarios of microalgal biodiesel and its co-products. Ozone depletion, global warming, photochemical smog formation, acidification and eutrophication potentials were assessed using the Tool for the Reduction and Assessment of Chemical and other environmental Impacts (TRACI). Monte Carlo Analysis was conducted to investigate the processes with major contribution in each impact category. The market opportunity for each co-product was examined based on supply, demand and prices of the products that could potentially be substituted by the co-products. The results indicated that the scenario with the least life-cycle environmental impacts in all the five impact categories with the highest net energy ratio was the scenario utilizing a multitude of co-products including bioethanol from lipid-extracted microalgae (LEA), biomethane (to produce electricity and heat) from simultaneous saccharification-fermentation (SSF) residues, land-applied material from SSF residue anaerobic digestion (AD) solid digestate, recycling nutrients from SSF residue AD liquid digestate and CO2 recovered from SSF process contributed. Decreasing the energy consumption of the centrifuge in the land-applied material production process and increasing the lipid content of microalgae can reduce environmental footprints of the co-products. The same scenario also had the highest total income indicating their potential as co-products in the market.

Evaluating industrial symbiosis and algae cultivation from a life cycle perspective.

A comparative life cycle assessment (LCA) was conducted on 20 scenarios of microalgae cultivation. These scenarios examined the utilization of nutrients and CO(2) from synthetic sources and waste streams as well as the materials used to construct a photobioreactor (PBR). A 0.2-m(3) closed PBR of Chlorella vulgaris at 30%-oil content by weight with the productivity of 25 g/m(2) × day was used as a case study. Results of the study show that the utilization of resources from waste streams mainly avoided global warming potential (GWP) and eutrophication impacts. Impacts from the production of material used to construct the PBR dominate total impacts in acidification and ozone depletion categories, even over longer PBR lifetimes; thus, the choice of PBR construction materials is important.