Characterization of potential cellulose fiber from cattail fiber: A study on micro/nano structure and other properties.

Exploration of the application prospects of cattail fibers (CFs) in natural composites, and other fields is important for the sustainable development of new, green, light-weight, functional biomass materials. In this study, the physical and chemical properties, micro/nano structure, and mechanical characteristics of CFs were investigated. The CFs have a low density (618.0 kg m-3). The results of transmission electron microscopy and tensile testing data indicated that the cattail trunk fiber (CTF) bundle is composed of parenchyma cells and solid stone cells, demonstrating high specific modulus (10.1 MPa∙m3·kg-1) and high elongation at break (3.9%). In turn, the cattail branch fiber (CBF) bundle is composed of parenchyma cells with specific "half-honeycomb" shape. The inner diaphragms divide these cells into the open cavities. This structural feature endows the CTF bundles with stable structure, good oil absorption and storage capacities. The chemical component and the Fourier transform infrared spectroscopy analyses show that the CFs have higher lignin content (20.6%) and wax content (11.5%), which are conducive to the improvement of corrosion resistance, thermal stability and lipophilic-hydrophobic property of CF. Finally, the thermogravimetric analysis indicates that its final degradation temperature is 404.5 °C, which is beneficial to the increase in processability of CFs-reinforced composites.

Influence of chemical treatment and drying method on the properties of cellulose fibers of luffa sponge.

The exploration of modified luffa sponge (LS) cellulose fiber in the field of polymer composite can contribute to the development of high-performance and lightweight composites. In this study, two chemical treatments (10%NaOH-20%CH3COOH (Method 1) and 10%NaOH-5%Na2SO3 (Method 2)) and two drying methods (air drying and freeze-drying) were used to treat LS. The microscopic characteristics and physical properties showed that Methods 1 and 2 caused shrinkage of the LS fibers and increased their fiber density by 30.6% and 15.0%. Meanwhile, freeze-drying kept the cells of modified LS fibers full and decreased their fiber density by 5.0% and 21.0%, respectively. The tensile properties test analyses indicated that freeze-drying further increased the elongation at break values of modified LS fibers by 25.3% and 17.7%, respectively. The moisture absorption analyses showed that freeze-drying could further decrease the moisture absorption ratios of modified LS fibers by 25.8% and 35.8%, respectively, which was useful for improving the dimensional stability of composite materials. Moreover, the thermogravimetric analysis reveals that freeze-drying increased onset degradation temperatures of the modified fibers by 24.0 °C and 6.7 °C, which was beneficial to improve the thermal stability of the composite material.

Characterization of potential cellulose fiber from Luffa vine: A study on physicochemical and structural properties.

The purpose of this study is to investigate the natural Luffa vine (LV) fiber to be effectively used as cellulose fiber reinforcing material for lightweight and decay-resistance composite materials. The physical, chemical, thermal, and morphological properties of the LV fibers, together with their microstructure are investigated. The test results conclude that the LV density, microscopic characteristics, and mechanical properties show that this crop is a lightweight (200-550 kg/m3) natural fiber with a porous structure and a high specific modulus (1.18-2.04 MPa∙ m3/kg). The chemical, X-ray diffraction and the Fourier transform infrared spectroscopy analyses indicate that the LV has a high lignin content (25.18%) and a relatively high relative crystallinity (37.18%) of cellulose, and it contains saponins, which increase its erosion resistance and hardness. The thermogravimetric analysis reveals that the fibers can stand up to 315.4 °C. Moreover, due to their kinetic activation energy of 63.9 kJ/mol, they can be used as reinforcement materials in thermoplastic green composites with a working temperature below 300°.

Effect of Chemical Treatments on the Properties of High-Density Luffa Mattress Filling Materials.

Luffa is a lightweight porous material with excellent biocompatibility and abundant resources. In this paper, three kinds of softening treatment methods, alkali-hydrogen peroxide (Method 1), alkali-acetic acid (Method 2), and alkali-urea (Method 3), were used to soften high-density (HD) cylindrical luffa (CL) mattress-filling materials (MFM). Microscopic observation, mechanical performance testing and other analyses were performed to evaluate the effects of the three kinds of softening methods on the wettability, compression resilience and support performance of CL MFM. The results showed that: (1) After the treatment by Method 1, Method 2 and Method 3, the peak stress of CL decreased by 73%, 10% and 27%, respectively. In addition, after three kinds of softening treatments, the uniformity of CL increased. (2) When the CL MFM of high density rank treated by Method 1 was compressed by 40%, the firmness values of the surface, core and bottom reduced by 53.49% 40.72%, and 46.17%, respectively, compared to that of untreated CL. In addition, for the CL MFM of high density rank treated by Method 3 and then compressed to 60%, the firmness of the surface layer, core layer and bottom layer reduced by 41.2%, 33.7%, and 36.9%, respectively. (3) The contact angle of luffa treated by Method 3 was the smallest, next came Method 1 and Method 2, and untreated was the largest. (4) After the treatment by Method 3, the fiber bundle of luffa was intact, and the compression resilience of the CL was obviously increased. Therefore, this method can effectively reduce the firmness of MFM and also improve the uniformity and wettability of CL.

Properties of Two-Variety Natural Luffa Sponge Columns as Potential Mattress Filling Materials.

Luffa sponge (LS) is a resourceful material with fibro-vascular reticulated structure and extremely high porosity, which make it a potential candidate for manufacturing light mattress. In this study, two types of LS columns, namely high-density (HD) and low-density (LD) columns, were investigated as materials for filling the mattress. The results showed that the compressive strength of HD LS columns was significantly greater than that of LD LS columns. However, the densification strains of the two types of LS column were both in the range of 0.6 to 0.7. Besides, HD LS columns separately pressed to the smooth plateau region and the initial densification region exhibited a partial recovery of instant height when they were unloaded, and then both of them showed no more than 4.2% of height recovery after being allowed to rest at a constant temperature and humidity for 24 h. In contrast, when LD LS columns were compressed to the smooth plateau region, the height recovery was less than 1.62% compared to when they were pressed to the initial densification region, and that was more than 15.62%. Similar to other plant fibers used as mattress fillers, the two types of LS columns also showed good water absorption capacity-both of them could absorb water from as much as 2.07 to 3.45 times their own weight. At the same time, the two types of LS columns also showed good water desorption. The water desorption ratio of HD and LD LS columns separately reached 76.86 and 91.44%, respectively, after being let rest at a constant temperature and humidity for 13 h.