RESUMEN
In the title complex, [Co(C7H4ClO2)2(C6H6N2O)2(H2O)2], the Co(II) cation is located on an inversion center and is coord-inated by two 2-chloro-benzoate anions, two nicotin-amide (NA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Co(II) cation form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 29.7â (4)°, while the pyridine and benzene rings are oriented at a dihedral angle of 83.17â (15)°. Intra-molecular O-Hâ¯O hydrogen bonding occurs between the carboxyl-ate group and coordinating water mol-ecule. In the crystal, inter-molecular N-Hâ¯O, O-Hâ¯O and weak C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network.
RESUMEN
In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O)2(H2O)2], the Cd(II) ion is chelated by two carboxyl-ate groups from 4-methyl-benzoate anions, and is further coordinated by one nicotinamide and one water mol-ecule; a carboxyl-ate O atom from an adjacent 4-methyl-benzoate anion bridges to the Cd(II) ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, inter-molecular O-Hâ¯O, N-Hâ¯O and weak C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. The methyl-benzene moiety of one bridging 4-methyl-benzoate anion is disordered over two orientations of equal occupancy.
RESUMEN
In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethyl-benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl-ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0â (6) and 13.3â (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4â (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl-ate groups via N-Hâ¯O hydrogen bonding. In the crystal, adjacent polymeric chains inter-act via N-Hâ¯O and weak C-Hâ¯O hydrogen bonds; and the lattice water mol-ecule links with the polymeric chains via N-Hâ¯O and O-Hâ¯O hydrogen bonding. π-π stacking between the benzene and the pyridine rings [centroid-centroid distance = 3.805â (5)â Å] and weak C-Hâ¯π inter-actions are also observed in the crystal structure.
RESUMEN
In the crystal structure of the title complex, [Mn(C(7)H(4)FO(2))(2)(H(2)O)(2)](n), the Mn(II) atom is located on an inversion centre. It is coordinated by two water mol-ecules in the apical directions and four 4-fluoro-benzoate (PFB) anions, bridging the symmetry related Mn atoms in the basal plane to form an infinite two-dimensional polymeric structure parallel to (100). The four O atoms of the PFB anions around the Mn(II) atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two O atoms of the water mol-ecules. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 27.29â (16)°. The O-Hâ¯O hydrogen bonds further connect the manganese-carboxyl-ate units. π-π contacts between the benzene rings [centroid-centroid distance = 3.6894â (15)â Å] further stabilize the crystal structure.
RESUMEN
In the title Cu(II) complex, [Cu(C(7)H(4)FO(2))(2)(C(7)H(5)FO(2))(C(6)H(6)N(2)O)(2)], the Cu(II) cation is coordinated by two N atoms of two nicotinamide (NA) ligands, and by four O atoms from two 4-fluoro-benzoate (PFB) anions and one 4-fluoro-benzoic acid (PFBA) mol-ecule, in a distorted octa-hedral geometry. In the mol-ecule, two Cu-O bond lengths are significantly longer than the other two. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 11.08â (14), 7.62â (13) and 5.73â (11)°, while the benzene rings are oriented at dihedral angles of 15.62â (6), 33.71â (8) and 26.60â (8)°. In the crystal structure, extensive N-Hâ¯O, C-Hâ¯F and C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. π-π contacts between the benzene rings [centroid-to-centroid distances = 3.5517â (15), 3.8456â (14) and 3.9265â (13)â Å] further stabilize the crystal structure.
RESUMEN
The asymmetric unit of the title mononuclear Cu(II) complex, [Cu(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], contains one half-mol-ecule, the Cu(II) atom being located on an inversion center. The unit cell contains two nicotinamide (NA), two 4-bromo-benzoate (PBB) ligands and two coordinated water mol-ecules. The four O atoms in the equatorial plane around the Cu(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the adjacent benzene ring is 22.17â (16)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 82.80â (6)°. In the crystal, N-Hâ¯O, O-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. A weak C-Hâ¯π inter-action is also observed.
RESUMEN
In the title compound, C(15)H(15)NO(3), the carbazole skeleton includes an eth-oxy-carbonyl group at the 3-position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 0.89â (4)°. The cyclo-hexenone ring has an envelope conformation. In the crystal, inter-molecular N-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a three dimensional network. A weak C-Hâ¯π inter-action is also observed.
RESUMEN
In the title compound, C(8)H(7)N(4)O(4) (+)·Cl(-), the cation possesses twofold symmetry, with the twofold axis bis-ecting the 2-methyl-5,6-dinitro-benzimidazolium cation. The methyl H atoms are disordered about this twofold axis and were assigned equal half-occupancies. The chloride anion also lies on a twofold axis. In the crystal, N-Hâ¯Cl and C-Hâ¯O hydrogen bonds link the ions to form a three-dimensional network.
RESUMEN
The title Co(II) complex, [Co(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl-benzoate (PEB), two monodentate diethyl-nicotinamide (DENA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra-molecular O-Hâ¯O hydrogen bonds link the water mol-ecules to the carboxyl-ate groups. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 4.52â (18) and 4.56â (18)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 7.76â (10) and 5.67â (13)°. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules into chains propagating along [010]. C-Hâ¯O inter-actions and a π-π contact between the pyridine rings [centroid-centroid distance = 3.476â (2)â Å] are also observed.
RESUMEN
In the title compound, C(24)H(15)NO(2), the oxazole ring is oriented at dihedral angles of 10.09â (4) and 6.04â (4)° with respect to the mean planes of the naphthalene ring systems, while the two naphthalene ring systems make a dihedral angle of 4.32â (3)°. Intra-molecular C-Hâ¯N hydrogen bonds link the oxazole N atom to the naphthalene ring systems. In the crystal, inter-molecular weak C-Hâ¯O hydrogen bonds link the mol-ecules into centrosymmetric dimers. π-π contacts between the oxazole and naphthalene rings and between the naphthalene ring systems [centroid-centroid distances = 3.5947â (9) and 3.7981â (9)â Å] may further stabilize the crystal structure. Three weak C-Hâ¯π inter-actions also occur.
RESUMEN
The crystal structure of the title compound, C(6)H(16)N(+)·C(19)H(18)O(2)PS(2) (-), consists of the dithio-phospho-nate anions and the triethyl-ammonium cations, which are linked by N-Hâ¯S hydrogen bonds and weak C-Hâ¯O hydrogen bonds. In the anion, the benzene ring is oriented with respect to the naphthalene ring system at a dihedral angle of 24.92â (5)°. In the crystal, weak C-Hâ¯π inter-actions also occur.
RESUMEN
The title Cu(II) complex, [Cu(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl-benzoate (PEB) ligands, two monodentate diethyl-nicotinamide (DENA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Cu(II) ion form a slightly distorted square-planar arrangement, while the distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra-molecular O-Hâ¯O hydrogen bonds link the water mol-ecules to the carboxyl-ate groups. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 4.6â (3) and 3.7â (2)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82â (11) and 3.63â (14)°. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules into chains propagating along [010]. C-Hâ¯O inter-actions and a π-π contact between the pyridine rings [centroid-centroid distance = 3.469â (2)â Å] are also observed.
RESUMEN
The asymmetric unit of the title compound, C(18)H(11)NO(2)S, contains two crystallographically independent mol-ecules. In one mol-ecule, the oxazole and thio-phene rings are oriented at dihedral angles of 17.40â (9) and 18.18â (7)° with respect to the naphthalene ring system, while the oxazole and thio-phene rings are oriented to each other at a dihedral angle of 0.86â (9)°. In the other mol-ecule, the corresponding angles are 3.05â (8), 9.62â (6) and 7.02â (8)°, respectively. In each mol-ecule, a weak intra-molecular C-Hâ¯N hydrogen bond links the oxazole N atom to the naphthalene group. Weak inter-molecular C-Hâ¯O hydrogen bonding is present in the crystal structure. π-π stacking between the oxazole and thio-phene rings, between the thio-phene and naphthalene rings, and between the oxaozole and naphthalene rings, [centroid-centroid distances = 3.811â (2), 3.889â (2), 3.697â (2) and 3.525â (2)â Å] may further stabilize the crystal structure.
RESUMEN
In the title mol-ecule, C(18)H(12)N(2)O(4)S, the carbazole skeleton is nearly planar [maximum deviation = 0.037â (1)â Å] and is oriented at a dihedral angle of 73.73â (5)° with respect to the benzene ring. An intra-molecular C-Hâ¯O hydrogen bond links a nitro O atom to the carbazole skeleton. In the crystal, inter-molecular C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network. π-π contacts between inversion-related benzene rings [centroid-centroid distance = 3.7828â (8)â Å] and two weak C-Hâ¯π inter-actions may also stabilize the structure.
RESUMEN
The title Zn(II) complex, [Zn(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)(2)], contains two 4-ethyl-benzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn(II) ion. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 10.33â (13) and 2.38â (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46â (5) and 81.09â (6)°. In the crystal, inter-molecular N-Hâ¯O hydrogen bonds link the mol-ecules, forming a three-dimensional network. C-Hâ¯O inter-actions also occur as well as two weak C-Hâ¯π inter-actions involving the benzene rings.
RESUMEN
In the title compound, C(17)H(14)Br(2)N(2), the carbazole skeleton is nearly planar [maximum deviation = 0.055â (2)â Å]. In the crystal, aromatic π-π stacking is observed between parallel carbazole ring systems of adjacent mol-ecules, the shortest centroid-centroid distance between benzene rings being 3.4769â (11)â Å.
RESUMEN
In the crystal of the title compound, C(14)H(15)NO(4), pairs of inter-molecular N-Hâ¯O hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(10) dimers. These dimers are further connected via inter-molecular C-Hâ¯O hydrogen bonds, forming a three-dimensional network. The heterocyclic ring adopts a twisted conformation.
RESUMEN
In the mononuclear title complex, [Mn(C(8)H(7)O(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Mn(II) ion is located on a crystallographic inversion center. The asymmetric unit contains one 4-methyl-benzoate anion, one nicotinamide (NA) ligand and one coordinated water mol-ecule. The four O atoms in the equatorial plane around the Mn(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 9.01â (7)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.44â (5)°. In the crystal structure, inter-molecular O-Hâ¯O, N-Hâ¯O and C-Hâ¯O hydrogen bonds, and O-Hâ¯π and C-Hâ¯π inter-actions link the mol-ecules into a two-dimensional network parallel to (001).
RESUMEN
In the centrosymmetric mononuclear title complex, [Co(C(8)H(7)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the Co(II) ion is located on an inversion center. The asymmetric unit contains one 4-methyl-benzoate (PMB) anion, one N,N-diethyl-nicotinamide (DENA) ligand and one coordinated water mol-ecule. The four O atoms in the equatorial plane around the Co(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two pyridine N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl-ate group and the attached benzene ring is 3.73â (14)°, while the pyridine and benzene rings are oriented at a dihedral angle of 77.28â (6)°. In the crystal structure, inter-molecular O-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a two-dimensional network parallel to (001). The structure is further stabilized by π-π contacts between the pyridine rings [centroid-centroid distance = 3.544â (1)â Å] and weak C-Hâ¯π inter-actions involving the benzene ring.
RESUMEN
The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methyl-amino)benzoate (PMAB) anions and four coordinated water mol-ecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by two O atoms of the PMAB anions in the axial positions. In the crystal structure, inter-molecular O-Hâ¯O, O-Hâ¯N, N-Hâ¯O and C-Hâ¯O hydrogen bonds link the mol-ecules into a three-dimensional network.