RESUMEN
With the proposal of carbon peaking and carbon neutrality goals, clean energy storage is attracting more and more attentions. In view of the lack of lithium resource in our earth, sodium-ion batteries are considered as the emerging and promising next-generation energy storage devices. Appropriate high-performance anode materials play a vital role in the development of sodium-ion batteries. Here, a core-shell hollow Ni-Co-P nanopolyhedron interconnected by oxygen defect TiO2 (Ni-Co-P@TiO2-x) is reported, which is synthesized by ion etching-hydrolysis and subsequent phosphatization/hydrogenation treatment using ZIF-67 as template and hybrid carbon source. The achieved Ni-Co-P@TiO2-x material has several distinct advantages including hollow core-shell structure, flexible conductive carbon matrix, stable electroactive coating layer, and efficient pseudocapacitive behavior, resulting in high reversible capacities, remarkable rate capability and excellent cycle stability. The synergetic battery-capacitor characteristic of Ni-Co-P@TiO2-x material makes it become a promising anode for sodium-ion batteries.
RESUMEN
Rechargeable lithium-sulfur (Li-S) batteries with environmental friendliness, low price, high specific capacity and energy density could be promising alternatives to a larger scope of energy storage in the near future. However, the practical application is impeded by the intrinsic insulation of sulfur and the fatal shuttle effect during the (dis)charging process. Herein, we report a strategy to address the drawbacks of Li-S batteries by inserting an interwoven carbon nanotubes/cerium dioxide electrocatalyst interlayer material (CNTs@CeO2) between the sulfur cathode and the separator. In the CNTs@CeO2 composite, the conductive network interwoven by CNTs facilitates electron transportation, and the abundant active sites in CeO2 cavities ensuring the adsorption-catalytic conversion of lithium polysulfides as well as the hollow structure of CeO2 is conducive to rapid electrolyte penetration and lithium ion migration. Benefiting from such multifunction, the battery with a CNTs@CeO2 interlayer exhibits superior rate performance, delivering a high discharge specific capacity of 1040.6 mAh g-1 at 0.2C and 652.5 mAh g-1 at 4C, respectively. Moreover, the battery shows excellent cycling stability with a capacity decay rate of 0.064% per cycle at 1C over 1000 cycles. These promising results demonstrate the potential application of CeO2-based electrocatalysts for high energy density Li-S batteries.
RESUMEN
Na2Fe0.6Mn0.4PO4F/C composite materials are synthesized with various carbon sources via a simple spray-drying method in this study, and the effect of carbon sources on structure, morphology, and electrochemical properties of Na2Fe0.6Mn0.4PO4F/C materials are investigated in detail. XRD and SEM results indicate that the reduction ability of carbon sources has a key impact on the structure and morphology of Na2Fe0.6Mn0.4PO4F/C composite materials. Among these Na2Fe0.6Mn0.4PO4F/C materials, the sample prepared with ascorbic acid presents a uniform hollow spherical architecture. Electrochemical analysis demonstrates that the Na2Fe0.6Mn0.4PO4F/C sample prepared with ascorbic acid has optimal electrochemical performance. The sample shows high discharge capacities of 95.1 and 48.1 mAh g-1 at 0.05C and 1C rates, respectively, and it exhibits an improved cycle stability (91.7% retention after 100 cycles at 0.5C), which are superior to Na2Fe0.6Mn0.4PO4F/C materials prepared with other carbon sources. This study demonstrates that the reduction ability of carbon sources significantly influences the electrochemical properties of fluorophosphate/C composite materials. This work also provides a promising strategy to obtain high performance cathode materials for sodium-ion batteries.
