Comprehensive review on recent production trends and applications of biochar for greener environment.

The suitability of biochar as a supplement for environmental restoration varies significantly based on the type of feedstocks used and the parameters of the pyrolysis process. This study comprehensively examines several aspects of biochar's potential benefits, its capacity to enhance crop yields, improve nutrient availability, support the co-composting, water restoration and enhance overall usage efficiency. The supporting mechanistic evidence for these claims is also evaluated. Additionally, the analysis identifies various gaps in research and proposes potential directions for further exploration to enhance the understanding of biochar application. As a mutually advantageous approach, the integration of biochar into agricultural contexts not only contributes to environmental restoration but also advances ecological sustainability. The in-depth review underscores the diverse suitability of biochar as a supplement for environmental restoration, contingent upon the specific feedstock sources and pyrolysis conditions used. However, concerns have been raised regarding potential impacts on human health within agricultural sectors.

Advanced biofuel production, policy and technological implementation of nano-additives for sustainable environmental management - A critical review.

This review article critically evaluates the significance of adopting advanced biofuel production techniques that employ lignocellulosic materials, waste biomass, and cutting-edge technology, to achieve sustainable environmental stewardship. Through the analysis of conducted research and development initiatives, the study highlights the potential of these techniques in addressing the challenges of feedstock supply and environmental impact and implementation policies that have historically plagued the conventional biofuel industry. The integration of state-of-the-art technologies, such as nanotechnology, pre-treatments and enzymatic processes, has shown considerable promise in enhancing the productivity, quality, and environmental performance of biofuel production. These developments have improved conversion methods, feedstock efficiency, and reduced environmental impacts. They aid in creating a greener and sustainable future by encouraging the adoption of sustainable feedstocks, mitigating greenhouse gas emissions, and accelerating the shift to cleaner energy sources. To realize the full potential of these techniques, continued collaboration between academia, industry representatives, and policymakers remains essential.

Cinnamaldehyde inhibits Enterococcus faecalis biofilm formation and promotes clearance of its colonization by modulation of phagocytes in vitro.

The nosocomial pathogen, Enterococcus faecalis plays a crucial role in the pathogenesis of variety of infections including endocarditis, urinary tract, and recurrent root canal infections. Primary virulence factors of E. faecalis such as biofilm formation, gelatinase production and suppression of host innate immune response can severely harm host tissue. Thus, novel treatments are needed to prevent E. faecalis biofilm development and pathogenicity due to the worrisome rise in enterococcal resistance to antibiotics. The primary phytochemical in cinnamon essential oils, cinnamaldehyde, has shown promising efficacy against a variety of infections. Here, we looked into how cinnamaldehyde affected the growth of biofilms, the activity of the enzyme gelatinase, and gene expression in E. faecalis. In addition, we looked at the influence of cinnamaldehyde on RAW264.7 macrophages' interaction with biofilm and planktonic E. faecalis in terms of intracellular bacterial clearance, NO generation, and macrophage migration in vitro. According to our research, cinnamaldehyde attenuated the biofilm formation potential of planktonic E. faecalis and gelatinase activity of the biofilm at non-lethal concentrations. The expression of the quorum sensing fsr locus and its downstream gene gelE in biofilms were also found to be significantly downregulated by cinnamaldehyde. Results also demonstrated that cinnamaldehyde treatment increased NO production, intracellular bacterial clearance, and migration of RAW264.7 macrophages in presence of both biofilm and planktonic E. faecalis. Overall these results suggest that cinnamaldehyde has the ability to inhibit E. faecalis biofilm formation and modulate host innate immune response for better clearance of bacterial colonization.

Critical review of biochemical pathways to transformation of waste and biomass into bioenergy.

In recent years, biofuel or biogas have become the primary source of bio-energy, providing an alternative to conventionally used energy that can meet the growing energy demand for people all over the world while reducing greenhouse gas emissions. Enzyme hydrolysis in bioethanol production is a critical step in obtaining sugars fermented during the final fermentation process. More efficient enzymes are being researched to provide a more cost-effective technique during enzymatic hydrolysis. The exploitation of microbial catabolic biochemical reactions to produce electric energy can be used for complex renewable biomasses and organic wastes in microbial fuel cells. In hydrolysis methods, a variety of diverse enzyme strategies are used to promote efficient bioethanol production from various lignocellulosic biomasses like agricultural wastes, wood feedstocks, and sea algae. This paper investigates the most recent enzyme hydrolysis pathways, microbial fermentation, microbial fuel cells, and anaerobic digestion in the manufacture of bioethanol/bioenergy from lignocellulose biomass.

Ecological disturbances and abundance of anthropogenic pollutants in the aquatic ecosystem: Critical review of impact assessment on the aquatic animals.

Anthropogenic toxins are discharged into the environment and distributed through a variety of environmental matrices. Trace contaminant detection and analysis has advanced dramatically in recent decades, necessitating further specialized technique development. These pollutants can be mobile and persistent in small amounts in the environment, and ecological receptors will interact with it. Despite the fact that few researches have been undertaken on invertebrate exposure, accumulation, and biological implications, it is apparent that a wide range of pollutants can accumulate in the tissues of aquatic insects, earthworms, amphipod crustaceans, and mollusks. Due to long-term stability during long-distance transit, a number of chemical and microbiological agents that were not previously deemed pollutants have been found in various environmental compartments. The uptake of such pollutants by the aquatic organism is done through the process of bioaccumulation when dangerous compounds accumulate in living beings while biomagnification is the process of a pollutant becoming more hazardous as it moves up the trophic chain. Organic and metal pollution harms animals of every species studied so far, from bacteria to phyla in between. The environmental protection agency says these poisons harm humans as well as a variety of aquatic organisms when the water quality is sacrificed in typical wastewater treatment systems. Contrary to popular belief, treated effluents discharged into aquatic bodies contain considerable levels of Anthropogenic contaminants. This evolution necessitates a more robust and recent advancement in the field of remediation and their techniques to completely discharge the various organic and inorganic contaminants.

Carbon-based nanomaterial intervention and efficient removal of various contaminants from effluents - A review.

Water treatment is a worldwide issue. This review aims to present current problems and future challenges in water treatments with the existing methodologies. Carbon nanotube production, characterization, and prospective uses have been the subject of considerable and rigorous research around the world. They have a large number of technical uses because of their distinct physical characteristics. Various catalyst materials are used to make carbon nanotubes. This review's primary focus is on integrated and single-treatment technologies for all kinds of drinking water resources, including ground and surface water. Inorganic non-metallic matter, heavy metals, natural organic matter, endocrine-disrupting chemicals, disinfection by-products and microbiological pollutants are among the contaminants that these treatment systems can remediate in polluted drinking water resources. Significant advances in the antibacterial and adsorption capabilities of carbon-based nanomaterials have opened up new options for excluding organic/inorganic and biological contaminants from drinking water in recent years. The advancements in multifunctional nanocomposites synthesis pave the possibility for their use in enhanced wastewater purification system design. The adsorptive and antibacterial characteristics of six main kinds of carbon nanomaterials are single-walled carbon nanotubes, multi-walled carbon nanotubes, graphene, graphene oxide, fullerene and single-walled carbon nanohorns. This review potentially addressed the essential metallic and polymeric nanocomposites, are described and compared. Barriers to use these nanoparticles in long-term water treatment are also discussed.

Bioprospecting of novel peroxidase from Streptomyces coelicolor strain SPR7 for carcinogenic azo dyes decolorization.

Peroxidase (POX) is a heme-containing oxidoreductase, its voluminous immuno-diagnostic and bioremediatory intuitions have incited optimization and large scale-generation from novel microbial repertoires. Azo dyes are the most detrimental classes of synthetic dyes and they are the common ecotoxic industrial pollutants in wastewater. In addition, azo dyes are refractory to degradation owing to their chemical nature, comprising of azoic linkages, amino moieties with recalcitrant traits. Moreover, they are major carcinogenic and mutagenic on humans and animals, whereby emphasizing the need for decolorization. In the present study, a novel POX from Streptomyces coelicolor strain SPR7 was investigated for the deterioration of ecotoxic dyestuffs. The initial medium component screening for POX production was achieved using, One Factor at a Time and Placket-Burman methodologies with starch, casein and temperature as essential parameters. In auxiliary, Response Surface Methodology (RSM) was recruited and followed by model validation using Back propagation algorithm (BPA). RSM-BPA composite approach prophesied that combination of starch, casein, and temperature at optimal values 2.5%, 0.035% and 35 °C respectively, has resulted in 7 folds enhancement of POX outturn (2.52 U/mL) compared to the unoptimized media (0.36 U/mL). The concentrated enzyme decolorized 75.4% and 90% of the two azo dyes with lignin (10 mM), respectively. Hence, this investigation confirms the potentiality of mangrove actinomycete derived POX for elimination of noxious azo dyes to overcome their carcinogenic, mutagenic and teratogenic effects on humans and aquatic organisms.

Sustainability and carbon neutralization trends in microalgae bioenergy production from wastewater treatment: A review.

Reducing CO2 emissions using biomass is gaining popularity as an environmentally friendly strategy. Due to high growth rates, low production costs, and ability to withstand harsh conditions, microalgae have become quite popular. Microalgae may also undertake photosynthesis, converting CO2 and solar energy into sugar before becoming biomass, making them an excellent source of renewable and promising biofuels. CO2 sequestration and biofixation was utilized to compare the synthesis of biodiesel as a third-generation biofuel from various types of wastewater was also used as a source for the algal cultivation. This review article focuses on recent developments, research discoveries in the field of microalgal CO2 capture modification and the optimization of conversion efficiency. This review is intended to serve as a helpful and reference for the use of wastewater treatment with microalgae to collect CO2. The overarching objective of this study is to assist wastewater treatment systems in achieving carbon neutrality.

Recent advances in biogas production using Agro-Industrial Waste: A comprehensive review outlook of Techno-Economic analysis.

Agrowaste sources can be utilized to produce biogas by anaerobic digestion reaction. Fossil fuels have damaged the environment, while the biogas rectifies the issues related to the environment and climate change problems. Techno-economic analysis of biogas production is followed by nutrient recycling, reducing the greenhouse gas level, biorefinery purpose, and global warming effect. In addition, biogas production is mediated by different metabolic reactions, the usage of different microorganisms, purification process, upgrading process and removal of CO2 from the gas mixture techniques. This review focuses on pre-treatment, usage of waste, production methods and application besides summarizing recent advancements in biogas production. Economical, technical, environmental properties and factors affecting biogas production as well as the future perspective of bioenergy are highlighted in the review. Among all agro-industrial wastes, sugarcane straw produced 94% of the biogas. In the future, to overcome all the problems related to biogas production and modify the production process.

Graphene materials: Armor against nosocomial infections and biofilm formation - A review.

Graphene has revolutionized the field of energy and storage sectors. Out of the total number of nosocomial infections diagnosed all around the world, the majority of the cases (around 70%) are found to be due to the medical device or assistance utilized while treating the patient. Combating these diseases is vital as they cause a nuisance to the patients and medical practitioners. Coatings of graphene and its derivatives hold the key to the formation of special surfaces that can rupture microbial cells using their sharp edges, ultimately leading to nuclear and cellular fragmentation. Their incorporation as a whole or as a part in the hospital apparel and the medical device has aided medical practitioners to combat many nosocomial diseases. Graphene is found to be highly virulent with broad-spectrum antimicrobial activity against nosocomial strains and biofilm formation. Their alternate mode of action like trapping and charge transfer has also been discussed well in the present review. The various combinational forms of graphene with its conjugates as a suitable agent to combat nosocomial infections and a potential coating for newer challenges like COVID-19 infections has also been assessed in the current study. Efficiency of graphene sheets has been found to be around 89% with a reaction time as less as 3 h. Polymers with graphene seem to have a higher potency against biofilm formation. When combined with graphene oxide, silver nanoparticles provide 99% activity against nosocomial pathogens. In conclusion, this review would be a guiding light for scientists working with graphene-based coatings to unfold the potentials of this marvelous commodity to tackle the present and future pandemics to come.

Advances in bioremediation of emerging contaminants from industrial wastewater by oxidoreductase enzymes.

The bioremediation of emerging recalcitrant pollutants in wastewater via enzyme biotechnology has been evolving as cost-effective with an input of low-energy technological approach. However, the enzyme based bioremediation technology is still not fully developed at a commercial level. The oxidoreductases being the domineering biocatalysts are promising candidates for wastewater treatments. Henceforth, comprehending their global market and biotransformation efficacy is mandatory for establishing these techno-economic bio-enzymes in commercial scale. The biocatalytic strategy can be established as a combinatorial approach with existing treatment technology to achieve towering bioremediation and effective removal of emerging pollutants from wastewater. This review provides a novel insight on the toxicological xenobiotics released from industries such as paper and pulps, soap and detergents, pharmaceuticals, textiles, pesticides, explosives and aptitude of peroxidases, nitroreductase and cellobiose dehydrogenase in their bio-based treatment. Moreover, the review comprehensively covers environmental relevance of wastewater pollution and the critical challenges based on remediation achieved through biocatalysts for future prospectives.

Semenogelin, a coagulum macromolecule monitoring factor involved in the first step of fertilization: A prospective review.

Human male infertility affects approximately 1/10 couples worldwide, and its prevalence is found more in developed countries. Along with sperm cells, the secretions of the prostate, seminal vesicle and epididymis plays a major role in proper fertilization. Many studies have proven the functions of seminal vesicle secretions, especially semenogelin protein, as an optimiser for fertilization. Semenogelin provides the structural components for coagulum formation after ejaculation. It binds with eppin and is found to have major functions like motility of sperm, transporting the sperm safely in the immune rich female reproductive tract until the sperm cells reach the egg intact. The capacitation process is essential for proper fertilization and semenogelin involved in mediating capacitation in time. Also, it has control of events towards the first step in the fertilization process. It is a Zn ions binding protein, and Zn ions act as a cofactor that helps in the proper motility of sperm cells. Therefore, any imbalance in protein that automatically affect sperm physiology and fertility status. This review sheds a comprehensive and critical view on the significant functions of semenogelin in fertilization. This review can open up advanced proteomics research on semenogelin towards unravelling molecular mechanisms in fertilization.

Role of Zinc (Zn) in Human Reproduction: A Journey from Initial Spermatogenesis to Childbirth.

Zinc (Zn), the second-most necessary trace element, is abundant in the human body. The human body lacks the capacity to store Zn; hence, the dietary intake of Zn is essential for various functions and metabolism. The uptake of Zn during its transport through the body is important for proper development of the three major accessory sex glands: the testis, epididymis, and prostate. It plays key roles in the initial stages of germ cell development and spermatogenesis, sperm cell development and maturation, ejaculation, liquefaction, the binding of spermatozoa and prostasomes, capacitation, and fertilization. The prostate releases more Zn into the seminal plasma during ejaculation, and it plays a significant role in sperm release and motility. During the maternal, labor, perinatal, and neonatal periods, the part of Zn is vital. The average dietary intake of Zn is in the range of 8-12 mg/day in developing countries during the maternal period. Globally, the dietary intake of Zn varies for pregnant and lactating mothers, but the average Zn intake is in the range of 9.6-11.2 mg/day. The absence of Zn and the consequences of this have been discussed using critical evidence. The events and functions of Zn related to successful fertilization have been summarized in detail. Briefly, our current review emphasizes the role of Zn at each stage of human reproduction, from the spermatogenesis process to childbirth. The role of Zn and its supplementation in in vitro fertilization (IVF) opens opportunities for future studies on reproductive biology.