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1.
ACS Nano ; 7(8): 6948-54, 2013 Aug 27.
Artículo en Inglés | MEDLINE | ID: mdl-23879640

RESUMEN

We have introduced a facile strategy to fabricate sandwich-stacked SnO2/Cu hybrid nanosheets as multichannel anodes for lithium-ion batteries applying rolled-up nanotechnology with the use of carbon black as intersheet spacer. By employing a direct self-rolling and compressing approach, a much higher effective volume efficiency is achieved as compared to rolled-up hollow tubes. Benefiting from the nanogaps formed between each neighboring sheet, electron transport and ion diffusion are facilitated and SnO2/Cu nanosheet overlapping is prevented. As a result, the sandwich-stacked SnO2/Cu hybrid nanosheets exhibit a high reversible capacity of 764 mAh g(-1) at 100 mA g(-1) and a stable cycling performance of ~75% capacity retention at 200 mA g(-1) after 150 cycles, as well as a superior rate capability of ~470 mAh g(-1) at 1 A g(-1). This synthesis approach presents a promising route to design multichannel anodes for high performance Li-ion batteries.

2.
J Synchrotron Radiat ; 11(Pt 2): 190-7, 2004 Mar 01.
Artículo en Inglés | MEDLINE | ID: mdl-14960785

RESUMEN

This paper discusses the experimental realisation of two types of X-ray interferometer based on pinhole diffraction. In both interferometers the beam splitter was a thin metal foil containing micrometer pinholes to divide the incident X-ray wave into two coherent waves. The interference pattern was studied using an energy-dispersive detector to simultaneously investigate in a large spectral range the diffraction properties of the white synchrotron radiation. For a highly absorbing pinhole mask the interference fringes from the classical Young's double-pinhole experiment were recorded and the degree of coherence of X-rays could be determined. In the case of low absorption of the metal foil at higher X-ray energies (>15 keV) the interference pattern of a point diffraction interferometer was observed using the same set-up. The spectral refraction index of the metal foil was determined.


Asunto(s)
Análisis de Falla de Equipo , Interferometría/instrumentación , Interferometría/métodos , Radiometría/métodos , Sincrotrones/instrumentación , Difracción de Rayos X/instrumentación , Difracción de Rayos X/métodos , Diseño de Equipo , Estudios de Factibilidad , Sensibilidad y Especificidad , Rayos X
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