Critical analysis on the transformation and upgrading strategy of Chinese municipal wastewater treatment plants: Towards sustainable water remediation and zero carbon emissions.

In the light of circular economy aspects, processing of large-scale municipal wastewater treatment plants (WWTPs) needs reconsideration to limit the overuse of energy, implement of non-green technologies and emit abundant greenhouse gas. Along with the huge increase in the worldwide population and agro-industrial activities, global environmental organizations have issued several recent roles to boost scientific and industrial communities towards sustainable development. Over recent years, China has imposed national and regional standards to control and manage the discharged liquid and solid waste, as well as to achieve carbon peaking and carbon neutrality. The aim of this report is to analyze the current state of Chinese WWTPs routing and related issues such as climate change and air pollution. The used strategies in Chinese WWTPs and upgrading trends were critically discussed. Several points were addressed including the performance, environmental impact, and energy demand of bio-enhanced technologies, including hydrolytic acidification pretreatment, efficient (toxic) strain treatment, and anaerobic ammonia oxidation denitrification technology, as well as advanced treatment technologies composed of physical and chemical treatment technologies, biological treatment technology and combined treatment technology. Discussion and critical analysis based on the current data and national policies were provided and employed to develop the future development trend of municipal WWTPs in China from the construction of sustainable and "Zero carbon" WWTPs.

Preparation of Mn/Ti-modified zeolite and its performance for removing iron and manganese.

Excessive iron and manganese presented in groundwater sources may cause harm to human health that needs to be solved urgently. This research aims to develop high-performance Mn/Ti-modified zeolites using sol-gel method and hydrothermal synthesis method to remove Fe2+ and Mn2+ simultaneously. The preparation parameters were optimized by response surface methodology, and the results confirmed that the optimal preparation conditions were as follows: mass ratio of MnO2-TiO2/zeolite = 1, hydrothermal temperature = 200°C, and calcination temperature = 500°C. The results of batch adsorption experiments showed that the best removal rate of Fe2+ and Mn2+ by modified zeolite materials which was prepared under the optimum conditions reached 96.8% and 94.4%, respectively, at which the saturated adsorption capacity was 2.80 mg/g and 1.86 mg/g. Through the adsorption kinetics, thermodynamics, internal diffusion, and isothermal adsorption analyses, it is confirmed that the adsorption process of Fe2+ and Mn2+ by the modified zeolite is mainly chemical adsorption. The results of the Weber-Morris internal diffusion model prove that internal diffusion is not the only step that controls the adsorption process. In addition, combined with the characterization of the composite-modified zeolite and the adsorption experimental study, it shows that there is an autocatalytic reaction in the adsorption process.