Interactions between carbon-based nanoparticles and steroid hormone micropollutants in water.

The occurrence of micropollutants (MPs) including steroid hormones is a global environmental and health challenge. Carbon-based nanoparticles can be incorporated with water treatment processes to allow MP removal by adsorption. The aim was to compare the suitability of such nanoparticles (graphene, graphene oxide, carbon nanotubes and C60) to adsorb steroid hormones for later incorporation in membrane composites. All nanoparticles displayed fast kinetics; carbon nanotubes and graphene showed high adsorption capacities for hormones undeterminable in isotherm studies (over 10 mg/g). External surface adsorption appears to be the most prominent factor impacting adsorption performance. Structure, conformation, geometry and surface charge of nanoparticles can influence the accessibility of surface area through colloidal instability in aqueous solution. Mechanism inspection shows that adsorption initiates at long ranges (up to 10 nm) through hydrophobic and electrostatic interactions. At relatively short ranges (0.2-0.5 nm), adsorption is enhanced by π/π stacking, XH / π (X = C, O) interactions, van der Waals forces and hydrogen bonding. Both long- and short-range forces transporting hormones from the liquid bulk into the adsorbed phase could control the rate. With relatively short residence time required and high adsorption capacity, carbon nanotubes and graphene are promising for incorporation in a membrane composite.

Polymer-based spherical activated carbon - ultrafiltration (UF-PBSAC) for the adsorption of steroid hormones from water: Material characteristics and process configuration.

The European Union has proposed the value of 1 ng L-1 as a drinking water quality standard for estradiol. With conventional technologies only partially removing estradiol, the investigation of novel alternatives is more than ever required. Tagliavini and Schäfer proposed that the use of a thin activated carbon layer combined with a membrane is worth considering. In this work, the process was further advanced through a systematic investigation of the role of activated carbon size, activation and surface chemistry on the removal of estradiol. The use of smaller carbon particles allows reaching the ambitious target value of 1 ng L-1 in a millimetric layer. Further, adsorption kinetic enhancement by increasing the oxygen content on the carbon improves the removal from 96 to 99 % (for a layer of 2 mm) for OH-containing pollutants such as estradiol. High removal, together with low pressure and no by-product formation, are characteristics that make the UF-PBSAC a promising and competitive approach.

Adsorption of steroid micropollutants on polymer-based spherical activated carbon (PBSAC).

Removal and interaction mechanisms of four different steroid micropollutants, estrone (E1), estradiol (E2), progesterone (P) and testosterone (T) were determined for different types of polymer-based spherical activated carbon (PBSAC). Higher than 90% removal and significantly faster kinetics compared to conventional granular activated carbon (GAC) were observed, while performance was comparable with powdered activated carbon (PAC). No influence of pH in the range 2-12 was determined, while the presence of humic acid (HA) reduced both the removal and the kinetic by up to 20%. PBSAC was characterized in terms of morphology and material properties. The low oxygen content was identified as the main cause for the high performance observed. This was attributed to the enhancement of the hydrophobic effect between PBSAC and hormones and the reduced interactions between PBSAC and water. The ratio of micropollutant size (∼0.8nm) and average pore size (1-2nm) proved ideal for both micropollutant adsorption and HA exclusion. The homogenous size, spherical shape and surface smoothness of PBSAC did not influence adsorption negatively and make PBSAC a very promising sorbent for a vast range of applications, in particular for the removal of micropollutants in water treatment applications.